Download or read book Metallocenes in Regio and Stereoselective Synthesis written by Tamotsu Takahashi and published by Springer Science & Business Media. This book was released on 2005-01-12 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metallocene is a well known sandwich complex with two cyclopentadienyl ligands such as ferrocene. Recently, such metallocene compounds have been found to be very characteristic and they have become very important, not only in the area of organic synthesis, but also in polymerization in industry. Metal complexes with one cyclopentadienyl ligand have also become popular as half sandwich complexes. The number of researchers in the field of metallocenes has increased rapidly. However, the origin of the characteristic reactivity of metallocenes is not fully understood. In this volume, the chemistry of metal complexes with at least one cyclopentadienyl ligand is comprehensively covered by leading experts. Reactions discussed here are (i) natural product synthesis, (ii) catalytic asymmetric synthesis, (iii) cyclization reactions, (iv)catalytic reactions, (iv) polymerization reactions and (v) carbon-carbon bond cleavage reactions. The reader will have access to useful information about the current state of metallocene chemistry.

Download or read book Cyclopentadienyl Metal Complexes written by Julie Hyde and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Steric Influences in Cyclopentadienyl and Substituted Cyclopentadienyl Metal Complexes written by Allan John Morris and published by . This book was released on 1987 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Metallocenes An Introduction to Sandwich Complexes written by Nicholas J Long and published by Wiley-Blackwell. This book was released on 1998-02-11 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of ferrocene in the 1950s, there has been an explosion of research in this area of organometallic chemistry, and metallocene chemistry is now a part of every undergraduate chemistry course. This book, aimed at advanced-level undergraduates, postgraduates and researchers in the field, is the first comprehensive account of the theory and applications of the various types of metallocenes for the last 30 years. The book develops from chapters on all aspects of the synthesis, structure, bonding and chemistry of metallocenes, to a discussion of the uses and importance of these compounds.

Download or read book Metal Complexes written by Peter Maitlis and published by Elsevier. This book was released on 2012-12-02 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.

Download or read book Synthesis and Characterisation of Substituted Cyclopentadienyl Metal Complexes written by Bhekie Brilliance Mamba and published by . This book was released on 1999 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-02 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.

Download or read book Synthesis and Asymmetric Reactivity of Electronically and Sterically Differentiating Chiral Cyclopentadienyl Metal Complexes written by Ronald Lee Halterman and published by . This book was released on 1985 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Bioinorganic Chemistry written by Philip Aisen and published by . This book was released on 1988 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Introduction to Metal Complex Chemistry written by M. Tsutsui and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Plenum Press series, Monographs in Inorganic Chemistry, is intended to fill an obvious need for high-level surveys of recent research in that area, particularly in matters which go beyond the traditional or classical bound aries of the subject. The study of n-bonding of hydrocarbon groups (and their derivatives) to metals is exactly that kind of subject, for it provides a new way of understanding the behavior of metals (which constitute four-fifths of all the chemical elements). In addition, n-bonding has expanded the intriguing area of organometallic chemistry threefold, bringing in all the transition metals, the lanthanides, and the actinides. So much has been discovered and developed in the area of n-bonded "complexes" of the metals that important new industrial processes based on such substances have been developed. A truly comprehensive review of all n-bonded compounds of the metals would now result in an impossibly large and expensive volume, and would require monthly revision. Instead, the present authors have wisely decided to write a survey which outlines the general aspects of preparation, properties, structure, reactions, and uses of such compounds-a survey which can serve as a textbook, but which can also lead the more experienced practitioner to the most advanced literature on the subject. They have clarified and condensed the subject by means of good organization and a liberal use of diagrams-features which will please the general reader.

Download or read book Tetraphenylcyclopentadienyl Complexes of First Row Transition Metals written by Michael Paul Castellani and published by . This book was released on 1986 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of New Cyclopentadienyl and Indenyl Transition Metal Complexes written by Gloria U. Obuzor and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Synthesis and Synthetic Utility of Novel Cyclopentadienyl Metal Complexes and Reactive Fragments written by Michael Bennett Freeman and published by . This book was released on 1979 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Experimental and Theoretical Investigations of Dimeric Cyclopentadienyl Metal Tetrathiooxalato Complexes written by Mark H. Englert and published by . This book was released on 1983 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 559 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Download or read book Synthesis and Reactivity of Transition Metal Complexes Containing Pentamercurated Cyclopentadienyl Ligands written by Young Hee Han and published by . This book was released on 1993 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Comprehensive Organometallic Chemistry III Volume 3 written by D. M. P. Mingos and published by . This book was released on 2007 with total page 976 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides essential information for any chemist or technologist who needs to use or apply organometallic compounds. Provides a comprehensive overview of recent developments in the field and attempts to predict trends in the field over the next ten years.