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Book Ion Exchange of Cesium by Crystalline Silico titanates

Download or read book Ion Exchange of Cesium by Crystalline Silico titanates written by and published by . This book was released on 1995 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: The crystalline silico-titanates developed by the Department of Chemical Engineering at Texas A & M University, Sandia National Laboratories and UOP exhibits extremely high ion exchange selectivity for removing cesium from aqueous defense wastes. Based on experimental data and structure studies, a competitive ion exchange model was proposed to predict the ion exchange performance in different simulated waste solutions. The predicted distribution coefficients were within 10% of the experimentally determined values.

Book Ion Exchange of Cesium by Crystalline Silico titanates

Download or read book Ion Exchange of Cesium by Crystalline Silico titanates written by Zhixin Zheng and published by . This book was released on 1995 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Ion Exchange Kinetics of Cesium for Various Reaction Designs Using Crystalline Silicotitanate UOP IONSIV IE 911

Download or read book Ion Exchange Kinetics of Cesium for Various Reaction Designs Using Crystalline Silicotitanate UOP IONSIV IE 911 written by Sung Hyun Kim and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Through collaborative efforts at Texas A & M University and Sandia National Laboratories, a crystalline silicotitanate (CST), which shows extremely high selectivity for radioactive cesium removal in highly concentrated sodium solutions, was synthesized. The effect of hydrogen peroxide on a CST under cesium ion exchange conditions has been investigated. The experimental results with hydrogen peroxide showed that the distribution coefficient of cesium decreased and the tetragonal phase, the major component of CST, slowly dissolved at hydrogen peroxide concentrations greater than 1 M.A simple and novel experimental apparatus for a single-layer ion exchange column was developed to generate experimental data for estimation of the intraparticle effective diffusivity. A mathematical model is presented for estimation of effective diffusivities for a single-layer column of CST granules. The intraparticle effective diffusivity for Cs was estimated as a parameter in the analytical solution. By using the least square method, the effective diffusivities of 1.56 ł 0.14 x 10-11 m2/s and 0.68 ł 0.09x 10-11 m2/s, respectively, were obtained. The difference in the two values was due to the different viscosities of the solutions. A good fit of the experimental data was obtained which supports the use of the homogeneous model for this system. A counter-current ion exchange (CCIX) process was designed to treat nuclear waste at the Savannah River Site. A numerical method based on the orthogonal collocation method was used to simulate the concentration profile of cesium in the CCIX loaded with CST granules. To maximize cesium loading onto the CST and minimize the volume of CST, two design cases of a moving bed, where the fresh CST is pulsed into the column at certain periods or at certain concentration of cesium, were investigated. Simulation results showed that cesium removal behavior in the pilot-scale test of CCIX experiment, where the column length is 22 ft and the CST is pulsed 1 ft in every 24 hours, was well predicted by using the values of the effective diffusivities of 1.0 to 6.0 x 10-11 m2/s.

Book Small Column Ion Exchange Analysis for Removal of Cesium from SRS Low Curie Salt Solutions Using Crystalline Silicotitanate CST Resin

Download or read book Small Column Ion Exchange Analysis for Removal of Cesium from SRS Low Curie Salt Solutions Using Crystalline Silicotitanate CST Resin written by and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Savannah River Technology Center (SRTC) researchers modeled ion exchange removal of cesium from dissolved salt waste solutions. The results assist in evaluating proposed configurations for an ion exchange process to remove residual cesium from low curie waste streams. A process for polishing (i.e., removing small amounts) of cesium may prove useful should supernate draining fail to meet the Low Curie Salt (LCS) target limit of 0.1 Ci of Cs-137 per gallon of salt solution. Cesium loading isotherms and column breakthrough curves for Low Curie dissolved salt solutions were computed to provide performance predictions for various column designs.

Book Science and Technology for Disposal of Radioactive Tank Wastes

Download or read book Science and Technology for Disposal of Radioactive Tank Wastes written by Wallace W. Shulz and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radioactive wastes resulting from over 40 years of production of nuclear weapons in the U. S. are currently stored in 273 underground tanks at the U. S. Department of Energy Hanford site, Idaho National Engineering and Environmental Laboratory, Oak Ridge Reservation, and Savannah River site. Combined, tanks at these sjtes contain approximately 94,000,000 gallons of waste in a variety of forms including liquid, concrete-like salt cake, and various sludges. More than 730,000,000 curies of several radioactive isotopes are present in the underground tanks. Certainly, one of the greatest challenges facing the U. S. Department of Energy is how to characterize, retrieve, treat, and immobilize the great variety of tank wastes in a safe, timely, and cost-effective manner. For several years now, the U. S. Department of Energy has initiated and sponsored scientific and engineering studies, tests, and demonstrations to develop the myriad of technologies required to dispose of the radioactive tank wastes. In recent times, much of the Department of Energy R&D activities concerning tank wastes have been closely coordinated and organized through the Tanks Focus Area (IF A); responsibility for technical operations of the TF A has been assigned to the Pacific Northwest National Laboratory.

Book Nuclear Waste Management Facilities

Download or read book Nuclear Waste Management Facilities written by Rehab O Abdel Rahman and published by Elsevier. This book was released on 2024-02-24 with total page 558 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear Waste Management Facilities: Advances, Environmental Impacts, and Future Prospects examines best practices and recent trends in improving nuclear safety and reducing the negative environmental impacts of nuclear waste. With strong emphasis on regulatory requirements, this reference is essential for designing new integrated waste management practices, using lessons learned from historical and current practices. Divided into three key sections, Part One introduces the reader to the safety and environmental impacts of the nuclear industry. Part Two reviews recent technological and methodological approaches to enhancing safety, as well as reducing the carbon footprint of both individual processes and integrated facilities. Topics covered include waste processing, transmutation and decommissioning. Part Three consider potential management schemes for special waste from innovative sources, and wastes that contain emerging contaminants, including waste recycling opportunities. Nuclear Waste Management Facilities: Advances, Environmental Impacts, and Future Prospects is a crucial tool needed to implement the safest and most environmentally considerate best practices within nuclear waste management facilities. - Presents recent approaches used to assess and improve the safety and reduce the environmental impacts of nuclear waste management facilities - Offers technical guidance to support the development and defense of the environmental impact assessment (EIA) and Safety Cases to support the waste management facilities licensing throughout their lifecycles - Highlights the future perspectives for wastes produced from innovative reactors and wastes containing emerging contaminants, and recycling opportunities

Book Research and Development on a Salt Processing Alternative for High Level Waste at the Savannah River Site

Download or read book Research and Development on a Salt Processing Alternative for High Level Waste at the Savannah River Site written by National Research Council and published by National Academies Press. This book was released on 2001-09-03 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. Department of Energy (DOE) is nearing a decision on how to process 30 million gallons of high-level radioactive waste salt solutions at the Savannah River Site in South Carolina to remove strontium, actinides, and cesium for immobilization in glass and eventual shipment to a geologic repository. The department is sponsoring research and development (R&D) work on four alternative processes and plans to use the results to make a downselection decision in a June 2001 time frame. The DOE requested that the National Research Council help inform this decision by addressing the following charge: evaluate the adequacy of the criteria that will be used by the department to select from among the candidate processes under consideration; evaluate the progress and results of the research and development work that is being undertaken on these candidate processes; and assess whether the technical uncertainties have been sufficiently resolved to proceed with downsizing the list of candidate processes. Responses to the last two points are provided in this report. Research and Development on a Salt Processing Alternative for High-Level Waste at the Savannah River Site focuses exclusively on the technical issues related to the candidate processes for radionuclide removal from high-level waste salt solutions at SRS. The committee's interim report served as a response to the first point of this charge, and may be read in Appendix B. In that report, the committee found that DOE's proposed criteria are an acceptable basis for selecting among the candidate processes under consideration, but that the criteria should not be implemented in a way that relies on a single numerical "total score."

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1994-06 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Radioactive Waste Management

Download or read book Radioactive Waste Management written by and published by . This book was released on 1996-05 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: