Download or read book Equilibrium Constants of Liquid Liquid Distribution Reactions written by Y. Marcus and published by Elsevier. This book was released on 2013-09-24 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Equilibrium Constants of Liquid-liquid Distribution Reactions Introduction, and Part 1: Organophosphorus Extractants focuses on the numerical representations, formulas, reactions, and characteristics of equilibrium constants of organophosphorus extractants. The text underscores that only a number of papers focusing on equilibrium constants for distribution reactions involving metal complexes are published before 1947. The book also states that no equilibrium constants have been reported on several organophosphorus extractants although they are used in practical extraction work. The publication provides a list of extractants, ligands, and metal ions. These include distribution and dissociation of extractants; dimerization and aggregation of extractants; homogeneous equilibria of extractants with metal ions; extraction of metal ions with extractants as ligands; and reactions of extractants with diluents and other solvents. The manuscript also highlights reactions, temperature, and equilibrium constants. The book is a valuable source of data for readers interested in the equilibrium constants of organophosphorus extractants.
Download or read book Equilibrium Constants of Liquid liquid Distribution Reactions written by Jiří Starý and published by Pergamon. This book was released on 1978 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Equilibrium Constants of Liquid liquid Distribution Reactions written by International Union of Pure and Applied Chemistry. Commission on Equilibrium Data and published by Franklin Book Company. This book was released on 1974 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Equilibrium Constants of Liquid liquid Distribution Reactions Alkylammonium salt extractants written by International Union of Pure and Applied Chemistry. Commission on Equilibrium Data and published by . This book was released on 1974 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Critical Evaluation of Equilibrium Constants Involving 8 Hydroxyquinoline and Its Metal Chelates written by J. Stary and published by Elsevier. This book was released on 2013-10-22 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates presents and evaluates the published data on the solubility, dissociation, and liquid–liquid distribution of oxine and its metal chelates to recommend the most reliable numerical data. This book explores the dissociation constants of oxine in aqueous solutions. Organized into four chapters, this book begins with an overview of the characteristics of 8-hydroxyquinoline (oxine). This text then examines the total solubility of oxine in aqueous solution at different pH values. Other chapters consider the distribution of oxine between an aqueous phase and an organic solvent, which can be generally described by an equation where the bar indicates the organic phase species. This book discusses as well the overall extraction constant involving metal chelate formation. The final chapter deals with the overall stability constants of metal oxinate. This book is a valuable resource for geochemists, chemists, scientists, and research workers.
Download or read book International Thermodynamic Tables of the Fluid State written by S. Angus and published by Elsevier. This book was released on 2013-10-22 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Thermodynamic Tables of the Fluid State - 7 Propylene (Propene) is a compilation of internationally agreed values of the equilibrium thermodynamic properties of propylene. This book is composed of three chapters, and begins with the presentation of experimental result of thermodynamic studies compared with the equations used to generate the tables. The succeeding chapter deals with correlating equations for thermodynamic property determination of propylene. The last chapter provides the tabulations of the propylene's thermodynamic properties and constants. This book will prove useful to physical chemists.
Download or read book Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution written by D. D. Perrin and published by Elsevier. This book was released on 2016-09-14 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution, Second Edition provides a compilation of tables that summarize relevant data recorded in the literature up to the end of 1980 for the ionization constants of inorganic acids and bases in aqueous solution. This book includes references to acidity functions for strong acids and bases, as well as details about the formation of polynuclear species. This text then explains the details of each column of the tables, wherein column 1 gives the name of the substance and the negative logarithm of the ionization constant and column 2 gives the temperature of measurements in degree Celsius. This book presents as well the method of measurement and the literature references that are listed alphabetically at the end of the tables. Chemists will find this book useful.
Download or read book Thermodynamic and Transport Properties of Organic Salts written by Paolo Franzosini and published by Elsevier. This book was released on 2013-10-22 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamic and Transport Properties of Organic Salts is concerned with the thermodynamic and transport properties of organic salts, namely, pure salts, mixtures, and solutions. The transport properties of pure molten salts and binary mixtures of molten salts with organic ions are given, along with the transport properties of organic salts in aqueous solutions. This book is divided into three sections and opens with a discussion on the statistical treatment and of computer simulation methods for molten salts as well as their results for pressure-volume-temperature (PVT) data. The PVT data for organic molten salts determined experimentally are considered, and the thermal properties as well as the melting mechanism of pure salts are described. A method by which PVT data at high pressure can be estimated from those at low pressure with sufficiently high accuracy is also outlined. The next section deals with salt mixtures, their phase diagrams, and their transport properties. The final section looks at the transport properties of organic salts in aqueous solutions; thermodynamic quantities of micelle formation; and formation of lyotropic liquid crystals by organic salts. Two appendixes showing the structure of the pure solids and the use of the melts in electrochemical studies are included. This monograph will be a useful resource for organic chemists.
Download or read book Critical Evaluation of Some Equilibrium Constants Involving Alkylammonium Extractants written by A. S. Kertes and published by Elsevier. This book was released on 2013-10-22 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: Critical Evaluation of Some Equilibrium Constants Involving Alkylammonium Extractants reviews the data on equilibrium constants involving long-chain alkylammonium salt extractants. The book considers only two types of pertinent heterogeneous equilibria: the formation constants of alkylammonium salts; and the constants of the aggregation equilibria of these salts in organic solvents employed as diluents in solvent extraction processes. The basic principles of the most reliable and recommended experimental procedures; and the methods of treatment of numerical data and the calculations involved are also reviewed. Chemists will find this book a good reference.
Download or read book Critical Evaluation of Some Equilibrium Constants Involving Organophosphorus Extractants written by Y. Marcus and published by Elsevier. This book was released on 2013-10-22 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt: Critical Evaluation of Some Equilibrium Constants Involving Organophosphorus Extractants is a supplementary text to the compilation "Equilibrium Constants of Liquid-Liquid Distribution Reactions (Introduction, and Part I: Organophosphorus Extractants). The book contains a number of well documented chemical reactions that are critically evaluated. The reactions evaluated comprise those from List 1 for which data are available. There are, however, a great variety of reactions that cannot be critically evaluated due to lack of experimental data and unverifiable results. Chemists will find this compendium very useful.
Download or read book Liquid Phase Extraction written by Colin F. Poole and published by Elsevier. This book was released on 2019-08-29 with total page 818 pages. Available in PDF, EPUB and Kindle. Book excerpt: Liquid Phase Extraction thoroughly presents both existing and new techniques in liquid phase extraction. It not only provides all information laboratory scientists need for choosing and utilizing suitable sample preparation procedures for any kind of sample, but also showcases the contemporary uses of sample preparation techniques in the most important industrial and academic project environments, including countercurrent chromatography, pressurized-liquid extraction, single-drop Microextraction, and more. Written by recognized experts in their respective fields, it serves as a one-stop reference for those who need to know which technique to choose for liquid phase extraction. Used in conjunction with a similar release, Solid Phase Extraction, it allows users to master this crucial aspect of sample preparation. - Defines the current state-of-the-art in extraction techniques and the methods and procedures for implementing them in laboratory practice - Includes extensive referencing that facilitates the identification of key information - Aimed at both entry-level scientists and those who want to explore new techniques and methods
Download or read book Chlorine written by S. Angus and published by Elsevier. This book was released on 2015-09-03 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chlorine: International Thermodynamic Tables of the Fluid State-8 is a four-chapter book that covers available and estimated data on chlorine; estimation of the element's properties; the correlating equations for the element; and how the tabulated properties are calculated from chosen equation. The tables in this book give the volume, entropy, enthalpy, isobaric heat capacity, compression factor, fugacity/pressure ratio, Joule-Thomson coefficient, ratio of the heat capacities, and speed of sound as a function of pressure and temperature. Given in the tables as well are the pressure, entropy, internal energy, and isochoric heat capacity as functions of density and temperature, for the gas and liquid states from 0.025 MPa to 25 MPa at temperatures from 180 K to 900 K.
Download or read book NBS Technical Note written by and published by . This book was released on 1972 with total page 86 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Aqueous Electrolyte Thermodynamics written by Joseph F. Zemaitis, Jr. and published by John Wiley & Sons. This book was released on 2010-09-16 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.
Download or read book Ion Exchange and Solvent Extraction written by Yitzhak Marcus and published by CRC Press. This book was released on 2004-07-23 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 17 in the Ion Exchange and Solvent Extraction series represents the vanguard of research on solvent extraction. It covers the principles of electrolyte extraction and other subjects of increasing interest to the field. This volume begins with pharmaceutical applications of supercritical fluid solvents, particularly supercritical carbon dioxi
Download or read book Critical Survey of Stability Constants and Related Thermodynamic Data of Fluoride Complexes in Aqueous Solution written by A. M. Bond and published by Elsevier. This book was released on 2017-07-07 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt: Critical Survey of Stability Constants and Related Thermodynamic Data of Fluoride Complexes in Aqueous Solution covers the problems and techniques for measuring fluoride stability constants. This book is composed of two parts encompassing five chapters that describe the general characteristics of fluoride as a ligand, as well as the techniques for measuring fluoride enthalpy. The second part contains tabulations of fluoride's stability constants in aqueous solution.
Download or read book Chelating Extractants written by J. Stary and published by Elsevier. This book was released on 2013-09-17 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part IV: Chelating Extractants is a compilation of liquid-liquid distribution equilibrium constants, with emphasis on extractants that form chelates. This tabulation includes all data published up to the end of 1972 for the major chelating extractants, and the given equilibrium parameters are supplemented by calculations (or recalculations) from experimental results. This monograph consists of 12 chapters and characterizes the homogeneous equilibria involving the acid dissociation of the extractant in the aqueous phase and adduct or mixed ligand complex formation in the organic phase. The information given for each system includes the chemical reactions, the equilibrium constant, the temperature, and the composition of the aqueous and organic phases. Compounds covered include dialkyldithiocarbamic acids (such as diethyldithiocarbamic acid and dibutyldithioarbamic acid), tropolones (beta-isopropyltropolone and gamma-isopropyltropolone), N-acylhydroxylamines, N-nitroso-N-arylhydroxylamines (cupferrons), alpha-dioximes, diarylthiocarbazones (dithizones), 8-hydroxyquinolines, 8-mercaptoquinolines, o-dimercaptobenzenes (toluene-3,4-dithiol), beta-diketones (such as acetylacetone and hexafluoroacetylacetone), 4-acylpyrazol-5-ones, and o-nitrosophenols (1-nitroso-2-naphthol and 2-nitroso-1-naphthol). This book will be of interest to chemists.
