Download or read book Clean Synthesis Using Porous Inorganic Solid Catalysts and Supported Reagents written by James H Clark and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt: Waste minimisation has a number of aims which include enhancing the intrinsic selectivity of any given process, providing a means of recovering reagents in a form which allows easy regeneration and the replacement of stoichiometric processes with catalytic ones. Solids, as catalysts or as supports for other reagents, offer potential for benefit in all these areas. This monograph provides an overview of the properties of the more useful solid catalysts and supported reagents, and highlights their most valuable applications in the preparation of organic chemicals in liquid phase reactions. Clean Synthesis Using Porous Inorganic Solid Catalysts and Supported Reagents is concerned with the use of solid catalysts in the clean synthesis of organic chemicals. The emphasis is on chemical processes of importance to the manufacture/preparation of fine and speciality chemicals, chemical intermediates and pharmaceutical intermediates, especially where catalysis is not currently used or where current catalysts are homogeneous, leading to difficult separation procedures and unacceptable levels of waste. This book focuses on solid catalysts based on inorganic supports and covers the emerging area of chemically modified mesoporous solid catalysts.
Download or read book Introduction to Green Chemistry written by John Andraos and published by CRC Press. This book was released on 2022-03-10 with total page 1406 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interest in green chemistry and clean processes has grown so much in recent years that topics such as fluorous biphasic catalysis, metal organic frameworks, and process intensification, which were barely mentioned in the First Edition, have become major areas of research. In addition, government funding has ramped up the development of fuel cells and biofuels. This reflects the evolving focus from pollution remediation to pollution prevention. Copiously illustrated with more than 800 figures, the Third Edition provides an update from the frontiers of the field. It features supplementary exercises at the end of each chapter relevant to the chemical examples introduced in each chapter. Particular attention is paid to a new concluding chapter on the use of green metrics as an objective tool to demonstrate proof of synthesis plan efficiency and to identify where further improvements can be made through fully worked examples relevant to the chemical industry. NEW AND EXPANDED RESEARCH TOPICS Metal-organic frameworks Metrics Solid acids for alkylation of isobutene by butanes Carbon molecular sieves Mixed micro- and mesoporous solids Organocatalysis Process intensification and gas phase enzymatic reactions Hydrogen storage for fuel cells Reactive distillation Catalysts in action on an atomic scale UPDATED AND EXPANDED CURRENT EVENTS TOPICS Industry resistance to inherently safer chemistry Nuclear power Removal of mercury from vaccines Removal of mercury and lead from primary explosives Biofuels Uses for surplus glycerol New hard materials to reduce wear Electronic waste Smart growth The book covers traditional green chemistry topics, including catalysis, benign solvents, and alternative feedstocks. It also discusses relevant but less frequently covered topics with chapters such as "Chemistry of Long Wear" and "Population and the Environment." This coverage highlights the importance of chemistry to everyday life and demonstrates the benefits the expanded exploitation of green chemistry can have for society.
Download or read book Design And Applications Of Single site Heterogeneous Catalysts Contributions To Green Chemistry Clean Technology And Sustainability written by John Meurig Thomas and published by World Scientific Publishing Company. This book was released on 2012-04-16 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: For far too long chemists and industrialists have relied on the use of aggressive reagents such as nitric and sulphuric acids, permanganates and dichromates to prepare the massive quantities of both bulk and fine chemicals that are needed for the maintenance of civilised life — materials such as fuels, fabrics, foodstuffs, fertilisers and pharmaceuticals. Such aggressive reagents generate vast quantities of environmentally harmful and often toxic by-products, including the oxides of nitrogen, of metal oxides and carbon dioxide.Now, owing to recent advances made in the synthesis of nanoporous solids, it is feasible to design new solid catalysts that enable benign, mild oxidants to be used, frequently without utilising solvents, to manufacture the products that the chemical, pharmaceutical, agro- and bio-chemical industries require. These new solid agents are designated single-site heterogeneous catalysts (SSHCs). Their principal characteristics are that all the active sites present in the high-area solids are identical in their atomic environment and hence in their energy of interaction with reactants, just as in enzymes.Single-site heterogeneous catalysts now occupy a position of growing importance both academically and in their potential for commercial exploitation. This text, the only one devoted to such catalysts, dwells both on principles of design and on applications, such as the benign synthesis of nylon 6 and vitamin B3. It equips the reader with unifying insights required for future catalytic adventures in the quest for sustainability in the materials used by humankind.Anyone acquainted with the language of molecules, including undergraduates in the physical and biological sciences, as well as graduates in engineering and materials science, should be able to assimilate the principles and examples presented in this book. Inter alia, it describes how clean technology and ‘green’ processes may be carried out in an environmentally responsible manner.
Download or read book Solid Supports and Catalysts in Organic Synthesis written by K. Smith and published by Prentice Hall. This book was released on 1992 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Reactions and Processes Under Flow Conditions written by Santíago V. Luis and published by Royal Society of Chemistry. This book was released on 2010 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt: On the contrary, flow continuous processes present a series of advantages leading to new ways to synthesise chemical products.
Download or read book Supported Catalysts and Their Applications written by David C Sherrington and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: The need to improve both the efficiency and environmental acceptability of industrial processes is driving the development of heterogeneous catalysts across the chemical industry, including commodity, specialty and fine chemicals and in pharmaceuticals and agrochemicals. Drawing on international research, Supported Catalysts and their Applications discusses aspects of the design, synthesis and application of solid supported reagents and catalysts, including supported reagents for multi-step organic synthesis; selectivity in oxidation catalysis; mesoporous molecular sieve catalysts; and the use of Zeolite Beta in organic reactions. In addition, the two discrete areas of heterogeneous catalysis (inorganic oxide materials and polymer-based catalysts) that were developing in parallel are now shown to be converging, which will be of great benefit to the whole field. Providing a snapshot of the state-of-the-art in this fast-moving field, this book will be welcomed by industrialists and researchers, particularly in the agrochemicals and pharmaceuticals industries.
Download or read book Modern Applications of High Throughput R D in Heterogeneous Catalysis written by Alfred Hagemeyer and published by Bentham Science Publishers. This book was released on 2014-04-04 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: This eBook covers the application of high-throughput R&D to both fundamental and applied catalysis including catalyst synthesis, characterization, and testing in various reactor types. Chapters include topics such as applications ranging from optimizations of established industrial catalysts to the discovery of innovative new materials, examples of the development of innovative parallel characterization methods, and cases of real catalyst testing in small scale reactor systems. Readers will also find chapters that cover commodity chemicals produced using continuous gas phase processes as well as fine chemicals produced in liquid phase batch reactors. The potential of industrial chemicals production from biorenewable feedstocks is also presented. The steadily improving high throughput workflows are today being applied to relevant reactions and targets such as hydrotreating, Deacon oxidation, Fischer-Tropsch, propane dehydrogenation, C4 oxidation, methane coupling, exhaust gas catalysis, bio-based Nylon, fuel cells and vitamins. The topics presented in this eBook have been contributed by researchers from academia as well as industry, making this eBook a well-balanced reference, which could be of particular interest to professional, industrial or service R&D labs.
Download or read book Innovations in Green Chemistry and Green Engineering written by Paul T. Anastas and published by Springer Science & Business Media. This book was released on 2012-12-13 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Processes that meet the objectives of green chemistry and chemical engineering minimize waste and energy use, and eliminate toxic by-products. Given the ubiquitous nature of products from chemical processes in our lives, green chemistry and chemical engineering are vital components of any sustainable future. Gathering together ten peer-reviewed articles from the Encyclopedia of Sustainability Science and Technology, Innovations in Green Chemistry and Green Engineering provides a comprehensive introduction to the state-of-the-art in this key area of sustainability research. Worldwide experts present the latest developments on topics ranging from organic batteries and green catalytic transformations to green nanoscience and nanotoxicology. An essential, one-stop reference for professionals in research and industry, this book also fills the need for an authoritative course text in environmental and green chemistry and chemical engineering at the upper-division undergraduate and graduate levels.
Download or read book Clean Energy written by R M Dell and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clean Energy presents a broad survey of the energy problems facing society over the coming decades and the prospects for their solution. The book emphasizes the importance of developing a strategy for the world's future energy supply. The strategy must take into account: the finite supplies of natural gas and petroleum; the increased consumption of fuel by developing economies; the concern over greenhouse gas emissions; the pollution caused by burning coal (especially coal with a high sulphur content); the difficulties and costs of extracting unconventional fossil fuels; and the technical, sociological and cost barriers that restrict the use of renewable forms of energy. Clean Energy sets the various renewable energies (wind, waves, solar etc) in the context of present and projected world production of energy and its use in the time-frame until 2020 and looks speculatively beyond that. It looks at the possibilities for reducing pollution from fossil fuels and tackles the serious problem of how to store energy, in order to smooth out fluctuations in supply and demand. Clean Energy is well illustrated with diagrams and photographs. It is accessible to anyone who has studied science to A-level and will appeal to anyone with a serious interest in environmental matters, and the interaction between energy usage and the environment.
Download or read book Introduction to Green Chemistry written by Albert Matlack and published by CRC Press. This book was released on 2010-04-05 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book covers traditional green chemistry topics, including catalysis, benign solvents, and alternative feedstocks. It also discusses relevant but less frequently covered topics with chapters such as Chemistry of Longer Wear and Population and the Environment. This coverage highlights the importance of chemistry to everyday life and demonstrates the benefits the expanded exploitation of green chemistry can have for society. Copiously illustrated with over 800 figures, this second edition provides an update from the frontiers of the field.
Download or read book Green Chemistry written by Mike Lancaster and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: The challenge for today's new chemistry graduates is to meet society's demand for new products that have increased benefits, but without detrimental effects on the environment. Green Chemistry: An Introductory Text outlines the basic concepts of the subject in simple language, looking at the role of catalysts and solvents, waste minimisation, feedstocks, green metrics and the design of safer, more efficient, processes. The inclusion of industrially relevant examples throughout demonstrates the importance of green chemistry in many industry sectors. Intended primarily for use by students and lecturers, this book will also appeal to industrial chemists, engineers, managers or anyone wishing to know more about green chemistry.
Download or read book The Sulfur Problem written by Diane Stirling and published by Royal Society of Chemistry. This book was released on 2000 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur compounds contaminate many industrially important feedstocks and, on release to the atmosphere as sulfur oxides, can cause widespread damage to the ecosystem. The main objectives of The Sulfur Problem: Cleaning Up Industrial Feedstocks are to demonstrate the importance of eliminating sulfur contaminants from the environment and the measures necessary to effect this. Using a systematic and pedagogical approach, the reader is first presented with the problem. Current technology for solving it is then outlined together with appropriate theory on the synthesis, structure and sorption behaviour of the materials used. Relevant characterisation techniques are described with reference to typical sorbents, to demonstrate how the sorption behaviour of the materials correlates with their properties. The book is unique in blending together aspects of environmental chemistry, materials/solid state chemistry, surface chemistry, catalysis and separation processes to address the problem of sulfur contaminants in a wide range of feedstocks.
Download or read book The Chemistry of Peroxides Volume 3 written by and published by John Wiley & Sons. This book was released on 2015-04-20 with total page 957 pages. Available in PDF, EPUB and Kindle. Book excerpt: The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Download or read book Nanotechnology Research written by Xiaohua J. Huang and published by Nova Publishers. This book was released on 2008 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanotechnology is a 'catch-all' description of activities at the level of atoms and molecules that have applications in the real world. A nanometer is a billionth of a meter, about 1/80,000 of the diameter of a human hair, or 10 times the diameter of a hydrogen atom. Nanotechnology is now used in precision engineering, new materials development as well as in electronics; electromechanical systems as well as mainstream biomedical applications in areas such as gene therapy, drug delivery and novel drug discovery techniques. This book presents new and important breakthroughs in the field from around the world.
Download or read book Liquid Phase Oxidation via Heterogeneous Catalysis written by Mario G. Clerici and published by John Wiley & Sons. This book was released on 2013-04-26 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.
Download or read book Catalysis for Clean Energy and Environmental Sustainability written by K. K. Pant and published by Springer Nature. This book was released on 2021-05-13 with total page 933 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is part of a two-volume work that offers a unique blend of information on realistic evaluations of catalyst-based synthesis processes using green chemistry principles and the environmental sustainability applications of such processes for biomass conversion, refining, and petrochemical production. The volumes provide a comprehensive resource of state-of-the-art technologies and green chemistry methodologies from researchers, academics, and chemical and manufacturing industrial scientists. The work will be of interest to professors, researchers, and practitioners in clean energy catalysis, green chemistry, chemical engineering and manufacturing, and environmental sustainability. This volume focuses on the potentials, recent advances, and future prospects of catalysis for biomass conversion and value-added chemicals production via green catalytic routes. Readers are presented with a mechanistic framework assessing the development of product selective catalytic processes for biomass and biomass-derived feedstock conversion. The book offers a unique combination of contributions from experts working on both lab-scale and industrial catalytic processes and provides insight into the use of various catalytic materials (e.g., mineral acids, heteropolyacid, metal catalysts, zeolites, metal oxides) for clean energy production and environmental sustainability.
Download or read book Catalysis from A to Z written by Boy Cornils and published by Wiley-VCH. This book was released on 2007 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: