Download or read book Diamine phosphine ruthenium II Complexes and Their Application in the Catalytic Hydrogenation of Alpha Beta unsaturated Ketones in Homogeneous and Heterogeneous Phase written by Ismail Khalil Warad and published by . This book was released on 2003 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Diamine phosphine ruthenium II Complexes and Their Application in the Catalytic Hydrogenation of unsaturated alpha Beta unsaturated Ketones in Homogeneous and Heterogeneous Phase written by Ismail Khalil Warad and published by . This book was released on 2003 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Novel Neutral and Cationic Diamine bis ether phosphine ruthenium II Complexes in Homogeneous and Heterogeneous States as Tools for Parallel Catalyst Screening written by Samer Ibrahim Abed-Rabbo Al-Gharabli and published by . This book was released on 2002 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ruthenium Oxidation Complexes written by William P. Griffith and published by Springer Science & Business Media. This book was released on 2010-11-03 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ruthenium Oxidation Complexes explores ruthenium complexes, particularly those in higher oxidation states, which function as useful and selective organic oxidation catalysts. Particular emphasis is placed on those systems which are of industrial significance. The preparation, properties and applications of the ruthenium complexes are described, followed by a presentation of their oxidative properties and summary of the different mechanisms involved in the organic oxidations (e.g. oxidations of alcohols, alkenes, arenes and alkynes, alkanes, amines, ethers, phopshines and miscellaneous substrates). Moreover, future trends and developments in the area are discussed. This monograph is aimed at inorganic, organic, industrial and catalysis chemists, especially those who wish to carry out specific organic oxidations using catalytic methods.

Download or read book Ruthenium II Complexes Bearing Bis phosphine and beta aminophosphine beta aminophosphine Ligands and Their Application to Homogeneous C written by Christian Kühnlein and published by . This book was released on 2005 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ruthenium II Complexes Bearing Bis phosphine and aminophosphine beta aminophosphine Ligands and Their Application to Homogeneous C written by Christian Kühnlein and published by . This book was released on 2005 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ruthenium II Complexes Bearing Bis phosphine and aminophosphine Ligands and Their Application to Homogeneous C written by Christian Kühnlein and published by . This book was released on 2005 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Arene ether phosphine ruthenium II Complexes and Their Application in Stoichiometrie and Catalytic Reaction written by Stefan Pautz and published by . This book was released on 1997 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ruthenium in Organic Synthesis written by Shun-Ichi Murahashi and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)

Download or read book Half sandwich Complexes of Ruthenium Supported by N Heterocyclic Carbene Ligands written by Van Hung Mai and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents the preparation and catalytic reactivity of novel half-sandwich ruthenium complexes supported by N-Heterocyclic Carbene (NHC) ligands. The cationic half-sandwich ruthenium complexes [Cp(IPr)Ru(CH3CN)2]+ show interesting reactivities toward the transfer hydrogenation of different unsaturated substrates, such as ketones, olefins, N-heterocycles, and nitriles. Kinetic studies disclose that a neutral trishydride ruthenium complex is actually involved in the catalytic cycle, playing the role as a resting state. Further investigations on the sub-class of trishydride ruthenium complexes bearing NHC ligands (Cp'(NHC)RuH3) reveal that these complexes have an unusual and great catalytic performance toward the hydrodefluorination (HDF) of fluorinated aromatic and aliphatic compounds. The combined kinetic studies, cross-over experiments and rate law analysis suggest an unusual mechanistic pathway for the Cp*(IPr)RuH3 catalyzed HDF. This study is one of the rare examples where isopropanol is employed as a reducing agent for the metal-mediated HDF reaction. A class of silyl dihydride ruthenium complexes, derived from Cp(IPr)RuH3 are prepared. These silyl hydrido derivatives are great compounds for the study of the inter ligand hypervalent interaction (IHI), an interesting phenomenon for many non-classical silane complexes. This study also suggests that the replacement of phosphines by their isolobally analogous NHC ligands result in stronger IHI interactions in the corresponding compounds. Another type of non-classical interaction was systematically scrutinized in a ii series of new cationic and neutral silane sigma complexes of ruthenium bearing different silyl moieties. These new NHC-supported ruthenium complexes allow for direct comparation with the known phosphine analogues, which reveals interplay of steric and electronic factors on the extent of Si-H complexation to metal and the extent of additional interligand interactions between Ru-Cl and chlorosilane ligand. Finally, new trishydride ruthenium complexes bearing NHC ligands (Cp'(NHC)RuH3) catalyze the H/D exchange reaction of various N-heterocycle substrates; their catalytic performance can be considered as one of the mildest, and most efficient approaches.

Download or read book Characterization of Chlorohydridobis tertiaryphosphine Ruthenium II Complexes and Their Use as Homogeneous Hydrogenation Catalysts written by Ian Stuart Thorburn and published by . This book was released on 1980 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis characterization and catalytic application of polysiloxane and poly alumosiloxane bound ether phosphine ruthenium II complexes written by Andreas Jäger and published by . This book was released on 1997 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Synthesis Characterization and Catalytic Properties of Ruthenium and Rhodium Phosphine Complexes written by Michael Francis McGuiggan and published by . This book was released on 1983 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterisation of N6 Arene Diphosphine Ruthenium II Complexes written by Corinne Daguenet and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Novel Ruthenium Dihydrogen Complexes and Their Application in Catalysis written by Martin H. G. Prechtl and published by . This book was released on 2007 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Dichloro sulphoxide Complexes of Ruthenium II and Their Use as Catalysts for Homogeneous Asymmetric Hydrogenation written by McMillan, Roderick Stewart and published by 1976.. This book was released on 1976 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Dichloro Sulphoxide Complexes of Ruthenium II and Their Use as Catalysts for Homogeneous Asymmetric Hydrogenation written by Roderick Stewart McMillan and published by . This book was released on 1976 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: