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Book In Situ Investigation of the Surface Films Fomred on Iron nickel chromium Alloys in High Temperature Water and Their Relevance to Stress Corrosion Cracking

Download or read book In Situ Investigation of the Surface Films Fomred on Iron nickel chromium Alloys in High Temperature Water and Their Relevance to Stress Corrosion Cracking written by J. L. Nelson and published by . This book was released on 2000 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book An In situ SERS Investigation of the Passive Film on Stainless Steel at High Temperature in Pressurized Water

Download or read book An In situ SERS Investigation of the Passive Film on Stainless Steel at High Temperature in Pressurized Water written by Christopher Shigeki Kumai and published by . This book was released on 2000 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book An In situ Investigation of the Passive Film on Stainless Steel and Inconel 600 in High Temperature  Pressurized  Impurity Containing Water

Download or read book An In situ Investigation of the Passive Film on Stainless Steel and Inconel 600 in High Temperature Pressurized Impurity Containing Water written by Todd Samuel Mintz and published by . This book was released on 2003 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Nuclear Science Abstracts

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1974 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Advances in Fracture and Failure Prevention

Download or read book Advances in Fracture and Failure Prevention written by and published by . This book was released on 2004 with total page 908 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1985 with total page 892 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book In situ Surface Enhanced Raman Spectroscopy Investigation of the Surface Films on Alloy 600 and Alloy 690 in Pressurized Water Reactor Primary Water

Download or read book In situ Surface Enhanced Raman Spectroscopy Investigation of the Surface Films on Alloy 600 and Alloy 690 in Pressurized Water Reactor Primary Water written by Feng Wang and published by . This book was released on 2012 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alloy 600 is found to be susceptible to stress corrosion cracking (SCC) in Pressurized Water Reactor (PWR) primary water environment. In this study, in-situ Surface Enhanced Raman Spectroscopy (SERS) is used to characterize surface films formed on Alloy 600 and Alloy 690 in PWR PW at 320oC. A simulated PWR PW system is constructed. In addition, a titanium autoclave is designed for high-temperature electrochemical tests. In this study, we have also measured SERS spectra of surface films formed on unalloyed nickel, unalloyed chromium, Ni-5Cr-8Fe, Ni-10Cr-8Fe, Ni-10Cr and Ni-20Cr. The surface films were formed at different potentials, from -0.9V to -0.5V vs SHE. A formation of NiO film is observed on the surface of nickel at -0.65V, which shows a Raman peak at 540 cm-1 due to crystal defects. For pure chromium, Cr2O3 passive film is formed on its surface. The Raman peaks are located at 540 cm-1 and 610 cm-1. The thickness of Cr2O3 passive film is about several nanometers, depending on the growth time in PWR PW. A peak at 610 cm-1 would likely indicate Cr2O3 and the absence of this peak, in conjunction with a peak at 540 cm-1, would indicate NiO. It is found that the surface films on Ni-5Cr-8Fe and Ni-10Cr-8Fe alloys are composed of Cr2O3 and FeCr2O4 spinel. No spinel oxide peak is observed in the SERS spectra for Ni-10Cr and Ni-20Cr binary alloys, and the surface film on both alloys is Cr2O3. An analysis of SERS spectra indicate that, as alloy's chromium concentration increases, the amount of Cr2O3 included in the alloy's surface film would increase. The surface film of Alloy 600 is composed of Cr2O3 inner layer (IL) and FeCr2O4 outer layer (OL). For short-time growth (10 min), the inner Cr2O3 layer is about 2 - 4 nm thick, and the average size of FeCr2O4 crystallites is about 10 nm. The actual film thickness depends on the growth time and aqueous environment. The surface film formed on Alloy 600 in PWR PW has a minor change if the sample is removed from the autoclave and exposed to air. The surface film of Alloy 690 is entirely a single layer of Cr2O3 (~ 2 nm thick). According to Diffusion Path Analysis, the difference on surface films formed on Alloy 600 and Alloy 690 is a consequence of a change in the relative diffusivity of O and Cr. Our in-situ SERS spectra measured for surface films on Alloy 600 and Alloy 690 are different with most of other people's findings. Three aspects have been considered and discussed. The first, there might be a difference between in-situ and ex-situ characterization techniques. The second, the film growth time in PWR PW is significantly different. The third, different autoclaves are used. The recirculating titanium autoclave is used in this study, while stainless steel autoclave is used in most of other studies, which might cause a change of the concentration of cations in the vicinity of metal surface and a precipitation of cations on the surface of oxides. It is found that the exposure time and testing autoclave might be responsible for the discrepancies between this study and the earlier studies. By using in-situ Surface Enhance Raman Spectroscopy (SERS), we have investigated the surface oxides formed on Alloy 600, Alloy 690, Ni-Cr, and Ni-Cr-Fe alloys in PWR primary water at 320oC. Our in-situ SERS spectra results suggest that SCC susceptibility of Ni-based alloys might be correlating with a formation of surface films formed in PWR primary water.

Book Government Reports Announcements   Index

Download or read book Government Reports Announcements Index written by and published by . This book was released on 1994 with total page 1502 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Engineering Index Annual

Download or read book The Engineering Index Annual written by and published by . This book was released on 1994 with total page 2398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since its creation in 1884, Engineering Index has covered virtually every major engineering innovation from around the world. It serves as the historical record of virtually every major engineering innovation of the 20th century. Recent content is a vital resource for current awareness, new production information, technological forecasting and competitive intelligence. The world?s most comprehensive interdisciplinary engineering database, Engineering Index contains over 10.7 million records. Each year, over 500,000 new abstracts are added from over 5,000 scholarly journals, trade magazines, and conference proceedings. Coverage spans over 175 engineering disciplines from over 80 countries. Updated weekly.

Book Corrosion

Download or read book Corrosion written by and published by . This book was released on 1961-07 with total page 826 pages. Available in PDF, EPUB and Kindle. Book excerpt: Issues include special section called Corrosion abstracts.

Book Metals Abstracts

Download or read book Metals Abstracts written by and published by . This book was released on 1995 with total page 1602 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Scientific and Technical Aerospace Reports

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1986 with total page 1160 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Government Reports Announcements

Download or read book Government Reports Announcements written by and published by . This book was released on 1974 with total page 1332 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Transactions

    Book Details:
  • Author : Iron and Steel Institute
  • Publisher :
  • Release : 1964
  • ISBN :
  • Pages : 1002 pages

Download or read book Transactions written by Iron and Steel Institute and published by . This book was released on 1964 with total page 1002 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book INIS Atomindex

Download or read book INIS Atomindex written by and published by . This book was released on 1996 with total page 794 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Proceedings of the 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems   Water Reactors

Download or read book Proceedings of the 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems Water Reactors written by Gabriell Ilevbare and published by Springer. This book was released on 2017-07-17 with total page 2354 pages. Available in PDF, EPUB and Kindle. Book excerpt: This 15th Edition of the International Conference on Materials Degradation in Light Water Reactors focuses on subject areas critical to the safe and efficient running of nuclear reactor systems through the exchange and discussion of reseach results as well as field operating and management experience.

Book Conference Papers Index

Download or read book Conference Papers Index written by and published by . This book was released on 1988 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monthly. Papers presented at recent meeting held all over the world by scientific, technical, engineering and medical groups. Sources are meeting programs and abstract publications, as well as questionnaires. Arranged under 17 subject sections, 7 of direct interest to the life scientist. Full programs of meetings listed under sections. Entry gives citation number, paper title, name, mailing address, and any ordering number assigned. Quarterly and annual indexes to subjects, authors, and programs (not available in monthly issues).