Download or read book Design Synthesis and Functionalization of Organic and Metal containing pi conjugated Push pull Chromophores written by 陳興 and published by . This book was released on 2016 with total page 387 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Design Synthesis and Functionalization of Organic pi conjugated Donor acceptor Chromophores written by 姚子希 and published by . This book was released on 2019 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Design Synthesis and Application of Novel Conjugated Materials written by Haichang Zhang and published by Frontiers Media SA. This book was released on 2021-02-11 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Design Synthesis and Application of Novel Conjugated Materials Part II written by Haichang Zhang and published by Frontiers Media SA. This book was released on 2021-11-09 with total page 70 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Conjugated Objects written by Atsushi Nagai and published by CRC Press. This book was released on 2017-09-01 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conjugated Objects: Development, Synthesis, and Application contains 17 chapters written by young researchers and contains current trends in pi-conjugated systems for application in broad research areas such as design of unique pi-conjugation, catalysts, self-assembly, charge transfer complexes, liquid crystals, supramolecules, and nanostructures by using conjugated small and/or macro-objects organically or electrochemically. The book can be used as a textbook of basic learning by undergraduate and graduate students of chemistry, electrical and electronics engineering, and materials science and by supramolecular researchers in nanotechnology and biotechnology.
Download or read book DESIGN SYNTHESIS FUNCTIONALI written by Yau-Hin Hong and published by Open Dissertation Press. This book was released on 2017-01-26 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Design, Synthesis and Functionalization of Luminescent Alkynylgold(I) Complexes With [pi]-conjugated Ligands: From Photophysics to Supramolecular Assembly" by Yau-hin, Hong, 康祐軒, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of the thesis entitled DESIGN, SYNTHESIS AND FUNCTIONALIZATION OF LUMINESCENT ALKYNYLGOLD(I) COMPLEXES WITH π-CONJUGATED LIGANDS FROM PHOTOPHYSICS TO SUPRAMOLECULAR ASSEMBLY Submitted by HONG Yau Hin for the Degree of Doctor of Philosophy at The University of Hong Kong in July 2015 A library of polynuclear thiophene-based alkynylgold(I) complexes with N-heterocyclic carbenes (NHCs) and triphenylphosphine as the peripheral ligands, [R{(C≡C)Au(NHC)} ] (R = benzo[1,2-b:4,5-b']dithiophene, n = 2, 4; benzo[1,2- b:3,4-b':5,6-b'']trithiophene, n = 3; dithieno[3,2-b:2',3'-d]thiophene, n = 2; dithieno[3,2-e:2',3'-g](dibenzo[b, d]-thiophene), n = 2; 4-hexyl-4H-dithieno[3,2- b:2',3'-d]pyrrole, n = 4) and [R'{(C≡C)Au(PPh )}] (R' = benzo[1,2-b:4,5- 3 2 b']dithiophene), has been synthesized and characterized. The X-ray crystal structure of [BDT{(C≡C)Au(IHex)} -2,6] (BDT = benzo[1,2-b:4,5-b']dithiophene, IHex = 1,3-dihexylimidazol-2-ylidene) has been determined by X-ray crystallography. This class of complexes showed dual emissive behaviour and exhibited broad vibronic-structured emission bands in degassed dichloromethane solution at ambient temperature. As demonstrated by the temperature-dependent UV-vis absorption spectroscopy, some of the alkynylgold(I) complexes were shown to self-assemble in THFwater mixtures through a cooperative growth mechanism. Variation of the alkyl chain length on the NHC ligands not only has a significant effect on the morphologies of the aggregates, but also on the thermodynamic parameters of the self-assembly processes as revealed by the nucleationelongation model. Apart from the thiophene-based sulfur heterocycle-containing alkynylgold(I) system, a series of N-alkyl substituted triindole-based nitrogen heterocycle-containing trinuclear alkynylgold(I) complexes with isocyanide and NHCs as the peripheral ligands, [(TATI){(C≡C)Au(C≡N-R)}] (TATI = trialkyltriindole; R = 2,6-dimethoxyphenyl, 2,6-dimethylphenyl), and [(TATI){(C≡C)Au(NHC)}], has been prepared and characterized. The photophysical properties of the trinuclear alkynylgold(I) complexes have been examined. Their self-assembly properties have also been explored using TEM, SEM, DLS, H NMR spectroscopy, solvent-dependent and variable-temperature UV-vis absorption experiments. Some of the complexes have been demonstrated to possess spherical nanostructures in their THFwater dispersions. The self-assembly was believed to be mediated by the ππ stacking interactions of the central triindole moiety and governed by a cooperative growth mechanism. In addition, a novel class of amphiphilic phosphole-based phosphorus heterocycle-containing alkynylgold(I) complexes, [Au(C≡C-R){Ph-DBP(O)- ] O(CH ) SO }]K (DBP = 5H-dibenzophosphole; R = phenyl, naphthyl, 2 3 3 phenanthrenyl, pyrenyl, perylenyl, 4-methoxyphenyl, 4-chlorophenyl) was designed and synthesized. The photophysical properties of this class of complexes have been studied. Some of the complexes were shown to display sheet-like nanostructures in aqueous DMSO solution. The self-assembly process was found to be governed by an isodesmic mechanism and mediated by hydrophobichydrophobic interactions between the alkynyl units. It has been shown that modulation of t
Download or read book Design and Synthesis of Organic and Organometallic pi conjugated Donor acceptor Chromophores written by 陳展耀 and published by . This book was released on 2015 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Encyclopedia of Color Science and Technology written by Renzo Shamey and published by Springer Nature. This book was released on 2023-09-29 with total page 1634 pages. Available in PDF, EPUB and Kindle. Book excerpt: This fully revised and expanded 2nd edition provides a single authoritative resource describing the concepts of color and the application of color science across research and industry. Significant changes for the 2nd edition include: New and expanded sections on color engineering More entries on fundamental concepts of color science and color terms Many additional entries on specific materials Further material on optical concepts and human visual perception Additional articles on organisations, tools and systems relevant to color A new set of entries on 3D presentation of color In addition, many of the existing entries have been revised and updated to ensure that the content of the encyclopedia is current and represents the state of the art. The work covers the full gamut of color: the fundamentals of color science; the physics and chemistry; color as it relates to optical phenomena and the human visual system; and colorants and materials. The measurement of color is described through entries on colorimetry, color spaces, color difference metrics, color appearance models, color order systems and cognitive color. The encyclopedia also has extensive coverage of applications throughout industry, including color imaging, color capture, display and printing, and descriptions of color encodings, color management, processing color and applications relating to color synthesis for computer graphics are included. The broad scope of the work is illustrated through entries on color in art conservation, color and architecture, color and education, color and culture, and biographies of some of the key figures involved in color research throughout history. With over 250 entries from color science researchers across academia and industry, this expanded 2nd edition of the Encyclopedia of Color Science and Technology remains the most important single resource in color science.
Download or read book Improvement of Anthruiums Through Breeding written by Haruyuki Kamemoto and published by . This book was released on 1968 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Design and Synthesis of Organic Chromophores for Faraday Rotation and Photoluminescence written by Zachary Nelson and published by . This book was released on 2021 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis summarizes the design, synthesis, and application of novel small-molecule and polymeric materials, with emphasis on understanding and tuning the chromophore electronic structure to maximize properties including Faraday rotation and delayed fluorescence. In Chapter 1, we introduce the magneto-optical property Faraday rotation. The current frontiers in performance, applications, and mechanistic understanding of Faraday rotation in organic-chromophore thin-films is discussed. Faraday rotation measurements of several novel materials are introduced in context. In Chapter 2, we evaluate the Faraday rotation in thin films of several phthalocyanine and porphyrin derivatives, and observe maximum Verdet constants greater than those found in competing inorganic materials. The effect of chemical modifications, including the introduction of paramagnetic and chiral centers, is discussed. In Chapter 3, we evaluate the Faraday rotation in thin films of pi-conjugated polymers when influenced by chiral moieties. We demonstrate the key role chirality serves in the magneto-optical properties of these materials, the influence of structural order and film thickness on Faraday rotation, and report among the largest Verdet constants observed to date in organic thin films. In Chapter 4, we develop the polymerization for and evaluate the properties of a new class of polyarylene chalcogenides. We utilized dynamic covalent SNAr behavior to demonstrate selective depolymerization. In addition, we studied the mechanism of the bright photoemission, ascribing it to delayed fluorescence enabled by the presence of sulfur atoms. In Chapter 5, we discuss the synthesis and properties of two classes of solution-processable materials: M(III) and Au(I) arylthiolate coordination polymers. We demonstrate the presence of strong metal-metal interactions between M(III) centers along the polymer backbone. Further, we discuss the strong phosphorescence and dynamic supramolecular coordination in the solution phase of the Au(I) coordination polymers.
Download or read book Electrogenerated Chemiluminescence written by Allen J. Bard and published by CRC Press. This book was released on 2004-07-20 with total page 707 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first source on this expanding analytical science, this reference explores advances in the instrumentation, design, and application of techniques with electrogenerated chemiluminescence (ECL), examining the use and impact of ECL-based assays in clinical diagnostics, life science research, environmental testing, food and water evaluation, and th
Download or read book Supramolecular Coordination Complexes written by Sankarasekaran Shanmugaraju and published by Elsevier. This book was released on 2022-10-28 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular Coordination Complexes: Design, Synthesis, and Applications discusses the growth of the field and explores the advantages, opportunities and latest applications of supramolecular complexes. Beginning with an introduction to design principles, synthetic methods, and post-synthetic functionalization of supramolecular complexes, the book goes on to compile the different analytical and computational modeling methods used to understand the structure and functional properties of supramolecular structures. Applications of supramolecular complexes in biomedicine, sensing, catalysis and materials are then explored in detail. Drawing on the knowledge of a global team of experts, this book provides a wealth of interesting information for students and researchers working in the design, synthesis or application of such complexes. Discusses cutting-edge approaches for the investigation of supramolecular coordination chemistry Summarizes a varied range of supramolecular coordination, complex designs and applications Highlights the interdisciplinary connections between supramolecular chemistry and the fields of biology and materials science
Download or read book Metal Organic Frameworks written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2010-12-17 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Download or read book Multiporphyrin Arrays written by Dongho Kim and published by CRC Press. This book was released on 2012-01-12 with total page 817 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive review of the fundamentals and applications of multiporphyrin arrays ranging from basic spectroscopic features to a wide range of promising applications such as molecular wires, switches, sensors, artificial photosynthetic devices, and dye-sensitized solar cells based on a variety of multiporphyrin architectures u
Download or read book Organic Polymers written by Arpit Sand and published by BoD – Books on Demand. This book was released on 2020-03-11 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Organic Polymers, covers aspects that are of immediate concern to a new entrant to the field of polymers. Taken as a whole, these eight chapters aim to help the readers easily assimilate other specialized and exhaustive treatises on the subject. Topics dealing with the chemistry and technology of polymers are presented in a careful and logical manner so as to provide an easy and enjoyable read. Several examples and analogies are included so to make the main concepts easy to follow and tables and figures are included so that the book can serve, to a limited extent, as a hand book dealing with polysaccharides with different parameters. This book is meant for students studying polysaccharides and those working on graft copolymers and other allied polymer industries but without a formal educational background in organic polymers.
Download or read book Functional Organic Materials written by Thomas J. J. Müller and published by John Wiley & Sons. This book was released on 2007-02-12 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: This timely overview of the syntheses for functional pi-systems focuses on target molecules that have shown interesting properties as materials or models in physics, biology and chemistry. The unique concept allows readers to select the right synthetic strategy for success, making it invaluable for a number of industrial applications. A "must have" for everyone working in this new and rapidly expanding field.
Download or read book Modern Colorants Synthesis and Structure written by A.T. Peters and published by Springer Science & Business Media. This book was released on 1994-12-31 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although the research actIvItIes of dyestuff chemists worldwide have been influenced to a great extent, in recent years, by the need to respond to a variety of environmental issues associated with the manufacture and application of synthetic dyes and pigments, a significant level of targeted research continues to be devoted to new chemistry aimed at enhancing the technical properties of dyes in commerce. This book is a presentation of various aspects of basic research conducted during the past decade but not reported in the recent review literature. The coverage herein is unique in that it emphasizes systematic approaches commonly utilized in the design and synthesis of dyes and pigments and the required intermediates. While it is well known that certain transition metals are important in the synthesis of technically viable metallized dyes for polyamide and protein fibers, these metals are demonstrated in Chapter 1 also to be effective agents in the regiospecific placement of substituents into azo compounds. The scope and limitations of this chemistry are presented. In other synthetic work, a description of the different processes employed to produce the major families of reactive dyes is presented. In Chapter 4, special attention is given to reactive dyes containing more than one reactive group, and to the more recent developments in the field. The two chapters which follow provide a review of the recent literature pertaining to novel chromophores and dyes for the D2T2 process, respectively.
