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Book Determination of Stepsize Parameters for Intermolecular Vibrational Energy Transfer  Final Report  May 1  1987  December 31  1991

Download or read book Determination of Stepsize Parameters for Intermolecular Vibrational Energy Transfer Final Report May 1 1987 December 31 1991 written by and published by . This book was released on 1992 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intermolecular energy transfer of highly excited polyatomic molecules plays an important role in many complex chemical systems: combustion, high temperature and atmospheric chemistry. By monitoring the relaxation of internal energy we have observed trends in the collisional efficiency for energy transfer as a function of the substrates̀ excitation energy and the complexities of substrate and deactivator. For a given substrate? increases as the deactivators̀ mass increase to -30 amu and then exhibits a nearly constant value; this is due to a mass mismatch between the atoms of the colliders. In a homologous series of substrate molecules (C3-C)? decreases as the number of atoms in the substrate increases; replacing F with H increases?. All substrates, except for CF2Cl2 and CF2HCl below 10,000 cm−1, exhibited that? is independent of energy, i.e. ?E{sub all} is linear with energy. The results are interpreted with a simple model which considers that? is a function of the ocillators energy and its vibrational frequency. Limitations of current approximations used in high temperature unimolecular reactions were evaluated and better approximations were developed. The importance of energy transfer in product yields was observed for the photoactivation of perfluorocyclopropene and the photoproduction of difluoroethyne. 3 refs., 18 figs., 4 tabs.

Book Scientific and Technical Aerospace Reports

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1993 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1992 with total page 886 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Summaries of FY     Research in the Chemical Sciences

Download or read book Summaries of FY Research in the Chemical Sciences written by and published by . This book was released on 1989 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Government Reports Announcements   Index

Download or read book Government Reports Announcements Index written by and published by . This book was released on 1992-10 with total page 852 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book INIS Atomindex

Download or read book INIS Atomindex written by and published by . This book was released on 1988 with total page 962 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Unimolecular Kinetics

Download or read book Unimolecular Kinetics written by and published by Elsevier. This book was released on 2019-05-30 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unimolecular Kinetics: Part 2: Collisional Energy Transfer and the Master Equation, Volume 43 in Elsevier’s Comprehensive Molecular Kinetics series, addresses collision energy transfer and the effects it has on gas phase reactions, particularly at low gas density. Such systems include combustion, industrial gas phase processes and atmospheric/environmental processes. The book also discusses The Master Equation to give a good overview of the mechanics underpinning unimolecular kinetics. This new volume will be of interest to researchers investigating gas phase processes which involve unimolecular reactions and the related intermolecular reactions. Discusses collision energy transfer and the effects it has on gas phase reactions Introduces stochastic techniques to energy transfer methods, allowing for an extension of the unimolecular theory beyond simple molecular dissociation Draws an important connection between detailed reaction dynamic studies and the rate of coefficient determination

Book Photochemistry

    Book Details:
  • Author : D Bryce-Smith
  • Publisher : Royal Society of Chemistry
  • Release : 2007-10-31
  • ISBN : 1847554679
  • Pages : 690 pages

Download or read book Photochemistry written by D Bryce-Smith and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 34 covers literature published from July 2001 to June 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.

Book Vibrational Energy Transfer in Molecular Collisions and Van Der Waals Clusters

Download or read book Vibrational Energy Transfer in Molecular Collisions and Van Der Waals Clusters written by Laurie Miller Yoder and published by . This book was released on 2000 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Physics Briefs

Download or read book Physics Briefs written by and published by . This book was released on 1994 with total page 1170 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Microcanonical Unimolecular Rate Theory at Surfaces

Download or read book Microcanonical Unimolecular Rate Theory at Surfaces written by Alex David Bukoski and published by . This book was released on 2005 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Vibrational Energy Relaxation of Methanol in Solution

Download or read book Vibrational Energy Relaxation of Methanol in Solution written by Tolga S. Gulmen and published by . This book was released on 2005 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Photochemistry

Download or read book Photochemistry written by and published by . This book was released on 1984 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Bulletin of the Korean Chemical Society

Download or read book Bulletin of the Korean Chemical Society written by and published by . This book was released on 2006 with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Journal

Download or read book Journal written by Chemical Society (Great Britain) and published by . This book was released on 1980 with total page 762 pages. Available in PDF, EPUB and Kindle. Book excerpt: