Download or read book Electronic Structure of Metal Phthalocyanines on Ag 100 written by Cornelius Krull and published by Springer Science & Business Media. This book was released on 2013-11-19 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: The application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip.
Download or read book Single NdPc2 Molecules on Surfaces Adsorption Interaction and Molecular Magnetism written by Sarah Fahrendorf and published by Forschungszentrum Jülich. This book was released on 2013 with total page 115 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molecular Electronic Structures of Transition Metal Complexes I written by David Michael P. Mingos and published by Springer Science & Business Media. This book was released on 2012-01-11 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt: J.P. Dahl: Carl Johan Ballhausen (1926–2010).- J.R. Winkler and H.B. Gray: Electronic Structures of Oxo-Metal Ions.- C.D. Flint: Early Days in Kemisk Laboratorium IV and Later Studies.- J.H. Palmer: Transition Metal Corrole Coordination Chemistry. A Review Focusing on Electronic Structural Studies.- W.C. Trogler: Chemical Sensing with Semiconducting Metal Phthalocyanines.- K.M. Lancaster: Biological Outer-Sphere Coordination.- R.K. Hocking and E.I. Solomon: Ligand Field and Molecular Orbital Theories of Transition Metal X-ray Absorption Edge Transitions.- K.B. Møller and N.E. Henriksen: Time-resolved X-ray diffraction: The dynamics of the chemical bond.
Download or read book Heavy Metals Advances in Research and Application 2012 Edition written by and published by ScholarlyEditions. This book was released on 2012-12-26 with total page 1713 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heavy Metals—Advances in Research and Application: 2012 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Heavy Metals. The editors have built Heavy Metals—Advances in Research and Application: 2012 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Heavy Metals in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Heavy Metals—Advances in Research and Application: 2012 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Download or read book Molecular Beam Epitaxy written by Mohamed Henini and published by Newnes. This book was released on 2012-12-31 with total page 745 pages. Available in PDF, EPUB and Kindle. Book excerpt: This multi-contributor handbook discusses Molecular Beam Epitaxy (MBE), an epitaxial deposition technique which involves laying down layers of materials with atomic thicknesses on to substrates. It summarizes MBE research and application in epitaxial growth with close discussion and a 'how to' on processing molecular or atomic beams that occur on a surface of a heated crystalline substrate in a vacuum.MBE has expanded in importance over the past thirty years (in terms of unique authors, papers and conferences) from a pure research domain into commercial applications (prototype device structures and more at the advanced research stage). MBE is important because it enables new device phenomena and facilitates the production of multiple layered structures with extremely fine dimensional and compositional control. The techniques can be deployed wherever precise thin-film devices with enhanced and unique properties for computing, optics or photonics are required. This book covers the advances made by MBE both in research and mass production of electronic and optoelectronic devices. It includes new semiconductor materials, new device structures which are commercially available, and many more which are at the advanced research stage. - Condenses fundamental science of MBE into a modern reference, speeding up literature review - Discusses new materials, novel applications and new device structures, grounding current commercial applications with modern understanding in industry and research - Coverage of MBE as mass production epitaxial technology enhances processing efficiency and throughput for semiconductor industry and nanostructured semiconductor materials research community
Download or read book STM Study of Self assembled Phthalocyanine Derivatives and Their Hosting Properties written by Tomáš Samuely and published by Cuvillier Verlag. This book was released on 2008 with total page 65 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dynamics at Surfaces Understanding Energy Dissipation and Physicochemical Processes at the Atomic and Molecular Level written by Marco Sacchi and published by Frontiers Media SA. This book was released on 2024-04-26 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy release to solid interfaces following chemical reactions is ubiquitous in a vast range of phenomena. Energy dissipation and dynamical disorder (surface entropy), surface friction and molecular diffusion control the rates of heterogeneous catalytic reactions, the efficiency of novel technology, lubrication as well as materials growth including self-assembly and nano-structures. Yet we understand little about the underlying nature of these mechanisms. Fundamentally, energy dissipation including interactions with phonons and electron-hole pairs determines the lifetime of molecular vibrations and rotations as well as the decoherence rate of quantum states. These processes form a central point for many aspects in physical chemistry, are embedded in the mechanisms that control surface dynamical processes and are critical factors in catalysis. They are equally relevant for physicochemical processes in the Earth's atmosphere and astrochemistry occurring on cosmic dust grains.
Download or read book Fundamentals of Picoscience written by Klaus D. Sattler and published by CRC Press. This book was released on 2013-09-26 with total page 766 pages. Available in PDF, EPUB and Kindle. Book excerpt: Now ubiquitous in public discussions about cutting-edge science and technology, nanoscience has generated many advances and inventions, from the development of new quantum mechanical methods to far-reaching applications in electronics and medical diagnostics. Ushering in the next technological era, Fundamentals of Picoscience focuses on the instrumentation and experiments emerging at the picometer scale. One picometer is the length of a trillionth of a meter. Compared to a human cell of typically ten microns, this is roughly ten million times smaller. In this state-of-the-art book, international scientists and researchers at the forefront of the field present the materials and methods used at the picoscale. They address the key challenges in developing new instrumentation and techniques to visualize and measure structures at this sub-nanometer level. With numerous figures, the book will help you: Understand how picoscience is an extension of nanoscience Determine which experimental technique to use in your research Connect basic studies to the development of next-generation picoelectronic devices The book covers various approaches for detecting, characterizing, and imaging at the picoscale. It then presents picoscale methods ranging from scanning tunneling microscopy (STM) to spectroscopic approaches at sub-nanometer spatial and energy resolutions. It also covers novel picoscale structures and picometer positioning systems. The book concludes with picoscale device applications, including single molecule electronics and optical computers. Introductions in each chapter explain basic concepts, define technical terms, and give context to the main material.
Download or read book Molecular Magnetic Materials written by Barbara Sieklucka and published by John Wiley & Sons. This book was released on 2017-01-17 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of this rapidly expanding interdisciplinary field of research. After a short introduction to the basics of magnetism and molecular magnetism, the text goes on to cover specific properties of molecular magnetic materials as well as their current and future applications. Design strategies for acquiring molecular magnetic materials with desired physical properties are discussed, as are such multifunctional materials as high Tc magnets, chiral and luminescent magnets, magnetic sponges as well as photo- and piezo-switching magnets. The result is an excellent resource for materials scientists, chemists, physicists and crystal engineers either entering or already working in the field.
Download or read book Unimolecular and Supramolecular Electronics II written by Robert M. Metzger and published by Springer Science & Business Media. This book was released on 2012-01-10 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: G. C. Solomon C. Herrmann M. A. Ratner Molecular Electronic Junction Transport: Some Pathways and Some Ideas R. M. Metzger D. L. Mattern Unimolecular Electronic Devices B. Branchi F. C. Simeone M. A. Rampi Active and Non-Active Large-Area Metal–Molecules–Metal Junctions C. Li A. Mishchenko T. Wandlowski Charge Transport in Single Molecular Junctions at the Solid/Liquid Interface K. W. Hipps Tunneling Spectroscopy of Organic Monolayers and Single Molecules N. Renaud M. Hliwa C. Joachim Single Molecule Logical Devices
Download or read book Molecular Magnets written by Juan Bartolomé and published by Springer Science & Business Media. This book was released on 2013-10-17 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of the physical phenomena discovered in magnetic molecular materials over the last 20 years. It is written by leading scientists having made the most important contributions to this active area of research. The main topics of this book are the principles of quantum tunneling and quantum coherence of single-molecule magnets (SMMs), phenomena which go beyond the physics of individual molecules, such as the collective behavior of arrays of SMMs, the physics of one-dimensional single–chain magnets and magnetism of SMMs grafted on substrates. The potential applications of these physical phenomena to classical and quantum information, communication technologies, and the emerging fields of molecular spintronics and magnetic refrigeration are stressed. The book is written for graduate students, researchers and non-experts in this field of research.
Download or read book Chemistry of Nanomolecular Systems written by Takayoshi Nakamura and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, molecular electronics, especially that utilizing single molecules, has been attracting much attention. This is mainly because the theoretical limit is approaching in the present silicon-based technology, and the development of an alternative process is strongly desired. Single-molecule electronics is aimed at a breakthrough toward the next generation of computing systems. By designing and synthesizing highly functionalized molecules of nanometer size and incorporating these molecules into electrical circuits, we shall obtain much dense and high-speed processors. The concept of single-molecule electronics was first introduced by Aviram and Ratnar in 1978. In the early 1980s, many groups all over the world had started research on molecular electronics. At that time, single-molecule manipulation techniques had not been born, and the research was mainly carried out on molecular films formed by the Langmuir~Blodgett technique, a wet process, and by molecular-beam epitaxy, a dry process. A number of prototypes of switching devices and logic gates were, however, reported in the 1980s. In the early 1990s, scanning probe microscopes became popular and researchers obtained a single-molecule manipulation and evaluation tech nique. It became possible to fabricate practical devices using single molecules or small numbers of molecules. Finally, at the end of the last century, an explosion in the research field of single-molecule electronics was witnessed. In addition, studies of "biocomputing" started in the early 1980s and significant progress was achieved in the last century.
Download or read book Chemistry of Nanomolecular Systems written by Manfred Baerns and published by Springer Science & Business Media. This book was released on 2004 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes contemporary efforts to develop nano-molecular systems for future molecular electronics in which single molecules act as the basic elements in electrical circuits. While describing frontier research, it also gives a comprehensive introduction and discusses the related work being pursued worldwide. The book is composed of three parts. The first part describes the synthesis of novel molecules for molecular nano-systems. The second part deals mainly with nano-molecular systems on solid surfaces and the evaluation of the system with SPM. The third part reviews the theory required as a background for molecular electronics.
Download or read book On Surface Synthesis written by André Gourdon and published by Springer. This book was released on 2016-01-14 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by leading international experts, this book presents a detailed compilation of a new and very active field. It is the first book devoted to the covalent coupling of molecular precursors on surfaces that allows the preparation of 0D, 1D and 2D molecules that cannot be synthesized in solution. This book is aimed at students and researchers interested in nanochemistry and molecular devices and it gives the reader a pedagogical up-to-date vision of the most recent developments. The editor ensures a multidisciplinary approach involving molecular chemistry, surface sciences, surface spectroscopies, theory, scanning tunneling and non-contact atomic force microscopies.
Download or read book Supramolecular Chirogenesis in Chemical and Related Sciences written by Victor Borovkov and published by Frontiers Media SA. This book was released on 2021-06-01 with total page 179 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Supramolecular Chemistry written by Jonathan W. Steed and published by John Wiley & Sons. This book was released on 2022-01-10 with total page 1220 pages. Available in PDF, EPUB and Kindle. Book excerpt: A one-stop, comprehensive, and thoroughly updated resource for students, professors, and researchers alike Thoroughly revised and updated, the Third Edition of Supramolecular Chemistry delivers a comprehensive and integrated approach to this rapidly evolving and quickly expanding field. Distinguished professors and authors Jonathan Steed and Jerry Atwood provide readers with a broad and exhaustive resource that assumes little in the way of prior knowledge of supramolecular chemistry. Extensive new content on cutting edge research throughout the field including molecular machines and the mechanical bond, mechanochemistry, halogen bonding, and crystal nucleation accompanies full-color imagery and study problems designed to help students understand and apply the principles introduced within the book. Additional material is provided in the supplementary online resources, including solutions to the student exercises and PowerPoint slides of the figures in the book. Supramolecular Chemistry, Third Edition also includes: The latest research and developments reported over the last decade A unique “key references” system that highlights crucial reviews and primary literature A description of key experimental techniques included in accessible “boxes” for the non-expert Exercises and problems for students, complete with online solutions Full-color illustrations and imagery designed to facilitate learning and retention of the key concepts and state-of-the art of the field Perfect for undergraduate and postgraduate students taking courses on supramolecular chemistry, the Third Edition of Supramolecular Chemistry also belongs on the bookshelves of all researchers in this, and any closely related, fields. Academics, in particular postdoctoral students and professors, will benefit significantly from this text.
Download or read book Future Trends For Top Materials written by Mário J. F. Calvete and published by Bentham Science Publishers. This book was released on 2016-01-07 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference focuses on defined types of compounds which are of interest to readers who are motivated to explore basic information about new materials for advanced industrial applications. General and established synthetic methodologies for several compounds are explained giving a straightforward approaches for researchers who intend to pursue new projects in materials sciences, This book presents 9 chapters, covering phthalocyanines, polymethines, porphyrins, BODIPYs, dendrimers, carbon allotropes, organic frameworks, nanoparticles and future prospects. Each chapter covers detailed synthetic aspects of the most established preparation routes for the specific compounds, while giving a historical perspective, with selective information on actual and outstanding applications of each material, unraveling what likely might be the future for each category. This book is intended as a hands-on reference guide for undergraduates and graduates interested in industrial chemistry and materials science.
