Download or read book Defects and doping in Cu2O written by Francesco Biccari and published by Lulu.com. This book was released on 2012-02-14 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is the Francesco Biccari's PhD thesis in physics, defended at the Sapienza - University of Rome in February 2010. The thesis deals with the study of the defects and doping of cuprous oxide (Cu2O) a very long studied semiconductor. The interest in Cu2O is due to its optical properties, its low cost and low toxicity which make it a perfect candidate for low cost photovoltaic cells.

Download or read book First Principles Studies on N type and P type Doping in Cuprous Oxide written by Qiong Bai and published by . This book was released on 2015 with total page 85 pages. Available in PDF, EPUB and Kindle. Book excerpt: We have performed studies on n-type and p-type cuprous oxide with and without doping by first principles methods. Generalized Gradient Approximation (GGA) is used for the geometry optimization. The total energy and the final electronic structure calculations are conducted using the nonlocal screened Heyd-Scuseria-Ernzerhof (HSE) hybrid density functionals approach for cuprous oxide. The HSE hybrid density functionals overcome the shortcoming of GGA, which gives a much reliable value of the band gap. The formation energies of native point defects in undoped cuprous oxide have been studied by HSE hybrid functional theory in two conditions, which are vacuum based condition and solution based condition. Copper vacancy always has the lowest formation energy and provides p-type conductivity in both Cu-rich and O-rich conditions in vacuum based conditions. In the solution with low pH value, n-type cuprous oxide is achievable, where the antisite defect CuO is the dominant defect and responsible for the n-type conduction. Various elements are used to dope in cuprous oxide. In n-type doped cuprous oxide, certain halogen atoms, i.e., F, Cl and Br, are used to substitute the O atom. The metallic atoms, i.e., Ca, Mg, and Zn, are used to substitute Cu atom. The dopant in substitutional site has lower formation energy. Cl has the shallowest defect level among halogen atoms, which is favorable for electron to go to conduction band. In metallic atoms, Ca is the best candidate dopant with low formation energy and shallow transition level. The extra electron can be excited into bottom of conduction band. Also, the bottom of conduction band is dominated by 3s orbital of O atom, which is non-localized. The excited electron can move fast in 3s orbital and further improve the conductivity. For p-type doping to improve the properties of the p-type material, certain group V elements, such as N, P and As, are used to substitute an O atom. In a solution with pH=9, the formation energy of nitrogen substitutional defect is lower than that of copper vacancy, which means that nitrogen substitutional defect is a dominant defect and provides more free carriers, and further improves the conductivity of cuprous oxide. From the consideration of both the formation energy and the donor level, N is the best dopant among these three dopants. Finally, n-type doping in ZnO by Y has been studied. Oxygen vacancies, zinc interstitials, and zinc substitution by Y are considered here. We considered the formation energy of defects from two limit conditions, which are Zn-rich and O-rich. In Zn-rich condition, copper vacancy has the lowest formation energy. In O-rich condition, yttrium substitutional has the lowest formation energy and is a dominant defect, which will decrease the resistivity of ZnO.

Download or read book Defect Engineering in Cuprous Oxide Cu2O Solar Cells written by Sin Cheng Siah and published by . This book was released on 2015 with total page 109 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is focused on the development of a cuprous oxide (Cu2O) thin-film (TF) solar cell that is fabricated by manufacturing-friendly methods such as electro-deposition, sputtering and atomic layer deposition. Due to its bandgap of close to 2 eV, it has the potential of being applied as top cell in a tandem configuration. Firstly, I perform bottom-up cost and price analysis to investigate the economic feasibility of TF and c-Si based tandem photovoltaic modules. Next, I investigate the formation of good ohmic back contacts on Cu2O absorber layer and demonstrate that low contact resistivity can be achieved with a variety of metals on heavily doped Cu2O films by forming a tunnel junction. Then, I apply synchrotron-based X-ray absorption spectroscopy (XAS) to characterize two front contact buffer materials: amorphous Zn-Sn-O (a-ZTO) and Sndoped Ga2O3. I elucidate a fundamental loss mechanism in the amorphous Zn-Sn-O (a-ZTO) electron-blocking layer that has origin in local structural disorder and establish the structure-process- property relationship of a-ZTO so that the front buffer layer can be optimized for photovoltaics. Then, I investigate the doping mechanism of Sn dopant atoms in TFs and single crystalline Ga2O3:Sn by revealing the doping mechanism so that Ga2O3:Sn can be optimized for photovoltaics. Lastly. I apply bulk defect engineering to manipulate the intrinsic point defect structure of Cu2O towards improved device performance. The key results will inform the processing conditions for improving mobility and minority carrier lifetime in Cu2O. Keywords - Earth-abundant, thin-film solar cells, tandem, defect engineering, cost modeling, synchrotron.

Download or read book Optical Properties of Metal Oxide Nanostructures written by Vijay Kumar and published by Springer Nature. This book was released on 2023-10-25 with total page 515 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights the optical properties of metal oxides at both the fundamental and applied level and their use in various applications. The book offers a basic understanding of the optical properties and related spectroscopic techniques essential for anyone interested in learning about metal oxide nanostructures. This is partly due to the fact that optical properties are closely associated with other properties and functionalities (e.g., electronic, magnetic, and thermal), which are of essential significance to many technological applications, such as optical data communications, imaging, lighting, and displays, life sciences, health care, security, and safety. The book also highlights the fundamentals and systematic developments in various optical techniques to achieve better characterization, cost-effective, user-friendly approaches, and most importantly, state-of-the-art developing methodologies for various scientific and technological applications. It provides an adequate understanding of the imposed limitations and highlights the prospects and challenges associated with optical analytical methods to achieve the desired performance in targeted applications.

Download or read book Fabrication and Characterization of Low Cost Solar Cells based on Earth Abundant Materials for Sustainable Photovoltaics written by Mahmoud Abdelfatah and published by Cuvillier Verlag. This book was released on 2016-07-08 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: The low cost and low temperature electrochemical deposition technique was employed to grow Cu2O thin films and ZnO:Al thin films were deposited by d.c. magnetron sputtering in order to fabricate solar cells. The potentiostatic and galvanostatic electrodeposition modes were used to deposit the Cu2O thin films. Raman spectra of thin films have shown characteristic frequencies of crystalline Cu2O. The contact between Cu2O and Au is found to be an Ohmic contact. The devices grown by a potentiostatic mode have higher efficiency than those grown by a galvanostatic mode. The optimum thickness of Cu2O thin films as an absorber layer in solar cells. was found to be around 3 µm respect to a high efficiency. Flexible and light weight solar cell was fabricated on plastic substrate.

Download or read book Photovoltaics for the 21st Century 5 written by M. Tao and published by The Electrochemical Society. This book was released on 2010-02 with total page 153 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the Proceedings of ECS Symposium on Photovoltaics for the 21st Century, held in October 2009 in Vienna. The Symposium received over 50 invited and contributed papers. These papers cover major solar cell technologies, from silicon to thin films to 3rd-generation. Material synthesis and characterization, cell fabrication, and device physics and testing for various solar cell technologies are reported.

Download or read book Nanomaterials for Environmental Protection written by Boris I. Kharisov and published by John Wiley & Sons. This book was released on 2014-08-27 with total page 1449 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is divided into four main sections thoroughly analyzing the use of nanomaterials for water, air and soil solutions, and emphasizing environmental risks. Providing background on nanomaterials' two-decade study, it discusses the characterization and application of unconventional disinfectants, called antimicrobial nanomaterials, which fall into three categories and, while seemingly harmless, have potential hazards if applied improperly. Special attention is given to the process of remediation, synthetics techniques, and properties of nanomaterials, with examples to which new and trained readers in the field can relate and understand. an interdisciplinary approach, aimed at scientists in physical chemistry, nanotechnology, and environmental sciences includes applications of non-conventional techniques in environmental protection furthers the development of applied nanoscience and nanotechnology suggests new industrial projects and university courses addressing nanotechnology in and for the environment includes applications for water, air and soil protection

Download or read book Nanostructured Materials for Next Generation Energy Storage and Conversion written by Tulay Aygan Atesin and published by Springer Nature. This book was released on 2019-11-15 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Materials for Next-Generation Energy Storage and Conversion: Photovoltaic and Solar Energy, is volume 4 of a 4-volume series on sustainable energy. Photovoltaic and Solar Energy while being a comprehensive reference work, is written with minimal jargon related to various aspects of solar energy and energy policies. It is authored by leading experts in the field, and lays out theory, practice, and simulation studies related to solar energy and allied applications including policy, economic and technological challenges. Topics covered include: introduction to solar energy, fundamentals of solar radiation, heat transfer, thermal collection and conversion, solar economy, heating, cooling, dehumidification systems, power and process heat, solar power conversion, policy and applications pertinent to solar energy as viable alternatives to fossil fuels. The aim of the book is to present all the information necessary for the design and analysis of solar energy systems for engineers, material scientists, economics, policy analysts, graduate students, senior undergraduates, solar energy practitioner, as well as policy or lawmakers in the field of energy policy, international energy trade, and libraries which house technical handbooks related to energy, energy policy and applications.

Download or read book Oxide Semiconductors written by and published by Academic Press. This book was released on 2013-05-18 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiconductors and Semimetals has distinguished itself through the careful selection of well-known authors, editors, and contributors. Originally widely known as the "Willardson and Beer" Series, it has succeeded in publishing numerous landmark volumes and chapters. The series publishes timely, highly relevant volumes intended for long-term impact and reflecting the truly interdisciplinary nature of the field. The volumes in Semiconductors and Semimetals have been and will continue to be of great interest to physicists, chemists, materials scientists, and device engineers in academia, scientific laboratories and modern industry. - Written and edited by internationally renowned experts - Relevant to a wide readership: physicists, chemists, materials scientists, and device engineers in academia, scientific laboratories and modern industry

Download or read book Nanostructured Photocatalyst via Defect Engineering written by Vitaly Gurylev and published by Springer Nature. This book was released on 2021-10-28 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book helps readers comprehend the principles and fundamentals of defect engineering toward realization of an efficient photocatalyst. The volume consists of two parts, each of which addresses a particulate type of defects. The first, larger section provides a comprehensive and rigorous treatment of the behaviour and nature of intrinsic defects. The author describes how their controlled introduction and consequent manipulation over concentration, distribution, nature and diffusion is one of the most effective and practical methodologies to modify the properties and characteristics of target photocatalytic materials. The second part of the book explains the formation of extrinsic defects in the form of metallic and non-metallic dopants and gives a detailed description of their characteristics as this approach is also often used to fabricate an efficient photocatalyst. Filling the gap in knowledge on the correlation between introduction of defects in various semiconducting materials and their photocatalytic performance, the book is ideal for graduate students, academics and researchers interested in photocatalysts, defect engineering, clean energy, hydrogen production, nanoscale advanced functional materials, CO2 deactivation, and semiconductor engineering.

Download or read book High Efficiency Crystalline Silicon Solar Cells written by Eun-Chel Cho and published by MDPI. This book was released on 2021-01-06 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is composed of 6 papers. The first paper reports a novel technique for the selective emitter formation by controlling the surface morphology of Si wafers. Selective emitter (SE) technology has attracted renewed attention in the Si solar cell industry to achieve an improved conversion efficiency of passivated-emitter rear-contact (PERC) cells. In the second paper, the temperature dependence of the parameters was compared through the PERC of the industrial-scale solar cells. As a result of their analysis, PERC cells showed different temperature dependence for the fill factor loss as temperatures rose. The third paper reports the effects of carrier selective front contact layer and defect state of hydrogenated amorphous silicon passivation layer/n-type crystalline silicon interface. The results demonstrated the effects of band offset determined by band bending at the interface of the passivation layer and carrier selective front contact layer. In addition, the nc-SiOx: H CSFC layer not only reduces parasitic absorption loss but also has a tunneling effect and field-effect passivation. The fourth paper reports excimer laser annealing of hydrogenated amorphous silicon film for TOPCon solar cell application. This paper analyzes the crystallization of a-Si:H via excimer laser annealing (ELA) and compared this process with conventional thermal annealing. The fifth paper reports the contact mechanism between Ag–Al and Si and the change in contact resistance (Rc) by varying the firing profile. Rc was measured by varying the belt speed and peak temperature of the fast-firing furnace. The sixth paper reports a silicon tandem heterojunction solar cell based on a ZnO/Cu2O subcell and a c-Si bottom subcell using electro-optical numerical modeling. The buffer layer affinity and mobility together with a low conduction band offset for the heterojunction are discussed, as well as spectral properties of the device model.

Download or read book Metal Oxide Defects written by Vijay Kumar and published by Elsevier. This book was released on 2022-11-19 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Defects: Fundamentals, Design, Development and Applications provides a broad perspective on the development of advanced experimental techniques to study defects and their chemical activity and catalytic reactivity in various metal oxides. This book highlights advances in characterization and analytical techniques to achieve better understanding of a wide range of defects, most importantly, state-of-the-art methodologies for controlling defects. The book provides readers with pathways to apply basic principles and interpret the behavior of metal oxides. After reviewing characterization and analytical techniques, the book focuses on the relationship of defects to the properties and performance of metal oxides. Finally, there is a review of the methods to control defects and the applications of defect engineering for the design of metal oxides for applications in optoelectronics, energy, sensing, and more. This book is a key reference for materials scientists and engineers, chemists, and physicists. - Reviews advances in characterization and analytical techniques to understand the behavior of defects in metal oxide materials - Introduces defect engineering applied to the design of metal oxide materials with desirable properties - Discusses applications of defect engineering to enhance the performance of materials for a wide range of applications, with an emphasis on optoelectronics

Download or read book Defect Modulation Doping for Transparent Conducting Oxide Materials written by Getnet Kacha Deyu and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book International journal of research in physical chemistry chemical physics written by Karl Friedrich Bonhoeffer and published by . This book was released on 1998 with total page 904 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advanced Micro and Nanomaterials for Photovoltaics written by and published by Elsevier. This book was released on 2019-05-25 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials are becoming increasingly important photovoltaic technologies from absorbers to contacts. This book is dedicated to describing the novel materials and technologies for photovoltaics that derive from these new and novel approaches in solar technologies. We have collected a set of renowned experts in their respective fields as authors and their expertise covers a broad set of areas including novel oxides, quantum dots, CZTS and organic solar cells, as well as light management and reliability testing. The organization of the book is divided into three sections; the first part deals with emerging photovoltaic absorbers and absorber approaches, the second part is focused on novel solar cell architectures and device concepts and components; and the last part is focused on their integration into module technologies. The first chapter is an introduction to the basics of solar cells technology facilitating an understanding by the non-expert of the following chapters. The book is intended for academics and professionals, at the research and R&D level in materials and devices, who are looking for opportunities for applications in the solar materials, devices and modules areas. Hopefully it will serve as a reference for students and professionals looking into the potential and development of novel photovoltaic technologies, researchers looking into the development of innovative projects, and teachers in the field of energy and sustainability. - Showcases a range of cutting-edge photovoltaic materials and devices, exploring their special properties and how they are best used - Assesses the challenges of fabricating solar cell devices using nanotechnology - Explores how producing cheaper modules, increasing reliability and increasing efficiency have led to new applications for photovoltaic devices

Download or read book Green Photocatalytic Semiconductors written by Seema Garg and published by Springer Nature. This book was released on 2021-09-20 with total page 855 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.

Download or read book Functional Metal Oxide Nanostructures written by Junqiao Wu and published by Springer Science & Business Media. This book was released on 2011-09-22 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal oxides and particularly their nanostructures have emerged as animportant class of materials with a rich spectrum of properties and greatpotential for device applications. In this book, contributions from leadingexperts emphasize basic physical properties, synthesis and processing, and thelatest applications in such areas as energy, catalysis and data storage. Functional Metal Oxide Nanostructuresis an essential reference for any materials scientist or engineer with aninterest in metal oxides, and particularly in recent progress in defectphysics, strain effects, solution-based synthesis, ionic conduction, and theirapplications.