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Book Infrared Laser Absorption Spectroscopy of Jet cooled Biomolecules and Water Clusters

Download or read book Infrared Laser Absorption Spectroscopy of Jet cooled Biomolecules and Water Clusters written by Ryan Patrick McLaughlin and published by . This book was released on 1999 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Infrared Cavity Ringdown Laser Absorption Spectroscopy of Jet cooled Clusters

Download or read book Infrared Cavity Ringdown Laser Absorption Spectroscopy of Jet cooled Clusters written by Robert Allen Provencal and published by . This book was released on 1999 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book American Doctoral Dissertations

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1999 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Laser Spectroscopy of Jet cooled Organic Molecules and Van Der Waals Clusters

Download or read book Laser Spectroscopy of Jet cooled Organic Molecules and Van Der Waals Clusters written by James Walter Hager and published by . This book was released on 1985 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Infrared Diode Laser Spectroscopy of Jet Cooled Molecules

Download or read book Infrared Diode Laser Spectroscopy of Jet Cooled Molecules written by Anthony Joseph Bednar and published by . This book was released on 1998 with total page 86 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Dissertation Abstracts International

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2004 with total page 806 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Laser Photodissociation and Spectroscopy of Mass separated Biomolecular Ions

Download or read book Laser Photodissociation and Spectroscopy of Mass separated Biomolecular Ions written by Nicolas C. Polfer and published by Springer Science & Business Media. This book was released on 2013-09-03 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: This lecture notes book presents how enhanced structural information of biomolecular ions can be obtained from interaction with photons of specific frequency - laser light. The methods described in the book "Laser photodissociation and spectroscopy of mass-separated biomolecular ions" make use of the fact that the discrete energy and fast time scale of photoexcitation can provide more control in ion activation. This activation is the crucial process producing structure-informative product ions that cannot be generated with more conventional heating methods, such as collisional activation. The book describes how the powerful separation capabilities and sensitivity of mass spectrometry (MS) can be combined with the structural insights from spectroscopy by measuring vibrational and electronic spectra of trapped analytes. The implementation of laser-based photodissociation techniques in MS requires basic knowledge of tunable light sources and ion trapping devices. This book introduces the reader to key concepts and approaches in molecular spectroscopy, and the light sources and ion traps employed in such experiments. The power of the methods is demonstrated by spectroscopic interrogation of a range of important biomolecular systems, including peptides, proteins, and saccharides, with laser light in the ultraviolet-visible, and infrared range. The book "Laser photodissociation and spectroscopy of mass-separated biomolecular ions" is an indispensable resource for students and researchers engaged or interested in this emerging field. It provides the solid background of key concepts and technologies for the measurements, discusses state-of-the-art experiments, and provides an outlook on future developments and applications.

Book Infrared Vibrational Predissociation Spectroscopy of Water Clusters by the Crossed Laser Molecular Beam Technique

Download or read book Infrared Vibrational Predissociation Spectroscopy of Water Clusters by the Crossed Laser Molecular Beam Technique written by and published by . This book was released on 1981 with total page 75 pages. Available in PDF, EPUB and Kindle. Book excerpt: Water clusters formed in a molecular beam are predissociated by tunable, pulsed, infrared radiation in the frequency range 2900~3750 cm−1. The recoiling fragments are detected off axis from the molecular beam using a rotatable mass spectrometer. Arguments are presented which show that the measured frequency dependent signal at a fixed detector angle is proportional to the absorption spectrum of the clusters. It is found that the spectra of clusters containing three or more water molecules are remarkably similar to the liquid phase spectrum. Dynamical information on the predissociation process is obtained from the velocity distribution of the fragments. An upper limit to the excited vibrational state lifetime of ~1 microsecond is observed for the results reported here. The most probable dissociation process concentrates the available excess energy into the internal motions of the fragment molecules. Both the time scale and translational energy distribution are consistent with the qualitative predictions of current theoretical models for cluster predissociation. From adiabatic dissociation trajectories and Monte Carlo simulations it is seen that the strong coupling present in the water polymers probably invalidates the simpler "diatomic" picture formulations of cluster predissociation. Instead, the energy can be extensively shared among the intermolecular motions in the polymer before dissociation. Comparison between current intermolecular potentials describing liquid water and the observed frequencies is made in the normal mode approximation. The inability of any potential to predict the gross spectral features (the number of bands and their observed frequency shift from the gas phase monomer) suggests that substantial improvement in the potential energy functions are possible, but that more accurate methods of solving the vibrational wave equation are necessary before a proper explanation of the spectral fine structure is possible. The observed differences between the dimer and larger polymers (trimer-hexamer) indicate a dramatic change in the hydrogen bonding, which is best explained as arising from the non-additive effects present when a water molecule is both donating and accepting a hydrogen bond. This difference between dimer and trimer also rationalizes the previous disagreement between potential functions based on condensed phase properties (where the water molecule is interacting with multiple neighbors) and those fit to imperfect gas or dimer properties which sample only the isolated pair potential. The data support an interpretation of the hydrogen bonded O-H stretching fundamental region as arising from a homogeneous broadening (not necessarily a result of the predissociation) whose width is characteristic of the hydrogen bond itself and not the sum of distinct bonding geometries. This is different from some previous theories of the water infrared absorption spectrum which assign each band to water molecules bound to different numbers of neighboring molecules.

Book Tunable Far infrared Laser Spectroscopy of Clusters

Download or read book Tunable Far infrared Laser Spectroscopy of Clusters written by Charles Albert Schmuttenmaer and published by . This book was released on 1991 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Infrared Laser Spectroscopy of Atomic Carbon and Carbon Clusters

Download or read book Infrared Laser Spectroscopy of Atomic Carbon and Carbon Clusters written by Andrew Lloyd Cooksy and published by . This book was released on 1990 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Infrared Laser Absorption Spectroscopy of Fast Ion Beams

Download or read book Infrared Laser Absorption Spectroscopy of Fast Ion Beams written by Eric Roll Keim and published by . This book was released on 1992 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Cavity ringdown Spectroscopy

Download or read book Cavity ringdown Spectroscopy written by Kenneth W. Busch and published by . This book was released on 1999 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cavity-ringdown spectroscopy is an emerging method for making high sensitivity absorption measurements with gas-phase samples. This volume, the first devoted to the method, covers the history, theory, and numerous applications. Written by leaders in the field, it is a comprehensive guide to current methods and ongoing research.

Book Directory of Graduate Research

Download or read book Directory of Graduate Research written by American Chemical Society. Committee on Professional Training and published by . This book was released on 2005 with total page 1932 pages. Available in PDF, EPUB and Kindle. Book excerpt: Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.