Download or read book Effects of Dopant Molecules on the Electronic Properties of Organic Thin Films written by Joel Walter Pankow and published by . This book was released on 1991 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Correlation between Structural and Electronic Properties of Co Evaporated Doped Organic Thin Films written by Daniela Donhauser and published by Cuvillier Verlag. This book was released on 2014-10-23 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Devices based on organic semiconductors, like organic light emitting diodes (OLEDs) or organic solar cells, often comprise electrochemically doped charge transport layers, which improve the performance of these devices. Although very efficient devices can be realized nowadays, a comprehensive description of the physical processes taking place in electrochemically doped thin films is still missing. For instance, it was shown for a variety of different material systems that the doping efficiency, defined as the number of free charge carriers compared to the number of incorporated dopants, often amounts to only a few per cent. The organic semiconductor CBP (4,4’-Bis(N-carbazolyl)-1,1’-biphenyl), doped with the transition metal oxide molybdenum oxide (MoO3), is used here as a model system to investigate the origin for this low doping efficiency. Results from different measurement techniques, like electron tomography, EF-TEM, PES, FTIR-spectroscopy and (temperature- dependent) electrical measurements were correlated to get insight into the origin of the low doping effiencies and to obtain a model to describe charge transport in MoO3-doped CBP films as a function of the doping concentration.

Download or read book Organic Thermoelectric Materials written by Zhiqun Lin and published by Royal Society of Chemistry. This book was released on 2019-10-18 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarises the significant progress made in organic thermoelectric materials, focusing on effective routes to minimize thermal conductivity and maximize power factor.

Download or read book Morphology Charge Transport Properties and Molecular Doping of Thiophene based Organic Semiconducting Thin Films written by Patrick Pingel and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic semiconductors combine the benefits of organic materials, i.e., low-cost production, mechanical flexibility, lightweight, and robustness, with the fundamental semiconductor properties light absorption, emission, and electrical conductivity. This class of material has several advantages over conventional inorganic semiconductors that have led, for instance, to the commercialization of organic light-emitting diodes which can nowadays be found in the displays of TVs and smartphones. Moreover, organic semiconductors will possibly lead to new electronic applications which rely on the unique mechanical and electrical properties of these materials. In order to push the development and the success of organic semiconductors forward, it is essential to understand the fundamental processes in these materials. This thesis concentrates on understanding how the charge transport in thiophene-based semiconductor layers depends on the layer morphology and how the charge transport properties can be intentionally modified by doping these layers with a strong electron acceptor. By means of optical spectroscopy, the layer morphologies of poly(3-hexylthiophene), P3HT, P3HT-fullerene bulk heterojunction blends, and oligomeric polyquaterthiophene, oligo-PQT-12, are studied as a function of temperature, molecular weight, and processing conditions. The analyses rely on the decomposition of the absorption contributions from the ordered and the disordered parts of the layers. The ordered-phase spectra are analyzed using Spano's model. It is figured out that the fraction of aggregated chains and the interconnectivity of these domains is fundamental to a high charge carrier mobility. In P3HT layers, such structures can be grown with high-molecular weight, long P3HT chains. Low and medium molecular weight P3HT layers do also contain a significant amount of chain aggregates with high intragrain mobility; however, intergranular connectivity and, therefore, efficient macroscopic charge transport are absent. In P3HT-fullerene blend layers, a highly crystalline morphology that favors the hole transport and the solar cell efficiency can be induced by annealing procedures and the choice of a high-boiling point processing solvent. Based on scanning near-field and polarization optical microscopy, the morphology of oligo-PQT-12 layers is found to be highly crystalline which explains the rather high field-effect mobility in this material as compared to low molecular weight polythiophene fractions. On the other hand, crystalline dislocations and grain boundaries are identified which clearly limit the charge carrier mobility in oligo-PQT-12 layers. The charge transport properties of organic semiconductors can be widely tuned by molecular doping. Indeed, molecular doping is a key to highly efficient organic light-emitting diodes and solar cells. Despite this vital role, it is still not understood how mobile charge carriers are induced into the bulk semiconductor upon the doping process. This thesis contains a detailed study of the doping mechanism and the electrical properties of P3HT layers which have been p-doped by the strong molecular acceptor tetrafluorotetracyanoquinodimethane, F4TCNQ. The density of doping-induced mobile holes, their mobility, and the electrical conductivity are characterized in a broad range of acceptor concentrations. A long-standing debate on the nature of the charge transfer between P3HT and F4TCNQ is resolved by showing that almost every F4TCNQ acceptor undergoes a full-electron charge transfer with a P3HT site. However, only 5% of these charge transfer pairs can dissociate and induce a mobile hole into P3HT which contributes electrical conduction. Moreover, it is shown that the left-behind F4TCNQ ions broaden the density-of-states distribution for the doping-induced mobile holes, which is due to the longrange Coulomb attraction in the low-permittivity organic semiconductors.

Download or read book From Molecular Parameters to Electronic Properties of Organic Thin Films a Photoelectron Spectroscopy Study written by Martin Schwarze and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Physics of Organic Semiconductors written by Wolfgang Brütting and published by John Wiley & Sons. This book was released on 2012-10-02 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of organic electronics has seen a steady growth over the last 15 years. At the same time, our scientific understanding of how to achieve optimum device performance has grown, and this book gives an overview of our present-day knowledge of the physics behind organic semiconductor devices. Based on the very successful first edition, the editors have invited top scientists from the US, Japan, and Europe to include the developments from recent years, covering such fundamental issues as: - growth and characterization of thin films of organic semiconductors, - charge transport and photophysical properties of the materials as well as their electronic structure at interfaces, and - analysis and modeling of devices like organic light-emitting diodes or organic lasers. The result is an overview of the field for both readers with basic knowledge and for an application-oriented audience. It thus bridges the gap between textbook knowledge largely based on crystalline molecular solids and those books focusing more on device applications.

Download or read book Electronic Processes in Organic Electronics written by Hisao Ishii and published by Springer. This book was released on 2015-01-07 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book covers a variety of studies of organic semiconductors, from fundamental electronic states to device applications, including theoretical studies. Furthermore, innovative experimental techniques, e.g., ultrahigh sensitivity photoelectron spectroscopy, photoelectron yield spectroscopy, spin-resolved scanning tunneling microscopy (STM), and a material processing method with optical-vortex and polarization-vortex lasers, are introduced. As this book is intended to serve as a textbook for a graduate level course or as reference material for researchers in organic electronics and nanoscience from electronic states, fundamental science that is necessary to understand the research is described. It does not duplicate the books already written on organic electronics, but focuses mainly on electronic properties that arise from the nature of organic semiconductors (molecular solids). The new experimental methods introduced in this book are applicable to various materials (e.g., metals, inorganic and organic materials). Thus the book is also useful for experts working in physics, chemistry, and related engineering and industrial fields.

Download or read book Handbook of Organic Materials for Optical and Opto Electronic Devices written by Oksana Ostroverkhova and published by Elsevier. This book was released on 2013-08-31 with total page 832 pages. Available in PDF, EPUB and Kindle. Book excerpt: Small molecules and conjugated polymers, the two main types of organic materials used for optoelectronic and photonic devices, can be used in a number of applications including organic light-emitting diodes, photovoltaic devices, photorefractive devices and waveguides. Organic materials are attractive due to their low cost, the possibility of their deposition from solution onto large-area substrates, and the ability to tailor their properties. The Handbook of organic materials for optical and (opto)electronic devices provides an overview of the properties of organic optoelectronic and nonlinear optical materials, and explains how these materials can be used across a range of applications.Parts one and two explore the materials used for organic optoelectronics and nonlinear optics, their properties, and methods of their characterization illustrated by physical studies. Part three moves on to discuss the applications of optoelectronic and nonlinear optical organic materials in devices and includes chapters on organic solar cells, electronic memory devices, and electronic chemical sensors, electro-optic devices.The Handbook of organic materials for optical and (opto)electronic devices is a technical resource for physicists, chemists, electrical engineers and materials scientists involved in research and development of organic semiconductor and nonlinear optical materials and devices. Comprehensively examines the properties of organic optoelectronic and nonlinear optical materials Discusses their applications in different devices including solar cells, LEDs and electronic memory devices An essential technical resource for physicists, chemists, electrical engineers and materials scientists

Download or read book EFFECT OF DOPING ON DIFFERENT PROPERTIES OF SEMICONDUCTING THIN FILMS written by Dr. Vinod Deoram Bhabad and published by Shashwat Publication. This book was released on 2023-02-12 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hard work is going on in finding novel resources for solar power alteration. Dual essential parameters must be considered in manufacturing of such materials. They are optical gap corresponding to solar range and affordability of fabrication price. Between the materials of abundant attention are crystalline metal chalcogenides. Numerous semiconducting photoelectrodes were comprehensively considered for electrochemical generation of current by using radiation in terms of continuous and effective trap as well as exchange of solar power. This dissertation illustrate the synthesis and characterization of polycrystalline cadmium selenide/trivalent ion like aluminum doped cadmium selenide/ monovalent ion like copper doped cadmium selenide thin films. Solar cells maintain great hopes to be used an environmental friendly and economically feasible renewable power sources. For this purpose semiconductor materials are being investigated. In the present investigation, deposition of cadmium selenide/aluminum and copper doped cadmium selenide samples by dip method applying amorphous as well as metallic templates. Aluminum trichloride, cadmium sulfate, ammonia,trichloroacetic acid, aluminum trichloride, sodium selenosulphate and copper chloride were utilized to deposit the samples. Diverse depositary considerations were outlined to acquired excellent samples. The materials have been characterized via XRD technique, SEM method, optical absorption measurement and electrical characteristics. The sample undergoes photoelectrochemical and thermoelectrical determination. Cadmium selenide films show dark red in color. For aluminum and copper doped samples different shades and dark brown color was obtained correspondingly. The extreme thickness of cadmium selenide became observed 0.54μm, aluminum doped sample indicates 0.74 μm as well as 0.70μm for copper doped samples. Each sample indicates hexagonal structure. Cadmium selenide and aluminum doped sample represents a strong peak o

Download or read book Molecular Layer Deposition for Tailored Organic Thin Film Materials written by Tetsuzo Yoshimura and published by CRC Press. This book was released on 2023-03-14 with total page 539 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides concepts and experimental demonstrations for various types of molecular layer deposition (MLD) and organic multiple quantum dots (organic MQDs), which are typical tailored organic thin-film materials. Possible applications of MLD to optical interconnects, energy conversion systems, molecular targeted drug delivery, and cancer therapy are also proposed. First, the author reviews various types of MLD processes including vapor-phase MLD, liquid-phase MLD, and selective MLD. Next, he introduces organic MQDs, which are typical tailored organic thin-film materials produced by MLD. The author then describes the design of light modulators/optical switches, predicts their performance, and discusses impacts of the organic MQDs on them. He then also discusses impacts of the organic MQDs on optical interconnects within computers and on optical switching systems. Finally, the author presents MLD applications to molecular targeted drug delivery, photodynamic therapy, and laser surgery for cancer therapy. This book is intended for researchers, engineers, and graduate students in optoelectronics, photonics, and any other field where organic thin-film materials can be applied.

Download or read book Thin Film Physics And Devices Fundamental Mechanism Materials And Applications For Thin Films written by Jianguo Zhu and published by World Scientific. This book was released on 2021-06-18 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin films have an extremely broad range of applications from electronics and optics to new materials and devices. Collaborative and multidisciplinary efforts from physicists, materials scientists, engineers and others have established and advanced a field with key pillars constituting (i) the synthesis and processing of thin films, (ii) the understanding of physical properties in relation to the nanometer scale, (iii) the design and fabrication of nano-devices or devices with thin film materials as building blocks, and (iv) the design and construction of novel tools for characterization of thin films.Against the backdrop of the increasingly interdisciplinary field, this book sets off to inform the basics of thin film physics and thin film devices. Readers are systematically introduced to the synthesis, processing and application of thin films; they will also study the formation of thin films, their structure and defects, and their various properties — mechanical, electrical, semiconducting, magnetic, and superconducting. With a primary focus on inorganic thin film materials, the book also ventures on organic materials such as self-assembled monolayers and Langmuir-Blodgett films.This book will be effective as a teaching or reference material in the various disciplines, ranging from Materials Science and Engineering, Electronic Science and Engineering, Electronic Materials and Components, Semiconductor Physics and Devices, to Applied Physics and more. The original Chinese publication has been instrumental in this purpose across many Chinese universities and colleges.

Download or read book Handbook of Organic Materials for Electronic and Photonic Devices written by Oksana Ostroverkhova and published by Woodhead Publishing. This book was released on 2018-11-30 with total page 911 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Organic Materials for Electronic and Photonic Devices, Second Edition, provides an overview of the materials, mechanisms, characterization techniques, structure-property relationships, and most promising applications of organic materials. This new release includes new content on emerging organic materials, expanded content on the basic physics behind electronic properties, and new chapters on organic photonics. As advances in organic materials design, fabrication, and processing that enabled charge unprecedented carrier mobilities and power conversion efficiencies have made dramatic advances since the first edition, this latest release presents a necessary understanding of the underlying physics that enabled novel material design and improved organic device design. Provides a comprehensive overview of the materials, mechanisms, characterization techniques, and structure property relationships of organic electronic and photonic materials Reviews key applications, including organic solar cells, light-emitting diodes electrochemical cells, sensors, transistors, bioelectronics, and memory devices New content to reflect latest advances in our understanding of underlying physics to enable material design and device fabrication

Download or read book Semiconductors written by Martin I. Pech-Canul and published by Springer. This book was released on 2019-01-17 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a practical guide to optical, optoelectronic, and semiconductor materials and provides an overview of the topic from its fundamentals to cutting-edge processing routes to groundbreaking technologies for the most recent applications. The book details the characterization and properties of these materials. Chemical methods of synthesis are emphasized by the authors throughout the publication. Describes new materials and updates to older materials that exhibit optical, optoelectronic and semiconductor behaviors; Covers the structural and mechanical aspects of the optical, optoelectronic and semiconductor materials for meeting mechanical property and safety requirements; Includes discussion of the environmental and sustainability issues regarding optical, optoelectronic, and semiconductor materials, from processing to recycling.

Download or read book C H N and O in Si and Characterization and Simulation of Materials and Processes written by A. Borghesi and published by Newnes. This book was released on 2012-12-02 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: Containing over 200 papers, this volume contains the proceedings of two symposia in the E-MRS series. Part I presents a state of the art review of the topic - Carbon, Hydrogen, Nitrogen and Oxygen in Silicon and in Other Elemental Semiconductors. There was strong representation from the industrial laboratories, illustrating that the topic is highly relevant for the semiconductor industry. The second part of the volume deals with a topic which is undergoing a process of convergence with two concerns that are more particularly application oriented. Firstly, the advanced instrumentation which, through the use of atomic force and tunnel microscopies, high resolution electron microscopy and other high precision analysis instruments, now allows for direct access to atomic mechanisms. Secondly, the technological development which in all areas of applications, particularly in the field of microelectronics and microsystems, requires as a result of the miniaturisation race, a precise mastery of the microscopic mechanisms.

Download or read book Assessing the Effects of Biaxial Strain and Chemical Doping on the Magnetic and Electronic Properties of Epitaxial Europium Monoxide Films written by Alexander Melville and published by . This book was released on 2014 with total page 121 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ferromagnetic semiconductor EuO, which possesses several record properties relevant to devices, has been researched in an attempt to enhance and understand this novel material, i.e., raising its Curie temperature (TC) and developing it as a viable electronic material, by investigating three distinct research directions for EuO: chemical doping via trivalent rare-earth cations, biaxial strain via substrates with varying degrees of lattice mismatch, and preservation via application of a well-chosen capping layer. The use of Lu3+ as a chemical dopant for enhancing the TC of EuO up to 119 K was established. The spin-polarization for the Lu-doped EuO thin film was measured to be 96%, confirming its near-complete spin-polarization. The effect of biaxial strain on TC for EuO thin films that are commensurately strained to the substrate was explored. The use LuAlO3, which imparts an asymmetric tensile strain of +0.4% strain and +1.5% strain along the [110] and [110] EuO directions, respectively, resulted in the reduction of the TC for commensurate EuO / LuAlO3 thin films of varying thicknesses. The strain-dependence was confirmed by comparing the series to an identical series grown on the lattice-matched, i.e., unstrained, substrate yttria-stabilized zirconia (YSZ). Biaxial compressive strain was explored by growing EuO thin films on both singlecrystal diamonds and epitaxial diamond thin films grown on silicon. Diamond is 2.2% smaller than EuO, so epitaxial integration of EuO on diamond was attempted in hopes of achieving symmetric 2.2% compressive strain. Though the EuO was epitaxial and free of extraneous phases and orientations, demonstrating the first instance of a ferromagnet epitaxially integrated with diamond, the EuO was not compressively strained, and no change in TC was observed. Finally, the formation of a protective Eu2O3 capping layer by controlled oxidation of the surface of EuO in vacuum was studied. The Eu2O3 was effective at preventing the degradation of the underlying EuO, as determined by the scanning tunneling electron microscopy and electron energy loss spectroscopy analysis. The analysis, in conjunction with X-ray diffraction experiments, demonstrated that the oxygen diffusion during the capping layer formation is heavily influenced by the presence of defects in the film.

Download or read book Electrical Optical and Magnetic Properties of Organic Solid State Materials written by and published by . This book was released on 1996 with total page 742 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Organic Conductors written by Jean-Pierre Farges and published by CRC Press. This book was released on 2022-09-16 with total page 874 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work examines all aspects of organic conductors, detailing recent theoretical concepts and current laboratory methods of synthesis, measurement, control and analysis. It describes advances in molecular-scale engineering, including switching and memory systems, Schottky and electroluminescent diodes, field-effect transistors, and photovoltaic devices and solar cells.