Download or read book Mechanisms of Ionic Polymerization written by B.L. Erusalimskii and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last twenty years the literature on the processes of ionic polymerization has reached such a level that there is not a single question which is not covered by the information contained in the many monographs, reference books, and textbooks in this field. It is easy for the interested reader to find sources for in-depth study, for a superficial acquaintance with the fundamentals of the subject or with the general features of these processes. At the same time the field is being continually enriched by new facts which have not only broadened the data base but which influence existing concepts on the mechanisms of these reactions. Such influences often touch the very foundations of these concepts, i. e. , they go beyond simple descriptions of the structure of the pre-reaction states or earlier schemes. It is therefore appropriate to attempt a critical appraisal of the modern views on the mechanisms of formation of macro molecules in ionic systems which envisages, so far as is possible, the differentiating of fundamental and hypothetical conclusions or concepts. With this in mind we have preferred to address ourselves to the reader who is already quite well acquainted with the general litera ture. This has allowed us to dispense with detailed introductions to the questions discussed and to limit ourselves to brief comments on the fundamentals of the subject.
Download or read book Ionic Polymerization and Living Polymers written by M. Szwarc and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: More than simply an up-to-date review of ionic polymerization, this book presents an in-depth and critical comparison of the anionic and cationic polymerization of vinyl monomers and heterocyclic compounds. These different modes of ionic polymerization are examined with regard to their capacity for producing living polymers. The concept of living polymers is re-examined and redefined in light of current knowledge of ionic polymerization and possible side reactions. Throughout, the authors offer perceptive insights into the basic concepts of polymerization chemistry and polymerization reaction mechanisms. The book begins with a review of ionic and radical polymerizations, the development of ionic polymerization, living and dormant polymers, and polymerizability. It goes on to consider important aspects of the structure and properties of ionic species; initiation and propagation of ionic polymerization; polymerization steps other than initiation or propagation, such as termination, isomerization, transfer, backbiting, and degraduation; and ionic copolymerization. Ionic Polymerization and Living Polymers is a much needed advanced text that will be widely read and referred to by polymer scientists, macromolecular chemists, and materials scientists.
Download or read book Cationic Polymerizations written by Krzysztof Matyjaszewski and published by CRC Press. This book was released on 1996-04-26 with total page 783 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unified presentation of cationic polymerization discusses initiation, propagation, transfer, and termination in cationic polymerizations of alkenes and heterocycles. It also elucidates the mechanisms of the reactions involved in all carbocationic and ring-opening polymerizations. It is written by internationally acclaimed experts in their resp
Download or read book The Chemistry of Cationic Polymerization written by P. H. Plesch and published by Pergamon. This book was released on 1963 with total page 762 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ionic Polymerizations and Related Processes written by Judit E. Puskas and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Ionic Polymerization and Related Processes, internationally recognised academic and industrial researchers discuss and debate the latest developments in the field. The major focus is on cationic polymerizations, but related anionic and controlled radical processes are also discussed.
Download or read book Anionic Polymerization written by Nikos Hadjichristidis and published by Springer. This book was released on 2015-09-01 with total page 1075 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.
Download or read book Mechanism and Kinetics of Addition Polymerizations written by M. Kucera and published by Elsevier. This book was released on 1991-11-26 with total page 595 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents an up-to-date survey of knowledge concerning addition type polymerizations. It contains nine chapters, each of which covers a particular basic term. Whenever necessary, the phenomena are discussed from the viewpoint of both stationary and non-stationary state of radical, ionic (i.e. anionic and cationic) and coordination polymerization. Special attention has been paid to the propagation process. It provides not only a general overview but also information on important special cases (theoretical conditions of propagation, influence of external factors, controlled propagation, copolymerization, mechanism of various propagation types, etc.). The book is arranged according to the basic steps in chain reactions, which is a novel approach in a monograph on this topic. It facilitates the identification of common features of various polymerization types which may appear quite different. This useful, comprehensive text should prove invaluable to all those involved in the field of macromolecular chemistry. It will also be of interest to all chemists who, beside the profound study of their own field, are looking for interdisciplinary liaison points.
Download or read book IONIC POLYMERIZATION ION PAIR CHAIN MECHANISMS THE EFFECT OF DIFFERENT LEWIS ACID CATALYSTS ON THE MONOMER REACTIVITY RATIOS IN COPOLYMERIZATION written by and published by . This book was released on 1953 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Anionic Polymerization Principles and Practice written by Maurice Morton and published by Elsevier. This book was released on 2012-12-02 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anionic Polymerization: Principles and Practice describes the unique nature of the anionic mechanism of polymerization. This book is composed of two parts encompassing 11 chapters that cover the aspects of the synthetic possibilities inherent in this system. Part I deals with the various aspects of anionic polymerization mechanism, including the monomers, initiators, solvents, and the involved initiation and propagation reactions. This part also describes the copolymerization and organolithium polymerization reactions of styrene and dienes. Part II explores the applications of anionic polymerization in polymer synthesis. This part specifically tackles the synthesis of narrow molecular weight, branched and a,?-difunctional polymers, and block copolymers. Polymer chemists and researchers who work in the chemical industry and who would wish to utilize the unique features of anionic polymerization in the synthesis of new products will find this book invaluable.
Download or read book Ionic Polymerization written by H. Chéradame and published by Wiley-VCH. This book was released on 1998-12-04 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: A new volume of the series 'Macromolecular Symposia'! We present you a unique collection of papers and articles from selected international meetings in the field of macromolecular chemistry and physics that will not be found in any other journal. The contributions include those from IUPAC, the European Polymer Federation (EPF), the American Chemical Society (ACS) and the Society of Polymer Science, Japan (SPSJ).
Download or read book Fundamentals Of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2012-11-30 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry.In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
Download or read book Proceedings of the 2003 International Symposium on Ionic Polymerization and Related Processes Boston USA June 30 July 4 2003 written by Jimmy W. Mays and published by John Wiley & Sons. This book was released on 2004 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the 2003 International symposium on Ionic Polymerization and Related Processes contains papers by world leaders in this important area of polymer science, Edited by world-known experts in ionic polymerization, Professors Jimmy Mays and Robson Storey, these peer reviewed papers are presented in three sub-categories: 1. anionic polymerization; 2. cationic polymerization; 3. related processes. Aspects covered include synthesis, mechanic Studies, and applications. This volume will be useful to both academic and industrial scientists and engineers seeking to keep up with current advances in these important areas of science and technology.
Download or read book Reactivity Mechanism and Structure in Polymer Chemistry written by Aubrey Dennis Jenkins and published by John Wiley & Sons. This book was released on 1974 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanism of Polyreactions Anionic polymerization Ionic coordination polymerization written by and published by . This book was released on 1969 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanism of Polyreactions Polyaddition and polycondensation Cationic polymerization v 2 Anionic polymerization Ionic coordination polymerization v 3 Radical polymerization Radiation and photochemical polymerization Polymerization in heterogeneous systems v 4 Polymerization and polycondensation in the solid phase Grafting and cross linking v 5 Polymer analogous reactions Depolymerization degradation and stabilization of polymers written by and published by . This book was released on 1969 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanisms of Polymerization Ring opening polymerization edited by K C Frisch and S L Reegen written by George Edloe Ham and published by . This book was released on 1969 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanisms of Polymerization Vinyl polymerization edited by G E Ham 2 pts written by and published by . This book was released on 1967 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:
