Download or read book Introducing Functionality to Poly arylene Ether s Via Modification of Diphenyl Sulfone Type Monomers written by Zahida Humayun and published by . This book was released on 2020 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of poly(arylene ether)s, with a pendent aryl iodide, was achieved via nucleophilic aromatic substitution (NAS) polycondensation of DI-DFDPS monomer. The platform diiodo-difluorodiphenyl sulfone monomer, DFDPS-DI (3), was prepared in one-step, via EAS chemistry. Structural characterization was provided by NMR spectroscopy, GC/MS, and elemental analysis. As "pre" approach didn't work here, so "post" approach was used to synthesize N-heterocycle functionalized copolymers. The DI-copolymers were subjected to copper-catalyzed C-N coupling reaction with carbazole, phenoxazine, and indole and the syntheses of chromophore based copolymer were successfully carried out. A series of PAEs containing carbazole, phenoxazine, and indole substituents were synthesized and characterized. The copolymers were characterized by a combination of NMR spectroscopy, UV/Vis spectroscopy. DI-copolymers displayed had sufficient molecular weight (Mn) and thermal stability with 5% weight loss temperature (Tg) above 388 0C and glass transition temperature, Tg, value above 193 0C. Optical analyses provided that all modified copolymer materials emitted in the light blue region.

Download or read book Synthesis and Characterization of Functionalized Poly arylene Ether Sulfone s Using ClickChemistry written by Kavitha Neithikunta and published by . This book was released on 2016 with total page 75 pages. Available in PDF, EPUB and Kindle. Book excerpt: Poly(arylene ether sulfone)s with pendent aryl iodide group was successfully synthesized via Nucleophilic aromatic polycondensation of 1-(3,5-difluorophenyl sulfonyl)-4-iodobenzene using 4,4{u2019}-difluorodiphenylsulfone (DFDPS) and Bisphenol A in the ratio 25:75:100. Iodo monomer was prepared by reacting 3,5-difluorodiphenyl sulfone with N-iodo succinimide (NIS). Using GC/MS and NMR spectroscopy, the quantitative analysis was done to this monomer. Modification was done to iodo copolymer using sodium azide and copper sulfate as catalyst to form azide copolymer. Further modification of the azide copolymer to triazole copolymers via Click Chemistry using different alkynes such as 1-octyne, phenyl acetylene, propargyl alcohol and acetylenedicarboxylic acid. Polymers characterization was done using 1H, 13C NMR, IR spectroscopy and SEC. The highest molecular weight (Mw) was found to be 19,033 Da with a PDI 3.0 for iodo copolymer and the least was found to be 6,888 with a PDI 2.5 for acetylenedicarboxylic acid derivative copolymer. Thermal analysis of polymers was done using TGA and DSC. The Td5% values were ranging from 260{u00BA} to 476{u00BA}. The highest Tg was 191{u00BA} for phenyl derivative copolymer and the least was 174{u00BA} for alkyl derivative copolymer. TGA was not ran on azide copolymer as it may contain explosive copper azide traces. IR spectroscopy was used to confirm the structures of azide copolymer, propargyl alcohol derivative and acetylenedicarboxylic acid derivative copolymers.

Download or read book Facile Synthesis of Functionalized Poly arylene Ether Sulfone s written by Mehmet Tatli and published by . This book was released on 2012 with total page 75 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of poly(arylene ether sulfone)s, with a pendant aryl iodide, was achieved via nucleophilic aromatic substitution (NAS) polycondensation of 3-iodo-3',5'-difluoro-diphenylsulfone (2) with Bisphenol-A. Monomer 2 was prepared by the reaction of 3, 5-difluorodiphenylsulfone with N-iodosuccinimide (NIS). Model reactions indicated that the iodo group was stable to NAS conditions. Both GC/MS analysis and NMR spectroscopy indicated quantitative displacement of the two fluorine atoms while the iodo group remained untouched. Furthermore, the modification of the iodo polymer was achieved via Suzuki-Miyaura cross-coupling reaction with phenyl, naphthyl, and phenylacetyl boronic acids. The thermal properties of the polymers were evaluated via DSC and TGA. The iodo polymer possessed a glass transition temperature, Tg, of 144 °C while the corresponding phenyl derivative displayed a slight decrease in Tg to 131 °C. The much bulkier naphthyl derivative provided a higher Tg of 150 °C. The more polar acetyl derivative showed a much higher Tg of 165 °C. All the polymers exhibited high Td-5% values between 400 °C and 500 °C. Moreover, conversion of the iodo moiety to an azide group was achieved by using sodium azide in a straightforward manner with the structure being confirmed by IR and NMR spectroscopies. In addition, the iodo group was replaced with a phenyl group, at the monomer stage, in order to prove that the system not only could be functionalized via "post" but also "pre" modification processes.

Download or read book Exploration of Gradient type Poly arylene Ether s Via an Abb Monomer System written by Alex V. Dolgov and published by . This book was released on 2008 with total page 53 pages. Available in PDF, EPUB and Kindle. Book excerpt: Evidence shows that a gradient like copolymer can be synthesized using nucleophilic aromatic substitution, NAS, chemistry. Using the 4-chloro-3-fluoro-4'hydroxydiphenylsulfone monomer, 5, it is possible to control the ratios of the leaving groups, in this case the fluorine and the chlorine, with the right solvent and temperature. Alternating the temperatures will alter the substitution of the leaving groups, thus forming a polymer backbone of gradient characteristics. Initial reactions to determine the relative rates of displacement of the chlorine and fluorine atoms were carried out using a model compound, 1, which possessed the chlorine and fluorine leaving groups, but not the phenol group. Determining the pattern of leaving group substitution was characterized using 1H and 13C NMR spectroscopy.

Download or read book Modifiable Poly arylene Ether s and Hyperbranched Poly esters written by Brian Scott Werry and published by . This book was released on 2007 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: Two different polymer systems have been studied in regards to their potential for functionalization to introduce new characteristics to the polymer. The first polymer system is a poly(arylene ether) with a truly pendant sulfone group from the monomer 3,5-difluorodiphenylsulfone. The work entails incorporating a bromine moiety onto the monomer for the versatile ability to bring in functional groups prior to or post the polymerization. The introduction of bromine onto the pendant ring had the best results from electrophilic bromine addition using N-bromosuccinimide in a mixture of sulfuric acid and acetic acid (80:20) yielding 76% of the desired material. Incorporation of the bromine moiety did not interfere with the nucleophilic aromatic substitution reaction utilized in the polymerization and modification was shown to proceed smoothly both prior and post polymerization. The second project involved the study and production of a poly(ester) hyperbranched system from glycerol and fumaric acid. These hyperbranched polymers were prepared using an A2 + B3 approach in a bulk synthesis. The study involves varying the molar ratio of A2 to B3 and temperature to control the polymerization and avoid gelation while pushing the polymerization to larger molecular weights. The two monomers bring the characteristic of biocompatibility with them into the polymer. In addition, the fumaric acid monomer unit brings an alkene bond available for modification. Average molecular weights achieved were around 5,000 daltons. Obtained PDI values were as low as 4.6, and DB values ranged from 0.26 to 0.38. Analysis on new compounds and polymers was done by NMR spectroscopy, GC/MS, and size exclusion chromatography where applicable.

Download or read book Routes to N heterocycle Functionalized Poly arylene Ether Sulfone s written by Jesse L. Picker and published by . This book was released on 2014 with total page 71 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of poly(arylene ether sulfone)s, with a pendant aryl iodide, was achieved via nucleophilic aromatic substitution (NAS) polycondensation of 3-iodo-3’,5’-difluoro-diphenylsulfone. The polymer series was subjected to amino acid promoted, copper catalyzed coupling reactions with various N-heterocycles. The resulting polymers became crosslinked and insoluble in any organic solvents. The iodo monomer was then subjected to an amino acid promoted, copper catalyzed coupling reaction with carbazole. The successful synthesis of 3’-(9-carbazole) 3,5-difluorodiphenylsulfone is reported. A series of PAES containing a carbazole substituent were synthesized and characterized. The polymers were characterized by a combination of NMR spectroscopy, SEC, TGA, DSC, UV-Vis spectroscopy. NMR spectroscopy was used to confirm that the carbazole monomer was successfully polymerized. SEC was used to find polymer molecular weights and dispersity. Several polymers in the series showed high thermal stability, and formed tough flexible films when solution cast from N-methyl pyrrolidinone.

Download or read book Synthetic Methods in Step Growth Polymers written by Martin E. Rogers and published by John Wiley & Sons. This book was released on 2003-08-08 with total page 619 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alles über die Stufenwachstums-Polymerisation - von Syntheseverfahren und Reinigungsmethoden bis zur Charakterisierung der Produkte - finden Sie in diesem Buch. - bietet einen Ausblick auf zukünftige Trends - mit historischen Informationen - erläutert die Klassifikation von Stufenwachstumspolymeren

Download or read book Synthesis and Characterization of Hyperbranched Poly arylene Ether Sulfone s Via AB2 and ABB Monomer Routes written by Patrick Himmelberg and published by . This book was released on 2005 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Encyclopedia of Polymeric Nanomaterials written by Shiro Kobayashi and published by Springer. This book was released on 2015-06-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last few years, nanoscience and nanotechnology have been the focus of significant research attention, both from academia and industry. This sustained focus has in-turn driven the interdisciplinary field of material science research to the forefront of scientific inquiry through the creation and study of nanomaterials. Nanomaterials play an important role in the development of new materials as they can be used to influence and control physical properties and specific characteristics of other materials. Nanostructured materials that have been created include nanoparticles, nanocapsules, nanoporous materials, polymer multi-layers to name a few. These are increasingly used across applications as diverse as automotive, environment, energy, catalysis, biomedical, pharmaceutical, and polymer industries. The Encyclopedia of Polymeric Nanomaterials (EPN) intends to be a comprehensive reference work on this dynamic field studying nanomaterials within the context of the relationship between molecular structure and the properties of polymeric materials. Alphabetically organized as an encyclopedic Major Reference Work, EPN will cover the subject along multiple classification axes represented by name, source, properties, function, and structures or even processes, applications and usage. The underlying themes of the encyclopedia has been carefully identified to be based not just on material-based and function-based representation but also on structure- and process-based representation. The encyclopedia will have an exclusive focus on polymeric nanomaterials (for e.g., nanoceramics, nanocomposites, quantum dots, thin films) and will be a first of its kind work to have such an organization providing an overview to the concepts, practices and applications in the field. The encyclopedia intends to cover research and development work ranging from the fundamental mechanisms used for the fabrication of polymeric nanomaterials to their advanced application across multiple industries.

Download or read book Comprehensive Organic Functional Group Transformations II written by and published by Elsevier. This book was released on 2004-12-16 with total page 9196 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Organic Functional Group Transformations II (COFGT-II) will provide the first point of entry to the literature for all scientists interested in chemical transformations. Presenting the vast subject of organic synthesis in terms of the introduction and interconversion of all known functional groups, COFGT-II provides a unique information source documenting all methods of efficiently performing a particular transformation. Organised by the functional group formed, COFGT-II consists of 144 specialist reviews, written by leading scientists who evaluate and summarise the methods available for each functional group transformation. Also available online via ScienceDirect – featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. By systematically treating each functional group in turn the work also identifies what is not known, thus pointing the way to new research areas Follows the systematic layout of the successful 1995 COFGT reference work, based on the arrangement and bonding of hetero-atoms around a central carbon atom The work will save researchers valuable time in their research as each chapter is written by experts who have critically read and reviewed the literature and presented the best methods of forming every known functional group

Download or read book High Performance Polymers and Engineering Plastics written by Vikas Mittal and published by John Wiley & Sons. This book was released on 2011-09-09 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes advances in synthesis, processing, and technology of environmentally friendly polymers generated from renewable resources. With contents based on a wide range of functional monomers and contributions from eminent researchers, this volume demonstrates the design, synthesis, properties and applications of plant oil based polymers, presenting an elaborate review of acid mediated polymerization techniques for the generation of green polymers. Chemical engineers are provided with state-of-the-art information that acts to further progress research in this direction.

Download or read book Functionalized Polysulfones written by Silvia Ioan and published by CRC Press. This book was released on 2015-04-24 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Functionalized Polysulfones: Synthesis, Characterization, and Applications focuses on polysulfones and their derivatives, which are widely used as functional materials in the biochemical, industrial, and medical fields due to their structural and physical characteristics, such as good optical properties, high thermal and chemical stability, mechani

Download or read book Comprehensive Membrane Science and Engineering written by Enrico Drioli and published by Newnes. This book was released on 2010-07-09 with total page 1528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Membrane Science and Engineering, Four Volume Set covers all aspects of membrane science and technology - from basic phenomena to the most advanced applications and future perspectives. Modern membrane engineering is critical to the development of process-intensification strategies and to the stimulation of industrial growth. The work presents researchers and industrial managers with an indispensable tool toward achieving these aims. Covers membrane science theory and economics, as well as applications ranging from chemical purification and natural gas enrichment to potable water Includes contributions and case studies from internationally recognized experts and from up-and-coming researchers working in this multi-billion dollar field Takes a unique, multidisciplinary approach that stimulates research in hybrid technologies for current (and future) life-saving applications (artificial organs, drug delivery)

Download or read book PEM Electrolysis for Hydrogen Production written by Dmitri Bessarabov and published by CRC Press. This book was released on 2016-02-03 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: An ever-increasing dependence on green energy has brought on a renewed interest in polymer electrolyte membrane (PEM) electrolysis as a viable solution for hydrogen production. While alkaline water electrolyzers have been used in the production of hydrogen for many years, there are certain advantages associated with PEM electrolysis and its relevan

Download or read book Advanced Nanomaterials for Membrane Synthesis and Its Applications written by Woei Jye Lau and published by Elsevier. This book was released on 2018-11-21 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Nanomaterials for Membrane Synthesis and Its Applications provides the academic and industrial communities the most up-to-date information on the latest trends in membrane nanomaterials and membrane nanotechnology used in wastewater treatment, environmental technology and energy. The rapid advances in nanomaterials and nanotechnology development over the past decade have resulted in significant growth of the membrane business for various industrial processes, particularly in nanotechnology-based membrane processes. While membrane technology is increasingly being used for liquid and gas separations, it has great potential in a variety of additional applications. As the worldwide academic community has a strong interest in advanced membrane processes, particularly membrane nanotechnology for specific separations, this book provides a timely update on the topic. Presents a unique focus on the use of advanced nanomaterials in membrane fabrication/modification, and in the description of membrane nanotechnologies, such as nanofiltration, thin film nanocomposites and nanofibers for various applications Describes next generation membranes, providing first resource details on the development and commercialization stages of these new membranes Represents the state-of-the-art on the use of nanomaterials in membrane science

Download or read book Comprehensive Membrane Science and Engineering written by Enrico Drioli and published by Elsevier. This book was released on 2017-07-20 with total page 1709 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Membrane Science and Engineering, Second Edition, Four Volume Set is an interdisciplinary and innovative reference work on membrane science and technology. Written by leading researchers and industry professionals from a range of backgrounds, chapters elaborate on recent and future developments in the field of membrane science and explore how the field has advanced since the previous edition published in 2010. Chapters are written by academics and practitioners across a variety of fields, including chemistry, chemical engineering, material science, physics, biology and food science. Each volume covers a wide spectrum of applications and advanced technologies, such as new membrane materials (e.g. thermally rearranged polymers, polymers of intrinsic microporosity and new hydrophobic fluoropolymer) and processes (e.g. reverse electrodialysis, membrane contractors, membrane crystallization, membrane condenser, membrane dryers and membrane emulsifiers) that have only recently proved their full potential for industrial application. This work covers the latest advances in membrane science, linking fundamental research with real-life practical applications using specially selected case studies of medium and large-scale membrane operations to demonstrate successes and failures with a look to future developments in the field. Contains comprehensive, cutting-edge coverage, helping readers understand the latest theory Offers readers a variety of perspectives on how membrane science and engineering research can be best applied in practice across a range of industries Provides the theory behind the limits, advantages, future developments and failure expectations of local membrane operations in emerging countries

Download or read book Click Polymerization written by Anjun Qin and published by Royal Society of Chemistry. This book was released on 2018-08-28 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Click Polymerization has been edited by world renowned experts and provides an authoritative guide to this reaction type.