Download or read book Making and Breaking Symmetry in Chemistry written by Michael J McGlinchey and published by World Scientific Publishing Company. This book was released on 2023-11 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The elucidation of reaction mechanisms generally requires the carefully designed control of molecular symmetry to distinguish between the many possible reaction pathways. Making and Breaking Symmetry in Chemistry emphasises the crucial role played by symmetry in modern synthetic chemistry. After discussion of a number of famous classical experiments, the advances brought about by the introduction of new techniques, in particular NMR spectroscopy, are exemplified in numerous cases taken from the recent literature. Experimental verification of many of the predictions made in Woodward and Hoffmann's explication of the Conservation of Orbital Symmetry are described. Applications that involve the breaking of molecular symmetry to resolve these and other mechanistic problems in organic, inorganic and organometallic chemistry are presented in the first sections of the book, together with many examples of the detection of hitherto hidden rearrangement processes. Subsequently, under the aegis of making molecular symmetry, examples of the preparation of highly symmetrical molecules found in the organic, organometallic or inorganic domains are discussed. These include Platonic hydrocarbons or boranes, tetrahedranes, cubanes, prismanes, dodecahedrane, fullerene fragments such as corannulene, sumanene or semibuckminsterfullerene, and other systems of unusual geometries or bonding characteristics (Möbius strips, molecular brakes and gears, Chauvin's carbomers, Fitjer's rotanes, persubstituted rings, metal-metal multiple bonds, etc.). The text also contains vignettes of many of the scientists who made these major advances, as well as short sections that briefly summarise key features of important topics that underpin the more descriptive material. These include some aspects of chirality, NMR spectroscopy, and the use of isotopic substitution to break molecular symmetry. A brief appendix on point group symmetry and nomenclature is also helpfully provided.
Download or read book Chemical Symmetry Breaking written by Rui Tamura and published by Mdpi AG. This book was released on 2021-07-26 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book entitled "Chemical Symmetry Breaking" is a collective volume of state-of-the-art reports on unique nonlinear chemical and physical symmetry-breaking phenomena that were experimentally observed upon a thermally or photochemically induced phase transition in various organic condensed phases, such as metastable liquid crystals, crystals, amorphous solids, and colloidal polymer materials, only under nonequilibrium conditions. Each author summarizes the introductory section in simple terms but in detail for beginners in this field. We wish that many readers familiarize themselves with the general concepts and features of nonlinear and nonequilibrium (or out of equilibrium) complexity theory, which govern a variety of unique dynamic behaviors observed in chemistry, physics, life science and other fields, so that they may discover novel symmetry-breaking phenomena in their own research areas.
Download or read book Molecular Symmetry written by David J. Willock and published by John Wiley & Sons. This book was released on 2009-03-16 with total page 441 pages. Available in PDF, EPUB and Kindle. Book excerpt: Symmetry and group theory provide us with a formal method for the description of the geometry of objects by describing the patterns in their structure. In chemistry it is a powerful method that underlies many apparently disparate phenomena. Symmetry allows us to accurately describe the types of bonding that can occur between atoms or groups of atoms in molecules. It also governs the transitions that may occur between energy levels in molecular systems, which in turn allows us to predict the absorption properties of molecules and hence their spectra. Molecular Symmetry lays out the formal language used in the area using illustrative examples of particular molecules throughout. It then applies the ideas of symmetry to describe molecular structure, bonding in molecules and consider the implications in spectroscopy. Topics covered include: Symmetry elements Symmetry operations and products of operations Point groups used with molecules Point group representations, matrices and basis sets Reducible and irreducible representations Applications in vibrational spectroscopy Symmetry in chemical bonding Molecular Symmetry is designed to introduce the subject by combining symmetry with spectroscopy in a clear and accessible manner. Each chapter ends with a summary of learning points, a selection of self-test questions, and suggestions for further reading. A set of appendices includes templates for paper models which will help students understand symmetry groups. Molecular Symmetry is a must-have introduction to this fundamental topic for students of chemistry, and will also find a place on the bookshelves of postgraduates and researchers looking for a broad and modern introduction to the subject.
Download or read book Physical Biology written by Ahmed H. Zewail and published by World Scientific. This book was released on 2008 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: Addresses significant problems in physical biology and adjacent disciplines. This volume provides a perspective on the methods and concepts at the heart of chemical and biological behavior, covering the topics of visualization; theory and computation for complexity; and macromolecular function, protein folding, and protein misfolding
Download or read book Making And Breaking Symmetry In Chemistry Syntheses Mechanisms And Molecular Rearrangements written by Michael James Mcglinchey and published by World Scientific. This book was released on 2022-03-09 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: The elucidation of reaction mechanisms generally requires the carefully designed control of molecular symmetry to distinguish between the many possible reaction pathways. Making and Breaking Symmetry in Chemistry emphasises the crucial role played by symmetry in modern synthetic chemistry. After discussion of a number of famous classical experiments, the advances brought about by the introduction of new techniques, in particular NMR spectroscopy, are exemplified in numerous cases taken from the recent literature. Experimental verification of many of the predictions made in Woodward and Hoffmann's explication of the Conservation of Orbital Symmetry are described. Applications that involve the breaking of molecular symmetry to resolve these and other mechanistic problems in organic, inorganic and organometallic chemistry are presented in the first sections of the book, together with many examples of the detection of hitherto hidden rearrangement processes.Subsequently, under the aegis of making molecular symmetry, examples of the preparation of highly symmetrical molecules found in the organic, organometallic or inorganic domains are discussed. These include Platonic hydrocarbons or boranes, tetrahedranes, cubanes, prismanes, dodecahedrane, fullerene fragments such as corannulene, sumanene or semibuckminsterfullerene, and other systems of unusual geometries or bonding characteristics (Möbius strips, molecular brakes and gears, Chauvin's carbomers, Fitjer's rotanes, persubstituted rings, metal-metal multiple bonds, etc.). The text also contains vignettes of many of the scientists who made these major advances, as well as short sections that briefly summarise key features of important topics that underpin the more descriptive material. These include some aspects of chirality, NMR spectroscopy, and the use of isotopic substitution to break molecular symmetry. A brief appendix on point group symmetry and nomenclature is also helpfully provided.
Download or read book Symmetry and Symmetry Breaking in Chemistry written by Wolfgang Kliesch and published by . This book was released on 2024-12-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work points out which important part symmetry of molecules and the breaking of symmetry im molecular systems plays in chemical reactions. After a thorough mathematical treatment of isometry groups and bifurcation subgroups it finally describes some interesting examples.
Download or read book Dynamical Symmetry Breaking in Molecules and Molecular Aggregates written by Günter Maximilian Schmid and published by . This book was released on 1994 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Amplification of Chirality written by Kenso Soai and published by Springer Science & Business Media. This book was released on 2008-07-11 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: Amplification of Chirality presents critical reviews of the present position and future trends in modern chemical research. The book contains short and concise reports on chemistry. Each is written by the world renowned experts. Still valid and useful after 5 or 10 years, more information as well as the electronic version of the whole content available at: springerlink.com.
Download or read book Symmetry Breaking in Biology written by Rong Li and published by . This book was released on 2010 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Experts examine the mechanisms by which cells polarize, divide asymmetrically, and produce asymmetric structures, providing examples from bacteria, yeast, plants, invertebrates, and mammals. Discussion include the molecular basis of polarization, mechanisms, and more.
Download or read book Patterns of Symmetry Breaking written by Henryk Arodz and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: The conceptofspontaneous symmetry breaking plays a fundamental role in contemporary physics. It is essential for the description of degenerate ground states, massless modes, and topological defects. Examples are abundant in condensed matter physics, atomic and particle physics, as well as in astro physics and cosmology. In fact, spontaneous symmetry breaking can be re garded as a cornerstone ofa whole branch ofphysics which intersects the above mentioned traditionally distinct fields. In the year 2000 the European Science Foundation (ESF) started the Pro gramme "Cosmology in the Laboratory" (COSLAB), with the goal to search for and to develop analogies betweencondensed matterphysics, particle physics, and cosmology. Not surprisingly, spontaneous symmetry breaking is among the most useful notions in that endeavour. It has been decided that in the sec ond year of the Programme a School should be held in order to work out and deliver to a wide audience of students synthetic overviews of achievements and of current research topics of COSLAB. This idea has been supported by the Scientific and Environmental Affairs Division of NATO by including the School in the renowned series of its Advanced Study Institutes. The School, entitled" Patterns of Symmetry Breaking", was held in Cracow during 16-28 September 2002. It gathered 17 lecturers and about 60 students. The present volume contains notes ofmost of the lectures from that School. We hope that of the physics of spon it will convey to the reader the breadth and the beauty taneous symmetry breaking.
Download or read book Chiral Nanomaterials written by Zhiyong Tang and published by John Wiley & Sons. This book was released on 2018-03-05 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thorough and up-to-date, this book presents recent developments in this exciting research field. To begin with, the text covers the fabrication of chiral nanomaterials via various synthesis methods, including electron beam lithography, ion beam etching, chemical synthesis and biological DNA directed assembly. This is followed by the relevant theory and reaction mechanisms, with a discussion of the characterization of chiral nanomaterials according to the optical properties of metal nanoparticles, semiconductor nanocrystals, and nanoclusters. The whole is rounded off by a summary of applications in the field of catalysis, sensors, and biomedicine. With its comprehensive yet concise coverage of the whole spectrum of research, this is invaluable reading for senior researchers and entrants to the field of nanoscience and materials science.
Download or read book The Autonomy of Chemistry written by Peter Janich and published by Königshausen & Neumann. This book was released on 1998 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Progress in Ultrafast Intense Laser Science XIV written by Kaoru Yamanouchi and published by Springer. This book was released on 2018-12-28 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: This 14th volume in the PUILS series presents up-to-date reviews of advances in Ultrafast Intense Laser Science, an interdisciplinary research field spanning atomic and molecular physics, molecular science, and optical science, which has been stimulated by the rapid developments in ultrafast laser technologies. Each chapter begins with an overview of the topics to be discussed, so that researchers unfamiliar to the subfield, as well as graduate students, can grasp the importance and appeal of the respective subject matter; this is followed by reports on cutting-edge discoveries. This volume covers a broad range of topics from this interdisciplinary field, e.g. atoms and molecules interacting in intense laser fields, laser-induced filamentation, high-order harmonics generation, and high-intensity lasers and their applications.
Download or read book Handbook of High resolution Spectroscopy written by Martin Quack and published by John Wiley & Sons. This book was released on 2011-09-26 with total page 2236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications
Download or read book Morphogenesis Deconstructed written by Len Pismen and published by Springer Nature. This book was released on 2020-01-02 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about morphogenesis as the genesis of forms. It is not restricted to plants growing from seed or animals developing from an embryo (although these do supply the most abundant examples) but also addresses kindred processes, from inorganic to social to biomorphic technology. It is about our morphogenetic universe: unplanned, unfair and frustratingly complicated but benevolent in allowing us to emerge, survive, and inquire into its laws.
Download or read book Broken Symmetries written by Leopold Mathelitsch and published by Springer. This book was released on 1999-03-10 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rapid and continuing growth on liquid crystal research is not only the result of the high success of liquid crystal display technology, but also because of the great potential for new and improved applications. This is a unique area of scientific research in which the joint research efforts of chemists, physicists and material scientists have led to spectacular practical developments which are been exploited commercially. This two-volume set of the series Structure and Bonding focuses on the structural properties of liquid crystals. The balanced, in-depth coverage of both theoretical and experimental aspects by leading experts serves as a basis for further innovations in this dynamic field and makes these volumes an essential resource for both academic and industrial researchers.
Download or read book Broken Symmetry written by T. Eguchi and published by World Scientific. This book was released on 1995 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text contains selected papers of the particle theorist, Professor Nambu. It comprises about 40 papers which made fundamental contributions to our understanding of particle physics during the last few decades. The unpublished lecture note on string theory (1969) and the first paper on spontaneous symmetry breaking (1961) are retyped and included. The book also contains a memoir of Professor Nambu on his research career.
