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Book Low dimensional Lead Halide Perovskites with Conjugated Organic Cations

Download or read book Low dimensional Lead Halide Perovskites with Conjugated Organic Cations written by Andrei Mitrofanov and published by . This book was released on 2024 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Low Dimensional Halide Perovskites

Download or read book Low Dimensional Halide Perovskites written by Yiqiang Zhan and published by Elsevier. This book was released on 2022-11-29 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Low-Dimensional Halide Perovskites: Structure, Properties and Applications provides an in-depth look at halide perovskite materials and their applications. Chapters cover history, fundamentals, physiochemical and optoelectronic properties, synthesis and characterization of traditional and Pb-free halide perovskites. The book concludes with sections describing the different applications of halide perovskites for solar cells, light-emitting diodes and photo detectors, as well as the challenges faced in the industrialization of halide perovskite-based devices and forward-thinking prospects for further deployment. - Discusses the applications of halide perovskites according to their dimensionality - Includes a look at current challenges for the commercialization of halide perovskites, while also previewing some possible solutions - Presents alternative environmentally-friendly materials that can used to replace the current toxic materials-based halide perovskites

Book Halide Perovskites

Download or read book Halide Perovskites written by Tze-Chien Sum and published by John Wiley & Sons. This book was released on 2019-03-25 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Real insight from leading experts in the field into the causes of the unique photovoltaic performance of perovskite solar cells, describing the fundamentals of perovskite materials and device architectures. The authors cover materials research and development, device fabrication and engineering methodologies, as well as current knowledge extending beyond perovskite photovoltaics, such as the novel spin physics and multiferroic properties of this family of materials. Aimed at a better and clearer understanding of the latest developments in the hybrid perovskite field, this is a must-have for material scientists, chemists, physicists and engineers entering or already working in this booming field.

Book Halide Perovskite Semiconductors

Download or read book Halide Perovskite Semiconductors written by Yuanyuan Zhou and published by John Wiley & Sons. This book was released on 2023-12-22 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: Halide Perovskite Semiconductors Enables readers to acquire a systematic and in-depth understanding of various fundamental aspects of halide perovskite semiconductors Halide Perovskite Semiconductors: Structures, Characterization, Properties, and Phenomena covers the most fundamental topics with regards to halide perovskites, including but not limited to crystal/defect theory, crystal chemistry, heterogeneity, grain boundaries, single-crystals/thin-films/nanocrystals synthesis, photophysics, solid-state ionics, spin physics, chemical (in)stability, carrier dynamics, hot carriers, surface and interfaces, lower-dimensional structures, and structural/functional characterizations. Included discussions on the fundamentals of halide perovskites aim to expand the basic science fields of physics, chemistry, and materials science. Edited by two highly qualified researchers, Halide Perovskite Semiconductors includes specific information on: Crystal/defect theory of halide perovskites, crystal chemistry of halide perovskites, and processing and microstructures of halide perovskites Single-crystals of halide perovskites, nanocrystals of halide perovskites, low-dimensional perovskite crystals, and nanoscale heterogeneity of halide perovskites Carrier mobilities and dynamics in halide perovskites, light emission of halide perovskites, photophysics and ultrafast spectroscopy of halide perovskites Hot carriers in halide perovskites, correlating photophysics with microstructures in halide perovskites, chemical stability of halide perovskites, and solid-state ionics of halide perovskites Readers can find solutions to technological issues and challenges based on the fundamental knowledge gained from this book. As such, Halide Perovskite Semiconductors is an essential in-depth treatment of the subject, ideal for solid-state chemists, materials scientists, physical chemists, inorganic chemists, physicists, and semiconductor physicists.

Book Perovskite Photovoltaics and Optoelectronics

Download or read book Perovskite Photovoltaics and Optoelectronics written by Tsutomu Miyasaka and published by John Wiley & Sons. This book was released on 2022-03-21 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perovskite Photovoltaics and Optoelectronics Discover a one-of-a-kind treatment of perovskite photovoltaics In less than a decade, the photovoltaics of organic-inorganic halide perovskite materials has surpassed the efficiency of semiconductor compounds like CdTe and CIGS in solar cells. In Perovskite Photovoltaics and Optoelectronics: From Fundamentals to Advanced Applications, distinguished engineer Dr. Tsutomu Miyasaka delivers a comprehensive exploration of foundational and advanced topics regarding halide perovskites. It summarizes the latest information and discussion in the field, from fundamental theory and materials to critical device applications. With contributions by top scientists working in the perovskite community, the accomplished editor has compiled a resource of central importance for researchers working on perovskite related materials and devices. This edited volume includes coverage of new materials and their commercial and market potential in areas like perovskite solar cells, perovskite light-emitting diodes (LEDs), and perovskite-based photodetectors. It also includes: A thorough introduction to halide perovskite materials, their synthesis, and dimension control Comprehensive explorations of the photovoltaics of halide perovskites and their historical background Practical discussions of solid-state photophysics and carrier transfer mechanisms in halide perovskite semiconductors In-depth examinations of multi-cation anion-based high efficiency perovskite solar cells Perfect for materials scientists, crystallization physicists, surface chemists, and solid-state physicists, Perovskite Photovoltaics and Optoelectronics: From Fundamentals to Advanced Applications is also an indispensable resource for solid state chemists and device/electronics engineers.

Book Metal Halide Perovskites for Generation  Manipulation and Detection of Light

Download or read book Metal Halide Perovskites for Generation Manipulation and Detection of Light written by Juan P. Martínez-Pastor and published by Elsevier. This book was released on 2023-07-20 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Halide Perovskites for Generation, Manipulation and Detection of Light covers the current state and future prospects of lead halide perovskite photonics and photon sources, both from an academic and industrial point-of-view. Advances in metal halide perovskite photon sources (lasers) based on thin films, microcrystals and nanocrystals are comprehensively reviewed, with leading experts contributing current advances in theory, fundamental concepts, fabrication techniques, experiments and other important research innovations. This book is suitable for graduate students, researchers, scientists and engineers in academia and R&D in industry working in the disciplines of materials science and engineering. - Includes comprehensive reviews from academic and industrial perspectives of current trends in the field of metal halide perovskite for photonics - Provides an up-to-date look at the most recent and upcoming applications in metal halide perovskite photonics, such as; photodetectors, lighting, lasing, nonlinear photonics and quantum technologies - Discusses future prospective trends and envisioned applications of metal halide perovskites, from near-UV to near-IR photonics

Book Hybrid Organic inorganic Halide Perovskite Single Crystals Directed by Phosphonium Cation templates

Download or read book Hybrid Organic inorganic Halide Perovskite Single Crystals Directed by Phosphonium Cation templates written by Saja Abdulrahman A. Althobaiti and published by . This book was released on 2021 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic/organic hybrid perovskites have emerged as synthetic materials that exhibit promising applications in optoelectronic devices. There is a wealth in choice of organic cations that can be used to create hybrid structures with different shape, size, polarizability, and electronegativity. Although perovskites with ammonium cations have been previously reported, a perovskite family with phosphonium cations has been less investigated. This study reports the synthesis, crystal, and characterization of the novel low-dimensional phosphonium-base organic-inorganic hybrid single crystal materials. First, the phosphonium bromide salts were reacted with the lead bromides and iodides towards creating a perovskite crystal. Further reactions of phosphonium salts with the transition metal halides were made to discover if variant perovskite structures will be obtained. On the basis of the single-crystal X-ray diffraction results carried out at room temperature, the reaction of lead(II) bromide and iodide with various phosphonium salts produced a charge-balanced network of PbBr3 and PbI3– fragments connecting in a face-sharing octahedral motif. However, the reaction of lead(II) chloride and lead(II) iodide with tetraphenylphosphonium bromide (TPPB = C24H20PBr) produced a [Pb3(Cl/Br)8]2- and a [Pb2I6]2-that is surrounded by (C24H20P+) molecules (organic part), featuring a one-dimensional (1D) double chines and zero-dimensional (0D) structure, respectively. We note the increased cation size causes greater separation of charges, which tears apart the linked metal anion chains and lowers dimensionality; a separate effect was the formation of a new plumbate ion [Pb3(Cl/Br)8]2– where a Pb-phenyl interaction from a cation replaces an expected Pb-halogen bond. These phosphonium-templated haloplumbates were found to possess semiconducting properties, as suggested by the results of UV-Vis. Four novel crystal structures were isolated from reactions of tetraphenylphosphonium salt with zinc(II), cadmium(II), cobalt(II) and copper(II) chloride, each of them producing a unique geometry. Reacting TPPB with ZnCl2, (C24H20P)[ZnCl3(C3H7NO)] results in one (C24H20P+) cation and one [ZnCl3(DMF)] anion (DMF is dimethylformamide). In the anion, the zinc atom is tetrahedrally coordinated by a DMF ligand via the O atom and by three terminal Cl atoms. However, a different structure forms using TPPB with CdCl2, in which the CdX4 ion has a mixture of Cl and Br in a disordered state. As a result of the larger TPP cation, the TPP cation was found to break the -Cu-Cu-Cu-Cu- infinite chain and form dimers in which the smaller Cl atoms are bridging in the middle and the Br atoms are occupying the outer position. Photoluminescence investigation for (C24H20P)2Pb3(Cl/Br)8, zinc and cadmium components reveals a strong emission in the green region at 310 and 350 nm excitation wavelengths, respectively.

Book Hybrid Organic Inorganic Perovskites

Download or read book Hybrid Organic Inorganic Perovskites written by Li Wei and published by John Wiley & Sons. This book was released on 2020-10-19 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hybrid organic-inorganic perovskites (HOIPs) have attracted substantial interest due to their chemical variability, structural diversity and favorable physical properties the past decade. This materials class encompasses other important families such as formates, azides, dicyanamides, cyanides and dicyanometallates. The book summarizes the chemical variability and structural diversity of all known hybrid organic-inorganic perovskites subclasses including halides, azides, formates, dicyanamides, cyanides and dicyanometallates. It also presents a comprehensive account of their intriguing physical properties, including photovoltaic, optoelectronic, dielectric, magnetic, ferroelectric, ferroelastic and multiferroic properties. Moreover, the current challenges and future opportunities in this exciting field are also been discussed. This timely book shows the readers a complete landscape of hybrid organic-inorganic pervoskites and associated multifuctionalities.

Book Perovskite Solar Cells

Download or read book Perovskite Solar Cells written by Shahzada Ahmad and published by John Wiley & Sons. This book was released on 2022-03-14 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents a thorough overview of perovskite research, written by leaders in the field of photovoltaics The use of perovskite-structured materials to produce high-efficiency solar cells is a subject of growing interest for academic researchers and industry professionals alike. Due to their excellent light absorption, longevity, and charge-carrier properties, perovskite solar cells show great promise as a low-cost, industry-scalable alternative to conventional photovoltaic cells. Perovskite Solar Cells: Materials, Processes, and Devices provides an up-to-date overview of the current state of perovskite solar cell research. Addressing the key areas in the rapidly growing field, this comprehensive volume covers novel materials, advanced theory, modelling and simulation, device physics, new processes, and the critical issue of solar cell stability. Contributions by an international panel of researchers highlight both the opportunities and challenges related to perovskite solar cells while offering detailed insights on topics such as the photon recycling processes, interfacial properties, and charge transfer principles of perovskite-based devices. Examines new compositions, hole and electron transport materials, lead-free materials, and 2D and 3D materials Covers interface modelling techniques, methods for modelling in two and three dimensions, and developments beyond Shockley-Queisser Theory Discusses new fabrication processes such as slot-die coating, roll processing, and vacuum sublimation Describes the device physics of perovskite solar cells, including recombination kinetics and optical absorption Explores innovative approaches to increase the light conversion efficiency of photovoltaic cells Perovskite Solar Cells: Materials, Processes, and Devices is essential reading for all those in the photovoltaic community, including materials scientists, surface physicists, surface chemists, solid state physicists, solid state chemists, and electrical engineers.

Book Industrial Organic Pigments

Download or read book Industrial Organic Pigments written by Willy Herbst and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 678 pages. Available in PDF, EPUB and Kindle. Book excerpt: 'Everything there is to know about organic pigments' Revised and updated, this highly acclaimed work, now in its third edition, remains the most comprehensive source of information available on synthetic organic pigments. The book provides up-to-date information on synthesis, reaction mechanisms, physical and chemical properties, test methods, and applications of all industrially produced organic pigments of the world market. Standardized methods have been used to obtain the data thus facilitating comparison between pigments. Chemists, engineers, colorists, and technicians are sure to find this book invaluable. 'Presentation throughout is of the highest quality and the volume must now become the standard reference text in this important area of colouring matters.' Dyes and Pigments 'This is a very wide-ranging reference work ... it would be difficult to find a topic in this field not covered by this book.' Ecochem

Book Lead Halide Perovskite Solar Cells

Download or read book Lead Halide Perovskite Solar Cells written by Fisher, D.J. and published by Materials Research Forum LLC. This book was released on 2020-06-06 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lead halide perovskite materials have a huge potential in solar cell technology. They offer the combined advantages of low-cost preparation and high power-conversion efficiency. The present review focusses on the following topics: Power Conversion Efficiency; Electron Transport, Hole Transport and Interface Layers; Material Preparation; Cesium-Doped Lead-Halide Perovskites; Formamidinium-Doped Lead-Halide Perovskites; Methylammonium Lead-Halide Perovskites; Hysteresis, Stability and Toxicity Problems. The book references 334 original resources and includes their direct web link for in-depth reading. Keywords: Solar Cells, Lead Halide Perovskite Materials, Cesium-Doped Lead-Halide Perovskites, Formamidinium-Doped Lead-Halide Perovskites, Methylammonium Lead-Halide Perovskites, Electron-Transport Layer, Hole-Transport Layer, Interface Layers, Hysteresis Problem, Stability Problem, Toxicity Problem.

Book Multifunctional Organic   Inorganic Halide Perovskite

Download or read book Multifunctional Organic Inorganic Halide Perovskite written by Nam-Gyu Park and published by CRC Press. This book was released on 2022-03-10 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perovskite is a well-known structure with the chemical formula ABX3, where A and B are cations coordinated with 12 and 6 anions, respectively, and X is an anion. When a halogen anion is used, the monovalent A and divalent B cations can be stabilized with respect to a tolerance factor ranging from ~0.8 to 1. Since the first report on ~10% efficiency and long-term stability of solid-state perovskite solar cells (PSCs) in 2012 and two subsequent seed reports on perovskite-sensitized solar cells in 2009 and 2011, PSCs have received increasing attention. The power conversion efficiency of PSCs was certified to be more than 25% in 2020, surpassing thin-film solar cell technologies. Methylammonium or formamidinium organic ion–based lead iodide perovskite has been used for high-efficiency PSCs. The first report on solid-state PSCs triggered perovskite photovoltaics, leading to more than 23,000 publications as of October 2021. In addition, halide perovskite has shown excellent performance when applied to light-emitting diodes (LEDs), photodetectors, and resistive memory, indicating that halide perovskite is multifunctional. This book explains the electro-optical and ferroelectric properties of perovskite and details the recent progress in scalable and tandem PSCs as well as perovskite LEDs and resistive memory. It is a useful textbook and self-help study guide for advanced undergraduate- and graduate-level students of materials science and engineering, chemistry, chemical engineering, and nanotechnology; for researchers in photovoltaics, LEDs, resistive memory, and perovskite-related opto-electronics; and for general readers who wish to gain knowledge about halide perovskite.

Book Lead Halide Perovskite Solar Cells

Download or read book Lead Halide Perovskite Solar Cells written by David J. Fisher and published by Materials Research Forum LLC. This book was released on 2020-06-05 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lead halide perovskite materials have a huge potential in solar cell technology. They offer the combined advantages of low-cost preparation and high power-conversion efficiency. The present review focusses on the following topics: Power Conversion Efficiency; Electron Transport, Hole Transport and Interface Layers; Material Preparation; Cesium-Doped Lead-Halide Perovskites; Formamidinium-Doped Lead-Halide Perovskites; Methylammonium Lead-Halide Perovskites; Hysteresis, Stability and Toxicity Problems. The book references 334 original resources and includes their direct web link for in-depth reading. Keywords: Solar Cells, Lead Halide Perovskite Materials, Cesium-Doped Lead-Halide Perovskites, Formamidinium-Doped Lead-Halide Perovskites, Methylammonium Lead-Halide Perovskites, Electron-Transport Layer, Hole-Transport Layer, Interface Layers, Hysteresis Problem, Stability Problem, Toxicity Problem.

Book Perovskite Photovoltaics

Download or read book Perovskite Photovoltaics written by Aparna Thankappan and published by Academic Press. This book was released on 2018-06-29 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perovskite Photovoltaics: Basic to Advanced Concepts and Implementation examines the emergence of perovskite photovoltaics, associated challenges and opportunities, and how to achieve broader development. Consolidating developments in perovskite photovoltaics, including recent progress solar cells, this text also highlights advances and the research necessary for sustaining energy. Addressing different photovoltaics fields with tailored content for what makes perovskite solar cells suitable, and including commercialization examples of large-scale perovskite solar technology. The book also contains a detailed analysis of the implementation and economic viability of perovskite solar cells, highlighting what photovoltaic devices need to be generated by low cost, non-toxic, earth abundant materials using environmentally scalable processes. This book is a valuable resource engineers, scientists and researchers, and all those who wish to broaden their knowledge on flexible perovskite solar cells. - Includes contributions by leading solar cell academics, industrialists, researchers and institutions across the globe - Addresses different photovoltaics fields with tailored content for what makes perovskite solar cells different - Provides commercialization examples of large-scale perovskite solar technology, giving users detailed analysis on the implementation, technical challenges and economic viability of perovskite solar cells

Book Perovskite Solar Cells Fabrication and Azobenzene Perovskite Synthesis

Download or read book Perovskite Solar Cells Fabrication and Azobenzene Perovskite Synthesis written by Tianyu Liu (Ph. D. in chemistry) and published by . This book was released on 2020 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic-inorganic hybrid perovskites have emerged in recent years as one of the most promising materials for solution-processed electronics and optoelectronics including solar cells, light-emitting diodes (LED) and field-effect transistors (FET). Combining the rigid inorganic framework with soft organic materials, these hybrid perovskites provide the opportunity for investigating organic-inorganic interactions at the molecular scale. This MS thesis summarizes studies on organic-inorganic hybrid lead halide perovskites to date, explores PSCs device fabrications and then conducts the synthesis targeting at a new lower-dimensional perovskite incorporating azobenzene. This thesis is organized by exploring the functions of organic cations ranging from structural building block (chapter 2), PSCs device fabrication progress (chapter 3) to the synthesis of azobenzene perovskite (chapter 4). To start the work, experiments were first repeated following established procedure. Then based on these practices, efforts were contributed to new material synthesis. In this process, challenges and problems were tried to be solved and rationalized by various techniques. Finally, synthetic strategy was proposed and conducted based on the rationalized motivation, proposing potential solutions or producing new chemical compounds for found problems.

Book Hybrid Perovskite Solar Cells

Download or read book Hybrid Perovskite Solar Cells written by Hiroyuki Fujiwara and published by John Wiley & Sons. This book was released on 2022-01-10 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unparalleled coverage of the most vibrant research field in photovoltaics! Hybrid perovskites, revolutionary game-changing semiconductor materials, have every favorable optoelectronic characteristic necessary for realizing high efficiency solar cells. The remarkable features of hybrid perovskite photovoltaics, such as superior material properties, easy material fabrication by solution-based processing, large-area device fabrication by an inkjet technology, and simple solar cell structures, have brought enormous attentions, leading to a rapid development of the solar cell technology at a pace never before seen in solar cell history. Hybrid Perovskite Solar Cells: Characteristics and Operation covers extensive topics of hybrid perovskite solar cells, providing easy-to-read descriptions for the fundamental characteristics of unique hybrid perovskite materials (Part I) as well as the principles and applications of hybrid perovskite solar cells (Part II). Both basic and advanced concepts of hybrid perovskite devices are treated thoroughly in this book; in particular, explanatory descriptions for general physical and chemical aspects of hybrid perovskite photovoltaics are included to provide fundamental understanding. This comprehensive book is highly suitable for graduate school students and researchers who are not familiar with hybrid perovskite materials and devices, allowing the accumulation of the accurate knowledge from the basic to the advanced levels.

Book The Optoelectronic Diversity of Layered Halide Perovskites

Download or read book The Optoelectronic Diversity of Layered Halide Perovskites written by Matthew David Smith and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The path towards emergent photophysics and new technologically desirable physical properties lies through synthesis of new materials. A powerful framework for developing such materials is the idea of hybrids, which contain both organic and inorganic components in a single chemical compound. These two building blocks each offer advantages compared to the other. The ability to design organic molecules with exact precision over atomic connectivity and elemental specificity is unmatched, while inorganic building units contribute increased robustness and intriguing optoelectronic properties. Additionally, the differing reactivities and stabilities of these components dictates simple and mild synthetic conditions such as solution-state self-assembly, allowing easy access to a diverse phase space of possible materials. I have explored how organic-inorganic hybrid materials contain both striking similarities and drastic departures from the optoelectronic properties of their separate components, particularly evident in the family of layered lead-halide hybrids. Much of my focus centers on understanding and controlling the behavior of excitons in the inorganic layers of the two-dimensional lead-halide perovskites. Using a combination of in situ optical spectroscopy and X-ray diffraction techniques, I demonstrated how reversible intercalation of polarizable species such as the molecular dihalogens, such as iodine, can tune the degree of electronic confinement without altering the structure of the inorganic layers in which excitons are confined. More reactive halogens react with the perovskite to perform unusual chemistry with both the organic and inorganic layers. Room-temperature white-light photoluminescence is a rare phenomenon exhibited by certain layered lead-halide perovskites. I initially helped elucidate the photoluminescence mechanism, which I ascribed to the radiative recombination of self-trapped excitons. I further demonstrated that this broad emission is not restricted to a few members of the halide perovskite family, but rather is common to all layered lead-chloride and lead-bromide perovskites, although this emission is highly temperature dependent. With variable-temperature photoluminescence and single-crystal X-ray diffraction, I established correlations between the propensity to exhibit broad photoluminescence at a given temperature and particular octahedral tilts of the lead-bromide octahedra, and provided further support for the self-trapped exciton hypothesis. With additional both static and time-resolved temperature-dependent optical spectroscopies, I found that self-trapped excitons are pervasive in the lead-bromide perovskites, even when the broad photoluminescence is not visible, suggesting a persistent pathway for non-radiative recombination that limits quantum efficiency. Finally, I extended the phenomenon of broadband photoluminescence beyond the layered perovskites to the class of lead-halide hybrids generally. I synthesized and characterized both layered and zero-dimensional lead-bromide hybrids templated by sulfonium-based cations that exhibit room-temperature broad red emission.