Download or read book Ions and Ion Pairs and Their Role in Chemical Reactions written by J. Smid and published by Elsevier. This book was released on 2013-09-03 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state. Organized into 12 chapters, this book begins with an overview of the theory and complications involved in dipole moment measurements in slightly conductive polar solvents. This text then explores the measurement of gas phase ion-molecule equilibria by special spectrometric methods. Other chapters consider the NMR experiments on potassium biphenyl, sodium biphenyl, and rubidium biphenyl, dissolved in different solvents. This book discusses as well the ion pair formation of some cyclic conjugated carbanions and nitranions. The final chapter deals with the information obtained from relaxation measurements on processes such as ionic dissociation, aggregation, and solvent separation. This book is a valuable resource for chemists, organic chemists, and quantum chemists.
Download or read book Organic Reaction Mechanisms 1979 Including Index 1975 1975 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 770 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1979 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1979. The 15th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Download or read book Summaries of Projects Completed in Fiscal Year written by and published by . This book was released on 1979 with total page 718 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Summaries of Projects Completed written by National Science Foundation (U.S.) and published by . This book was released on with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Summaries of Projects Completed in Fiscal Year written by National Science Foundation (U.S.) and published by . This book was released on 1979 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book XXIIIrd International Congress of Pure and Applied Chemistry written by Sam Stuart and published by Elsevier. This book was released on 2013-09-17 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: XXIIIrd International Congress of Pure and Applied Chemistry, Volume 4 contains papers presented at the XXIIIrd International Congress of Pure and Applied Chemistry held in Boston, USA on July 26-30, 1971. This book is organized into two main topics—short-lived intermediates, free radicals and homolytic mechanisms, and ion pair processes. This publication specifically discusses the chemically induced dynamic nuclear polarization, formation of radical anions by the attack of radicals upon anions, and high temperature organic reactions by flash vacuum pyrolysis. The structure-reactivity relationships in the chemistry of aliphatic free radicals, medium effects on radical-radical reactions, and oxidation of alkyl radicals by metal complexes are also described. This text likewise considers the end group association and complexation in anionic polymerization and reversal of singlet and triplet states in aromatic dianions with trigonal symmetry. This compilation is useful to chemists and specialists researching on pure and applied chemistry.
Download or read book Science Technology and the Future written by E. P. Velikhov and published by Elsevier. This book was released on 2013-10-22 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science, Technology and the Future is an analysis of the problems of and prospects for the development of science and technology and their role in society. Drawing on the perspectives of Soviet scientists, this book examines the relation between society and nature as well as the prospects for resolving ecological problems with the aid of science and technology. This book is comprised of 33 chapters and begins with a discussion on the role of science and technology in modern society and their place in the solution of global problems. The axiological and ethical aspects of the development of science and the mechanism of scientific and technical progress, economics, and social development are also considered. The next section deals with concrete questions pertaining to the development of natural and technical sciences and their significance for the future of mankind, with emphasis on the role of science in the development of productive forces; the state of and the prospects for resolving the energy problem; the most important achievements in the leading branches of physics, chemistry, and biology; opportunities for utilizing space research for man's daily needs; oceanology and geology in the year 2000; science and fertility of the soils; materials for the technology of the future; and prospects for the development of automation and man's place in future production. This monograph will be of interest to sociologists, environmentalists, and science policymakers.
Download or read book Progress in Physical Organic Chemistry written by Andrew Streitwieser and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Progress in Physical Organic Chemistry are not only of interest to scientists working in physical organic chemistry, but also scientists working in the many subdisciplines of chemistry in which physical organic chemistry approaches are now applied, such as biochemistry, pharmaceutical chemistry, and materials and polymer science. Among the topics explored in this series are reaction mechanisms; reactive intermediates; combinatorial strategies; novel structures; spectroscopy; chemistry at interfaces; stereochemistry; conformational analysis; quantum chemical studies; structure-reactivity relationships; solvent, isotope and solid-state effects; long-lived charged, sextet or open-shell species; magnetic, non-linear optical and conducting molecules; and molecular recognition.
Download or read book Grants and Awards for Fiscal Year written by National Science Foundation (U.S.) and published by . This book was released on 1978 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Reaction Mechanisms 1972 written by B. Capon and published by John Wiley & Sons. This book was released on 2008-05-23 with total page 691 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1972 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1972. The 8th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Download or read book New Technical Books written by New York Public Library and published by . This book was released on 1980 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Industrial Wastewater Reuse written by and published by . This book was released on 1981 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fourth International Conference on Non Aqueous Solutions written by V. Gutmann and published by Elsevier. This book was released on 2013-10-22 with total page 127 pages. Available in PDF, EPUB and Kindle. Book excerpt: Non-Aqueous Solutions is a collection of papers presented at the Fourth International Conference on the same subject. One paper presents the application of far- and mid-infra-red, Raman, alkali metal n.m.r. and 35C1 n.m.r. techniques to the study of electrolyte solutions in non-aqueous solvents. The paper notes that spectroscopic techniques can be very useful in the elucidation of the structure of electrolyte solutions. Both the vibrational spectroscopy and particularly the alkali metal n.m.r. are very sensitive probes of the immediate chemical environment of ions in solutions. Another paper points out that the energy change associated with the solvation of ions can be represented as the sum of two energy terms; firstly, from the dielectric polarization of the solvent molecules in the continuous dielectric medium; and secondly, due to specific ion-solvent interactions in the inner solvation shells of the ions. The energy contribution of the latter is minimal but can show comparatively large differences in various types of solvents. Another paper describes the chemistry of solutions in highly associated strong protonic acid solvents, including sulphuric acid, oleums, fluorosulfuric acid, and hydrogen fluoride. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the collection truly beneficial.
Download or read book Inorganic Reactions and Methods The Formation of Bonds to C Si Ge Sn Pb Part 3 written by J. J. Zuckerman and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 621 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Reactions and Methods systemizes the discipline of modern inorganic chemistry according to a plan constructed by a council of editorial advisors and consults that include three Nobel laureates (E.O. Fischer, H. Taube, and G. Wilkinson). Rather than producing a collection of unrelated review articles, this series creates a framework that reflects the creative potential of this scientific discipline. In a clear, concise, and highly organized manner, it provides an in-depth treatment of bond formation reactions categorized by element type. The series covers all areas of inorganic chemistry including chemistry of the elements, coordination compounds, donor-acceptor adducts, organometallic, polymer and solid-state material, and compounds relevant to bioinorganic chemistry. A unique index system provides users with several fast options for accessing information on forming any bond type, compound, or reaction. Coverage of both classical chemistry and the frontiers of today's research make this series a valuable reference for years to come.
Download or read book Polymerization of Heterocycles Ring Opening written by S. Penczek and published by Elsevier. This book was released on 2016-02-03 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymerization of Heterocycles (Ring Opening) is a collection of papers presented at the International Symposium on Polymerization of Heterocycles (Ring-Opening) held in Warsaw, Poland on June 23-25, 1975. The first paper describes the developments and physical meaning of ion pairs and higher ionic aggregates. Another paper explains the process of obtaining linear polymers, containing rings in the main chain. The book interprets the various behaviors of polymers that can result in high optical yields of stereoelectivity ratios equal to 8. The text then discusses future trends in aldehyde and carbonyl polymerization, including some problem areas pertaining to failures to homopolymerize or copolymerize tetrachloroethylene oxide. Another paper reviews the elemental reactions of selected combinations of copolymerization; the next paper discuses aspects of the mechanism of nucleophilic opening of epoxide rings through studies of certain kinetics. The book then analyzes the ability of lactams to undergo ring-opening polymerization, which mainly depends on the ring size and on the substitution and presence of heteroatoms in the lactam ring itself. The text also discusses the preparation, properties, and applications of the heterochain polymers in medicine or biologically active materials. The book can provide useful information for biochemists, researchers dealing with inorganic and organic compounds, and scientists working in the fields of chemistry such as synthetic chemistry, as well as polymer engineering.
Download or read book Radical Ionic Systems written by Anders Lund and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.
Download or read book Electrochemistry in Ionic Liquids written by Angel A. J. Torriero and published by Springer. This book was released on 2015-07-17 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids – as opposed to the more commonly used aqueous and organic environments – and the many applications. Readers will find 20 chapters gathered in two books: The first volume critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed The second volumes major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.