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Book Infrared and Visible Laser Double Resonance Studies of Vibrational Energy Transfer Processes in Polyatomic Molecules   Chromyl Chloride Solutions

Download or read book Infrared and Visible Laser Double Resonance Studies of Vibrational Energy Transfer Processes in Polyatomic Molecules Chromyl Chloride Solutions written by and published by . This book was released on 1991 with total page 21 pages. Available in PDF, EPUB and Kindle. Book excerpt: A study of the spectroscopy of chromyl chloride (CrO2Cl2) in dilute solutions has been initiated. A discussion is given of its spectra and emission bands. 17 refs, 5 figs, 1 tab. (DLC).

Book Infrared and Visible Laser Double Resonance Studies of Vibrational Energy Transfer Processes in Polyatomic Molecules  Final Report  June 15  1988  June 14  1991

Download or read book Infrared and Visible Laser Double Resonance Studies of Vibrational Energy Transfer Processes in Polyatomic Molecules Final Report June 15 1988 June 14 1991 written by and published by . This book was released on 1991 with total page 21 pages. Available in PDF, EPUB and Kindle. Book excerpt: A study of the spectroscopy of chromyl chloride (CrO2Cl2?) in dilute solutions has been initiated. A discussion is given of its spectra and emission bands. 17 refs, 5 figs, 1 tab. (DLC).

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1992 with total page 806 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Overtone Vibration laser Double Resonance Measurements of Vibrational Energy Transfer Rates and Mechanisms in HF and DF

Download or read book Overtone Vibration laser Double Resonance Measurements of Vibrational Energy Transfer Rates and Mechanisms in HF and DF written by Jeanne Marie Robinson and published by . This book was released on 1985 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Studies of Energy Transfer and Selective Chemical Reaction Using Tunable IR Radiation

Download or read book Studies of Energy Transfer and Selective Chemical Reaction Using Tunable IR Radiation written by Ian W. M. Smith and published by . This book was released on 1982 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tunable infrared lasers have been used to excite selected vibrational levels of molecules for kinetic studies. It was demonstrated that stimulated electronic Raman scattering (SERS) in Cs vapour provides a useful tunable source between 2.7 and 3.3 micrometers. Later this source was supplanted by an optical parametric oscillator (OPO) supplying high energy pulses (1-5 mJ) over a wider range (1.5-3.6 micrometers). Both sources have been used in detailed studies of the relaxation of HCN. When finished these experiments will yield the most complete picture of relaxation rates and pathways in any simple polyatomic molecule. In addition, new direct methods have yielded rates of relaxation of (a) high vibrational levels in HF, and (b) NO and OH in collision with other free radicals. Finally, some preliminary work on selective laser-induced chemistry both in the gas-phase and in low temperature matrices has been carried out. (Author).

Book Molecular Vibrations

    Book Details:
  • Author : E. Bright Wilson
  • Publisher : Courier Corporation
  • Release : 2012-05-11
  • ISBN : 0486137155
  • Pages : 418 pages

Download or read book Molecular Vibrations written by E. Bright Wilson and published by Courier Corporation. This book was released on 2012-05-11 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pedagogical classic and essential reference focuses on mathematics of detailed vibrational analyses of polyatomic molecules, advancing from application of wave mechanics to potential functions and methods of solving secular determinant.

Book Vibrational Energy Flow in Electronically Excited Polyatomic Molecules

Download or read book Vibrational Energy Flow in Electronically Excited Polyatomic Molecules written by David Bates Moss and published by . This book was released on 1986 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Vibrational Energy Transfer Processes in Gaseous Mixtures Investigated by the Laser Induced Vibrational Fluorescence Technique

Download or read book Vibrational Energy Transfer Processes in Gaseous Mixtures Investigated by the Laser Induced Vibrational Fluorescence Technique written by Barbara M. Hopkins and published by . This book was released on 1974 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Vibrational Spectra of Polyatomic Molecules

Download or read book Vibrational Spectra of Polyatomic Molecules written by Lazarʹ Matveevich Sverdlov and published by . This book was released on 1973 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Double Resonance Spectroscopy of Multiple photon Excited Molecules

Download or read book Double Resonance Spectroscopy of Multiple photon Excited Molecules written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A diode-infrared laser-double resonance investigation was conducted of the initial photon absorption step (.nu./sub 3/ reverse arrow O) in SF/sub 6/. A variety of double resonance effects were observed: two-level, three-level, and four-level. It is concluded that diode-infrared laser double resonance can be used to study multiple photon excitation in polyatomic molecules and vibrational levels above the first excited state onto the quasi-continuum. 4 figs. (DLC).

Book Index to American Doctoral Dissertations

Download or read book Index to American Doctoral Dissertations written by and published by . This book was released on 1974 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Dynamics of Vibrational Energy Relaxation and Bimolecular Reactions in Solution

Download or read book The Dynamics of Vibrational Energy Relaxation and Bimolecular Reactions in Solution written by Maximilian Morrison Heckscher and published by . This book was released on 2002 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Vibrational Spectra and Structure of Polyatomic Molecules

Download or read book Vibrational Spectra and Structure of Polyatomic Molecules written by Ta-you Wu and published by . This book was released on 1946 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Vibrational Relaxation and Energy Transfer of Matrix Isolated HCl and DCl

Download or read book Vibrational Relaxation and Energy Transfer of Matrix Isolated HCl and DCl written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Vibrational kinetic and spectroscopic studies have been performed on matrix-isolated HCl and DCl between 9 and 20 K. Vibrational relaxation rates for v = 2 and v = 1 were measured by a tunable infrared laser-induced, time-resolved fluorescence technique. In an Ar matrix, vibrational decay times are faster than radiative and it is found that HCl relaxes about 35 times more rapidly than CCl, in spite of the fact that HCl must transfer more energy to the lattice than DCl. This result is explained by postulating that the rate-determining step for vibrational relaxation produces a highly rotationally excited guest in a V yield R step; rotational relaxation into lattice phonons follows rapidly. HCl v = 1, but not v = 2, excitation rapidly diffuses through the sample by a resonant dipole-dipole vibrational energy transfer process. Molecular complexes, and in particular the HCl dimer, relax too rapidly for direct observation, less than or approximately 1 .mu.s, and act as energy sinks in the energy diffusion process. The temperature dependence for all these processes is weak--less than a factor of two between 9 and 20 K. Vibrational relaxation of HCl in N2 and O2 matrices is unobservable, presumably due to rapid V yield V transfer to the host. A V yield R binary collision model for relaxation in solids is successful in explaining the HCl(DCl)/Ar results as well as results of other experimenters. The model considers relaxation to be the result of ''collisions'' due to molecular motion in quantized lattice normal modes--gas phase potential parameters can fit the matrix kinetic data.