Download or read book Crossed Molecular Beam Experiments Involving Excited Species written by Elisabeth Wallin and published by . This book was released on 1994 with total page 71 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Absolute Collisional Excitation Cross Section Measurements Using Crossed Molecular Beams written by Andrew Freedman and published by . This book was released on 1983 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: The measurement of absolute excitation cross-sections of the asymmetric stretch mode (001) of H20 and C02 for collisions with atomic oxygen is important in understanding the signatures of high-altitude rocket plumes. Experiments are performed in a crossed molecular beam apparatus in which a CVF detector measures the collisionally-induced infrared fluorescent signal. Calibration and testing of the atomic oxygen source was completed. It was installed into the crossed beam apparatus and vacuum tested in preparation for performing the excitation cross-section measurements. Upper limits have been established for the excitation cross sections for the systems 0 + C02 and Ar + C02. The values determined are 0.03A squared for 0 + C02 at 3.85 km/sec and 0.003 A squared for Ar + C02 at 2.27 km/sec. Monte Carlo trajectory analysis of the data provides accurate correction factors to the raw data that account for kinematic and experimental constraints inherent in these measurements. It further shows that measurements near threshold cannot be used to determine the functional energy dependence of the cross section. Further modifications and improvements in the experimental approaches to improve sensitivity will be discussed.

Download or read book Absolute Collisional Excitation Cross Section Measurements Using Crossed Molecular Beams written by and published by . This book was released on 1983 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Experiments with Crossed Molecular Beams and Tunable Laser Intramultiplet Mixing written by Terrence P. Goddard and published by . This book was released on 1973 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Molecular Beam Experiments and Theoretical Studies on the Dynamics and Photochemistry of Several Small Molecules written by Preston Garrieth Scrape and published by . This book was released on 2017 with total page 169 pages. Available in PDF, EPUB and Kindle. Book excerpt: These experimental and computational studies characterize the dynamics and thermochemistry of several species that are important in atmospheric, combustion, and interstellar chemistry. The species are selected both as interesting problems in their own right, and as proxies that give insight into even more complex problems. In crossed laser-molecular beam experiments, the uv photochemistry of BrCH2CH2ONO and CH2Cl2 are probed, revealing rich excited-state dynamics including the unexpected photoelimination of HNO from BrCH2CH2ONO and an unusual trimodal kinetic energy release in HCl photoelimination from CH2Cl2. In the case of CH2Cl2, C-Cl photofission produces the CH2Cl radical, allowing a first characterization of its photoionization cross section. BrCH2CH2ONO also generates the openshell nitrite CH2CH2ONO, which is found to dissociate predominately via its lowest-barrier pathway to NO2 + ethene; however, this radical evinces significant dissociation to HNO + vinoxy, even though the barrier to this process (calculated at the G4/B3LYP/6-311++G(3df,2p) level of theory) is prohibitively high. This result implies a non-intrinsic reaction coordinate pathway to HNO that circumvents the classical transition state; thus, HNO production from nitrite radicals is likely a more important channel than was previously believed. In a theoretical study, a new model of energy partitioning in dissociation reactions is developed that estimates the distribution of vibrational energy based solely on the intrinsic reaction coordinate surface; the predictions of this model are found to agree quite well with experimental measurements in the case of HCl photoelimination from acryloyl chloride. Finally, in support of future dynamics studies, a novel composite thermochemical protocol is assessed by calculating the singlet-triplet gap of CH2 and the dissociation threshold of (H2O)2. The protocol agrees exceptionally well with experimental values, giving confidence that it may be applied to other systems.

Download or read book A Molecular Beam Experiment Using Laser Excited SF6 Molecules written by Eric Weitz and published by . This book was released on 1968 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reaction Dynamics Involving Ions Radicals Neutral and Excited Species written by Stefano Falcinelli and published by Frontiers Media SA. This book was released on 2020-01-22 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Crossed Molecular Beam Studies of Chemiluminescent Reactions written by Carol Cuzens Kahler and published by . This book was released on 1980 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1987 with total page 964 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976-03 with total page 938 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Crossed Molecular Beam and Tunable Laser Apparatus Applied to Reactive Scattering Studies written by Carlo Parravano and published by . This book was released on 1974 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Crossed Molecular Beam Study Rotational Excitation of HD J written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The observation is reported of rotationally inelastic scattering in the He + HD system in a crossed molecular beam experiment conducted at a collision energy of 19.3 MeV, low enough that only the J = 0 .-->. J = 1 rotational excitation occurs. (GHT).

Download or read book Research and Development in Progress written by and published by . This book was released on 1973 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book FY US Air Force Plan for Defense Research Sciences written by and published by . This book was released on 1984 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Excited State in Chemical Physics Volume 45 Part 2 written by J. W. McGowan and published by John Wiley & Sons. This book was released on 2009-09-08 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

Download or read book Investigation of Excited Electronic Species Using Molecular Beam Techniques written by Thomas Andrew Davidson and published by . This book was released on 1973 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Femtochemistry Ultrafast Dynamics Of The Chemical Bond In 2 Volumes Volume 1 written by Ahmed H Zewail and published by World Scientific. This book was released on 1994-09-12 with total page 605 pages. Available in PDF, EPUB and Kindle. Book excerpt: These two volumes on Femtochemistry present a timely contribution to a field central to the understanding of the dynamics of the chemical bond. This century has witnessed great strides in time and space resolutions, down to the atomic scale, providing chemists, biologists and physicists with unprecedented opportunities for seeing microscopic structures and dynamics. Femtochemistry is concerned with the time resolution of the most elementary motions of atoms during chemical change - bond breaking and bond making - on the femtosecond (10-15 second) time scale. This atomic scale of time resolution has now reached the ultimate for the chemical bond and as Lord George Porter puts it, chemists are near the end of the race against time. These two volumes cover the general concepts, techniques and applications of femtochemistry.Professor Ahmed Zewail, who has made the pioneering contributions in this field, has from over 250 publications selected the articles for this anthology. These volumes begin with a commentary and a historical chronology of the milestones. He then presents a broad perspective of the current state of knowledge in femtochemistry by researchers around the world and discusses possible new directions. In the words of a colleague, ';it is a must on the reading-list for all of my students ...; all readers will find this to be an informative and valuable overview.';The introductory articles in Volume I provide reviews for both the non-experts as well as for experts in the field. This is followed by papers on the basic concepts. For applications, elementary reactions are studied first and then complex reactions. Volume I is complete with studies of solvation dynamics, non-reactive systems, ultrafast electron diffraction and the control of chemical reactions.Volume II continues with reaction rates, the concept of elementary intramolecular vibrational-energy redistribution (IVR) and the phenomena of rotational coherence which has become a powerful tool for the determination of molecular structure via time resolution. The second volume ends with an extensive list of references, according to topics, based on work by Professor Zewail and his group at Caltech.These collected works by Professor Zewail will certainly be indispensable to both experts and beginners in the field. The author is known for his clarity and for his creative and systematic contributions. These volumes will be of interest and should prove useful to chemists, biologists and physicists. As noted by Professor J Manz (Berlin) and Professor A W Castleman, Jr. (Penn State): femtochemistry is yielding exciting new discoveries from analysis to control of chemical reactions, with applications in many domains of chemistry and related fields, e.g., physical, organic and inorganic chemistry, surface science, molecular biology, ...; etc.