Download or read book Guidelines for Sediment Tracing Using the Compound Specific Carbon Stable Isotope Technique written by International Atomic Energy Agency and published by . This book was released on 2019 with total page 57 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Guidelines for Sediment Tracing Using the Compound Specific Carbon Stable Isotope Technique written by International Atomic Energy Agency and published by . This book was released on 2019-10-21 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication is intended to support the proper use of the compound specific stable isotope (CSSI) technique for identifying sources of sediment within agroecosystems. Based on the measurement of Carbon-13 natural abundance signatures of fatty acids in the soil, this technique allows to discriminate and apportion the sources soil contribution that originate from different land use. While covering the fundamental concepts of the CSSI technique, this publication is unique in providing step-by-step instructions for scientists, technicians and students on how to effectively use this isotopic approach. This comprehensive illustrated guide highlights new opportunities for improving area-wide soil conservation strategies in fragile agricultural landscapes.
Download or read book That s Phat written by Dominic Reiffarth and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Rivers and lakes are subject to various forms of pollution from anthropogenic activity and natural sources. Many pollutants, such as those from agricultural runoff, are transported in rivers by binding to sediment. Sediment itself is a pollutant, and is often an indicator of terrestrial erosive processes. Common methods of establishing sediment provenance on a broad scale include the use of fallout radio nuclides and geochemistry. In 2008, Dr. Max Gibbs published a sediment tracing article on the use of compound-specific stable isotopes (CSSIs) of plant origin which identified sediment sources based on land use in sub-tropical New Zealand. The objective of the research undertaken here was to apply the CSSI concept to agricultural watersheds in a northern, temperate climate. Two watersheds were selected: the Horsefly River Watershed (HRW) near Horsefly, BC, Canada and the South Tobacco Creek Watershed (STCW), near Miami, Manitoba, Canada. The HRW represented a mostly pristine watershed. The STCW represented a heavily cropped agricultural watershed. The HRW samples were used to develop laboratory methodology, while the STCW samples were used to evaluate the CSSI technique using carbon stable isotopes. The dissertation addresses the following: (i) literature review of plant biomarkers and spatial/temporal variability of CSSIs due to biological, environmental and analytical factors; (ii) methodology, analysis and variability associated with bulk soil and sediment isotope determination; (iii) methodologies for processing soil and sediment from sampling to isotope analysis; and (iv) spatial and temporal variability of CSSI tracers. The CSSI tracers were evaluated to reveal spatial and temporal variability of VLCFA concentrations and isotope signatures at the point, transect and field scales. Weighted t-tests were used to differentiate sediment sources spatially and temporally. The use of bulk carbon as a proxy for VLCFA concentrations in source apportioning was also explored. The work presented here demonstrates the ability of CSSIs to differentiate sediment sources based on land use. The development of analytical methods and the resulting analysis of soil and sediment extracts have indicated that VLCFAs may be isolated and quantified to generate reliable isotope data. The methods will hopefully lead to the standardization of CSSIs protocols.
Download or read book Compound specific Stable Isotope Analysis written by Maik A Jochmann and published by Royal Society of Chemistry. This book was released on 2015-11-09 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of Compound-specific Stable Isotope Analysis (CSIA) is increasing in many areas of science and technology for source allocation, authentication, and characterization of transformation reactions. Until now, there have been no textbooks available for students with an analytical chemical background or basic introductory books emphasising the instrumentation and theory. This book is the first to focus solely on stable isotope analysis of individual compounds in sometimes complex mixtures. It acts as both a lecture companion for students and a consultant for advanced scientists in fields including forensic and environmental science. The book starts with a brief history of the field before going on to explain stable isotopes from scratch. The different ways to express isotope abundances are introduced together with isotope effects and isotopic fractionation. A detailed account of the required technical equipment and general procedures for CSIA is provided. This includes sections on derivatization and the use of microextraction techniques in GC-IRMS. The very important topic of referencing and calibration in CSIA is clearly described. This differs from approaches used in quantitative analysis and is often difficult for the newcomer to comprehend. Examples of successful applications of CSIA in food authenticity, forensics, archaeology, doping control, environmental science, and extraterrestrial materials are included. Applications in isotope data treatment and presentation are also discussed and emphasis is placed on the general conclusions that can be drawn from the uses of CSIA. Further instrumental developments in the field are highlighted and selected experiments are introduced that may act as a basis for a short practical course at graduate level.
Download or read book Stable Isotope Technique to Assess Intake of Human Milk in Breastfed Infants written by International Atomic Energy Agency and published by . This book was released on 2010 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication was developed by an international group of experts as an integral part of the IAEA's efforts to contribute to the transfer of technology and knowledge in nutrition. Its aim is to assist Member States in their efforts to combat malnutrition by facilitating the use of relevant nuclear techniques. The stable (non-radioactive) isotope technique has been developed to assess intake of human milk in breastfed infants. The practical application of the stable isotope technique, based on analysis of deuterium by Fourier transform infrared spectrometry (FTIR), is presented in this book.
Download or read book Tracking Environmental Change Using Lake Sediments written by William M. Last and published by Springer. This book was released on 2010-10-28 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Theory Instrumentation NIR analysis of sediment samples Uses of NIRS in palaeolimnology Future perspectives Summary References Fly-ash particles. Neil Rose 319 12. Introduction A brief history Methods of extraction and enumeration Temporal distribution Spatial distribution Source apportionment The future Summary Acknowledgements References Part III: Stable Isotope Techniques 13. Application of stable isotope techniques to inorganic and biogenic carbonates. Emi Ito 351 Introduction Nomenclature and systematics of lake-water Mg/Ca and Sr/Ca ratios of lake-water of dissolved inorganic carbon (DIC) Carbonates in lake-sediments Mollusks Ostracodes Charaphytes Isotope analysis Preparation of carbonate samples for isotope analysis Conclusions Summary Acknowledgments References 14. Carbon and oxygen isotope analysis of lake sediment cellulose: methods and applications. Brent B. Wolfe, Thomas W. D. Edwards, Richard J. Elgood & Kristina R. M. Beuning 373 xi Introduction Stable isotope tracers in lake Historical development Methods Key criteria for paleohydrologic reconstruction Applications Future research directions Summary Acknowledgements References Nitrogen isotopes in palaeolimnology. Michael R. Talbot 15. 401 Introduction Nitrogen in lakes: forms and distribution Nitrogen isotopes Nitrogen isotope studies in palaeolimnology: sampling and measurement Some examples Closing remarks Summary Acknowledgments References Glossary, acronyms and abbreviations 441 Index 493 xiii PREFACE The explosive growth of paleolimnology over the past two decades has provided impetus for the publication of this series of monographs detailing the numerous advances and new techniques being applied to the interpretation of lake histories. This is the second volume in the series and deals mainly with physical and geochemical analytical techniques.
Download or read book Encyclopedia of Geochemistry written by William M. White and published by Springer. This book was released on 2018-07-24 with total page 1680 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.
Download or read book Tracing the Sources and Fate of Contaminants in Agroecosystems written by Joseph Adu-Gyamfi and published by Springer Nature. This book was released on with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Stable Isotope Ecology written by Brian Fry and published by Springer Science & Business Media. This book was released on 2007-01-15 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: A solid introduction to stable isotopes that can also be used as an instructive review for more experienced researchers and professionals. The book approaches the use of isotopes from the perspective of ecological and biological research, but its concepts can be applied within other disciplines. A novel, step-by-step spreadsheet modeling approach is also presented for circulating tracers in any ecological system, including any favorite system an ecologist might dream up while sitting at a computer. The author’s humorous and lighthearted style painlessly imparts the principles of isotope ecology. The online material contains color illustrations, spreadsheet models, technical appendices, and problems and answers.
Download or read book Tracking Environmental Change Using Lake Sediments written by William M. Last and published by Springer. This book was released on 2002-06-30 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Theory Instrumentation NIR analysis of sediment samples Uses of NIRS in palaeolimnology Future perspectives Summary References Fly-ash particles. Neil Rose 319 12. Introduction A brief history Methods of extraction and enumeration Temporal distribution Spatial distribution Source apportionment The future Summary Acknowledgements References Part III: Stable Isotope Techniques 13. Application of stable isotope techniques to inorganic and biogenic carbonates. Emi Ito 351 Introduction Nomenclature and systematics of lake-water Mg/Ca and Sr/Ca ratios of lake-water of dissolved inorganic carbon (DIC) Carbonates in lake-sediments Mollusks Ostracodes Charaphytes Isotope analysis Preparation of carbonate samples for isotope analysis Conclusions Summary Acknowledgments References 14. Carbon and oxygen isotope analysis of lake sediment cellulose: methods and applications. Brent B. Wolfe, Thomas W. D. Edwards, Richard J. Elgood & Kristina R. M. Beuning 373 xi Introduction Stable isotope tracers in lake Historical development Methods Key criteria for paleohydrologic reconstruction Applications Future research directions Summary Acknowledgements References Nitrogen isotopes in palaeolimnology. Michael R. Talbot 15. 401 Introduction Nitrogen in lakes: forms and distribution Nitrogen isotopes Nitrogen isotope studies in palaeolimnology: sampling and measurement Some examples Closing remarks Summary Acknowledgments References Glossary, acronyms and abbreviations 441 Index 493 xiii PREFACE The explosive growth of paleolimnology over the past two decades has provided impetus for the publication of this series of monographs detailing the numerous advances and new techniques being applied to the interpretation of lake histories. This is the second volume in the series and deals mainly with physical and geochemical analytical techniques.
Download or read book Using Geochemical Data written by Hugh Rollinson and published by Cambridge University Press. This book was released on 2021-05-06 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is a complete rewrite, and expansion of Hugh Rollinson's highly successful 1993 book Using Geochemical Data: Evaluation, Presentation, Interpretation. Rollinson and Pease's new book covers the explosion in geochemical thinking over the past three decades, as new instruments and techniques have come online. It provides a comprehensive overview of how modern geochemical data are used in the understanding of geological and petrological processes. It covers major element, trace element, and radiogenic and stable isotope geochemistry. It explains the potential of many geochemical techniques, provides examples of their application, and emphasizes how to interpret the resulting data. Additional topics covered include the critical statistical analysis of geochemical data, current geochemical techniques, effective display of geochemical data, and the application of data in problem solving and identifying petrogenetic processes within a geological context. It will be invaluable for all graduate students, researchers, and professionals using geochemical techniques.
Download or read book Isoscapes written by Jason B. West and published by Springer Science & Business Media. This book was released on 2009-11-25 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable isotope ratio variation in natural systems reflects the dynamics of Earth systems processes and imparts isotope labels to Earth materials. Carbon isotope ratios of atmospheric CO2 record exchange of carbon between the biosphere and the atmosphere; the incredible journeys of migrating monarchs is documented by hydrogen isotopes in their wings; and water carries an isotopic record of its source and history as it traverses the atmosphere and land surface. Through these and many other examples, improved understanding of spatio-temporal isotopic variation in Earth systems is leading to innovative new approaches to scientific problem-solving. This volume provides a comprehensive overview of the theory, methods, and applications that are enabling new disciplinary and cross-disciplinary advances through the study of "isoscapes": isotopic landscapes. "This impressive new volume shows scientists deciphering and using the natural isotope landscapes that subtly adorn our spaceship Earth.", Brian Fry, Coastal Ecology Institute, Louisiana State University, USA "An excellent timely must read and must-have reference book for anybody interested or engaged in applying stable isotope signatures to questions in e.g. Anthropology, Biogeochemistry, Ecology, or Forensic Science regarding chronological and spatial movement, changes, or distribution relating to animals, humans, plants, or water.", Wolfram Meier-Augenstein, Centre for Anatomy & Human Identification, University of Dundee, UK "Natural resources are being affected by global change, but exactly where, how, and at what pace? Isoscapes provide new and remarkably precise answers.", John Hayes, Woods Hole Oceanographic Institution, USA "This exciting volume is shaping a new landscape in environmental sciences that is utilizing the remarkable advances in isotope research to enhance and extend the capabilities of the field.", Dan Yakir, Weizmann Institute of Science, Israel
Download or read book Environmental Isotopes in Biodegradation and Bioremediation written by C. Marjorie Aelion and published by CRC Press. This book was released on 2009-11-04 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: Enhanced analytical capabilities and separation techniques, improved detection limits, and accessibility of instrumentation have led to massive strides in the use of isotopes to assess microbial processes in surface and subsurface sediments. Considering the rapid growth of research and commercial interest in stable isotope and radioisotope applicat
Download or read book Application of Compound Specific Stable Isotope Analysis to Spatial and Temporal Tracing of Organic Molecular Biomarkers Through the Environment written by Abigail M Oakes and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the critical challenges facing modern environmental chemistry is how to identify sources, process of formation, and transport of organic compounds and pollutants in the environment. In recent decades, molecular and stable isotopic analysis of individual organic biomarkers, produced by living organisms, has emerged as a novel tool for identifying sources and processes associated with the synthesis of biological compounds. Specifically, this thesis focused on the questions related to processes controlling the production and movement of n-alkanes produced in plant leaf waxes and PAHs produced through the partial combustion of organic material. The aims of this thesis were to use compound-specific isotope analysis of these organic molecular biomarkers to understand how environmental changes are recorded, determine source materials, and evaluate potential methods of transport through the environment. Chapters 3 and 4 used stable hydrogen (Î ́D) and carbon (Î ́13C) isotopes of n-alkanes produced by leaf waxes to determine how differences in taxonomic class are recorded and how these biomarkers are preserved in fluvial sediments. This study found that n-alkanes from individual plants record plant specific differences in photosynthetic processes and physiology whereas n‑alkanes preserved in fluvial sediments can identify large scale ecosystem changes. In Chapter 5, the concentrations, Î ́D and Î ́13C of 16 EPA priority PAHs were measured from samples collected from around the states of Connecticut and Rhode Island. Using a multivariate approach to source identification, this study found that PAHs extracted from sediments and soils in Connecticut were sourced from a complex mixture of vehicular exhaust, coal burning exhaust, and industrial emissions. These projects represent a significant contribution to the understanding of carbon mobility over the earth surface with broad applications to environmental pollution tracing and paleoenvironmental reconstructions.
Download or read book Application of Geochemical Tracers to Fluvial Sediment written by Jerry R. Miller and published by Springer. This book was released on 2014-12-03 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book takes an in-depth look at the theory and methods inherent in the tracing of riverine sediments. Examined tracers include multi-elemental concentration data, fallout radionuclides (e.g., 210Pb, 137Cs, 7Be), radiogenic isotopes (particularly those of Pb, Sr, and Nd), and novel (“non-traditional”) stable isotopes (e.g., Cd, Cu, Hg, and Zn), the latter of which owe their application to recent advances in analytical chemistry. The intended goal is not to replace more ‘traditional’ analyses of the riverine sediment system, but to show how tracer/fingerprinting studies can be used to gain insights into system functions that would not otherwise be possible. The text, then, provides researchers and catchment managers with a summary of the strengths and limitations of the examined techniques in terms of their temporal and spatial resolution, data requirements, and the uncertainties in the generated results. The use of environmental tracers has increased significantly during the past decade because it has become clear that documentation of sediment and sediment-associated contaminant provenance and dispersal is essential to mitigate their potentially harmful effects on aquatic ecosystems. Moreover, the use of monitoring programs to determine the source of sediments to a water body has proven to be a costly, labor intensive, long-term process with a spatial resolution that is limited by the number of monitoring sites that can be effectively maintained. Alternative approaches, including the identification and analysis of eroded upland areas and the use of distributed modeling routines also have proven problematic. The application of tracers within riverine environments has evolved such that they focus on sediments from two general sources: upland areas and specific, localized, anthropogenic point sources. Of particular importance to the former is the development of geochemical fingerprinting methods that quantify sediment provenance (and to a much lesser degree, sediment-associated contaminants) at the catchment scale. These methods have largely developed independently of the use of tracers to document the source and dispersal pathways of contaminated particles from point-sources of anthropogenic pollution at the reach- to river corridor-scale. Future studies are likely to begin merging the strengths of both approaches while relying on multiple tracer types to address management and regulatory issues, particularly within the context of the rapidly developing field of environmental forensics.
Download or read book The Geochemistry of Stable Chlorine and Bromine Isotopes written by Hans Eggenkamp and published by Springer. This book was released on 2014-08-25 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides detailed information on the history, analysis and applications of chlorine and bromine isotope geochemistry. Chlorine and bromine are geochemically unique as they prefer to exist as single charged negative ions. For this reason isotope fractionation reflects mostly processes that are not related to changes in the redox state and this fractionation is generally modest. The book will describe the processes that are most easily detected using these isotopes. Also isotope variations, and processes that cause them, measured in oxidised species such as perchlorates and in organic molecules will be described in this book.
Download or read book Practical Guidelines for the Analysis of Seawater written by Oliver Wurl and published by CRC Press. This book was released on 2009-06-09 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: As we discover more about the role of the ocean in global changes and identify the effects of global change on the ocean, understanding its chemical composition and processes becomes increasingly paramount. However, understanding these processes requires a wide range of measurements in the vast ocean, from the sea surface to deep-ocean trenches, fr
