Download or read book Characterisation and Reactivity of Thermal and Photo assisted Charge Transfer Processes in TiO2 written by Charles Jenkins and published by . This book was released on 1998 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Photoredox Reactivity of Titanium oxo Clusters written by Seb Pike and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-oxo clusters have exciting potential to act as new photocatalysts or as precursors to important materials. Their well-defined structures and reactivites can also give insight into photo-activated processes that occur at the surface of bulk oxide semiconductors. In this presentation we explore the photo-redox reactivity of titanium-oxo-alkoxide clusters. Even the smallest titanium-oxo clusters (with 4 titanium atoms) are able to absorb UV light via an oxo to metal charge transfer - analogous to a valence band to conduction band excitation in TiO2. Despite their small sizes we show that charge separation and productive photochemistry can still occur. The mechanism of photo-reaction is probed by spectroscopic methods and mixed valent Ti(III)/Ti(IV)-oxo cluster products, with two ferromagentically coupled d-electrons, are identified and characterised using X-ray crystallography. The photo-redox process is shown to occur via an intramolecular, solvent assisted, two-electron pathway indicating the participation of both the metal oxo core and surface organic substituents. Subsequent re-oxidation of the photo-reduced products is also investigated under air. Such processes allow the detailed mechanism of photo-reduction and photocatalysis to be explored in atomically precise molecules, shining light on materials chemistry by using molecular techniques.
Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 2005 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Characterisation and Reactivity of Thermal and Photo generated Surface Defects and Radical Centres Over TiO2 written by Anna Lisa Attwood and published by . This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Materials Science in Photocatalysis written by Elisa I. Garcia Lopez and published by Elsevier. This book was released on 2021-08-15 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: Materials Science in Photocatalysis provides a complete overview of the different semiconductor materials, from titania to third-generation photocatalysts, examining the increasing complexity and novelty of the materials science in photocatalytic materials. The book describes the most recommended synthesis procedure for each of them and the suitable characterization techniques for determining the optical, structural, morphological, and physical-chemical properties. The most suitable applications of the photocatalysts are described in detail, as well as their environmental applications for wastewater treatment, gaseous effluents depollution, water splitting, CO2 ?xation, selective organic synthesis, coupling reactions, and other selective transformations under both UV light and visible-light irradiation. This book offers a useful reference for a wide audience from students studying chemical engineering and materials chemistry to experienced researchers working on chemical engineering, materials science, materials engineering, environment engineering, nanotechnology, and green chemistry. - Includes a complete overview of the different semiconductor materials used as photocatalysts - Describes methods of preparation and characterization of photocatalysts and their applications - Examines new possibilities to prepare effective photocatalysts
Download or read book Environmentally Benign Photocatalysts written by Masakazu Anpo and published by Springer Science & Business Media. This book was released on 2010-11-11 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past few decades, mankind has observed an unprecedented and remarkable growth in industry, resulting in a more prosperous lifestyle for peoples of many countries. In developing countries, however, explosive industrial growth is just now beginning to raise the living standards of the people. Most industries, especially in these developing countries, are still powered by the burning of fossil fuels; con- quently, a lack of clean energy resources has caused environmental pollution on an unprecedented large and global scale. Toxic wastes have been relentlessly released into the air and water leading to serious and devastating environmental and health problems while endangering the planet and life itself with the effects of global warming. To address these urgent environmental issues, new catalytic and photocatalytic processes as well as open-atmospheric systems are presently being developed that can operate at room temperature while being totally clean and ef?cient and thus environmentally harmonious. Essential to technologies harnessing the abundant solar energy that reaches the earth are the highly functional photocatalytic proce- es that can utilize not only UV light, but also visible light.
Download or read book TiO2 Photocatalysis written by Akira Fujishima and published by . This book was released on 1999 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Photocatalytic Systems by Design written by Mohan Sakar and published by Elsevier. This book was released on 2021-08-14 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalytic Systems by Design: Materials, Mechanisms and Applications explores various aspects of photocatalysis, including the photocatalytic phenomenon and process, applications, and the design of photocatalysts via band gap engineering. The book also covers band edge position engineering for multiple photocatalytic applications, such as pollutant degradations, hydrogen production, CO2 reduction into hydrocarbon fuels, antimicrobial disinfections, organic synthesis, N2 fixation, and more. This book is designed to enable beginners to learn the concepts and applications of photocatalysis. Unlike conventional books on photocatalysis, the book provides a 360° perspective into the field of photocatalysis and serves as an informative handbook for all audiences. - Addresses all concepts and applications of photocatalysis - Covers the fundamentals, including mechanisms of photocatalytic materials - Describes the various material systems and engineering of photocatalysts - Offers insight into the schemes for photocatalysis of various materials - Discusses the application-specific design of photocatalysts
Download or read book Heterogeneous Photocatalysis written by Giuseppe Marcì and published by Elsevier. This book was released on 2019-02-21 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous Photocatalysis: Relationships with Heterogeneous Catalysis and Perspectives highlights the differences between thermal-catalysis and photo-catalysis and indicates borderlines, in particular, the possible synergism between them. The book outlines the basic aspect of thermal- and photo-catalysis, along with the most important characterization techniques. In addition, it presents case studies of thermal-catalytic and photo-catalytic or thermal-photo-catalytic reactions and includes a comparison between the results obtained using an inorganic solid as thermal catalyst and photocatalyst for the same reaction, and in the same setup. Final sections offer information on the preparation methods of (photo)catalysts, various techniques used for their characterization, engineering and economical aspects. This book will be a valuable reference source for students and researchers involved in heterogeneous photocatalysis and catalysis, chemistry, chemical engineering, materials science, materials engineering, environment engineering, nanotechnology and green chemistry. - Provides selective methods for the preparation of microcrystalline/nanocrystalline solids or films used in catalytic and photocatalytic processes - Describes (photo)reactions that can be carried out catalytically and/or photocatalytically - Outlines the different mechanisms, yields and experimental conditions under which photocatalytic reactions can take place - Describes various (photo)reactors and set ups under which the photacatalytic reactions can be carried out - Provides an economic assessment to understand the feasibility of some photocatalytic reactions
Download or read book Nanostructured Photocatalyst via Defect Engineering written by Vitaly Gurylev and published by Springer Nature. This book was released on 2021-10-28 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book helps readers comprehend the principles and fundamentals of defect engineering toward realization of an efficient photocatalyst. The volume consists of two parts, each of which addresses a particulate type of defects. The first, larger section provides a comprehensive and rigorous treatment of the behaviour and nature of intrinsic defects. The author describes how their controlled introduction and consequent manipulation over concentration, distribution, nature and diffusion is one of the most effective and practical methodologies to modify the properties and characteristics of target photocatalytic materials. The second part of the book explains the formation of extrinsic defects in the form of metallic and non-metallic dopants and gives a detailed description of their characteristics as this approach is also often used to fabricate an efficient photocatalyst. Filling the gap in knowledge on the correlation between introduction of defects in various semiconducting materials and their photocatalytic performance, the book is ideal for graduate students, academics and researchers interested in photocatalysts, defect engineering, clean energy, hydrogen production, nanoscale advanced functional materials, CO2 deactivation, and semiconductor engineering.
Download or read book Nano Materials as Photocatalysts for Degradation of Environmental Pollutants written by Pardeep Singh and published by Elsevier. This book was released on 2019-12-02 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nano-Materials as Photocatalysts for Degradation of Environmental Pollutants: Challenges and Possibilities contains both practical and theoretical aspects of environmental management using the processes of photodegradation and various heterogeneous catalysts. The book's main focus is on the degradation of harmful pollutants, such as petrochemicals, crude oils, dyes, xenobiotic pharmaceutical waste, endocrine disrupting compounds, and other common pollutants. Chapters incorporate both theoretical and practical aspects. This book is useful for undergraduate or university students, teachers and researchers, especially those working in areas of photocatalysis through heterogeneous catalysts. The primary audience for this book includes Chemical Engineers, Environmental Engineers and scientists, scholars working on the management of hazardous waste, scientists working in fields of materials science, and Civil Engineers working on wastewater treatment. Reviews recent trends in the photodegradation of organic pollutants Offers a bibliometric analysis of photocatalysis for environmental abatement Includes many degradation mechanisms of organic pollutants using various catalysts Includes examples on the degradation of organic pollutants from various sources, e.g., pharmaceuticals, dyes, pesticides, etc. Discusses the effect of nanocatalysts on soil, plants and the ecosystem
Download or read book Solar Energy Update written by and published by . This book was released on 1984 with total page 884 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Recent Applications in Sol Gel Synthesis written by Usha Chandra and published by BoD – Books on Demand. This book was released on 2017-07-05 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Versatility, extended compositional ranges, better homogeneity, lesser energy consumption, and requirement of nonexpensive equipments have boosted the use of sol-gel process on top of the popularity in the synthesis of nanosystems. The sol-gel technique has not only revolutionized oxide ceramics industry and/or material science but has also extended widely into multidimensional applications. The book Recent Applications in Sol-Gel Synthesis comprises 14 chapters that deal mainly with the application-oriented aspects of the technique. Sol-gel prepared metal oxide (MO) nanostructures like nanospheres, nanorods, nanoflakes, nanotubes, and nanoribbons have been employed in biomedical applications involving drug deliveries, mimicking of natural bone, and antimicrobial activities. The possibility of controlling grain size in aerogel and preparation of ultrahigh-temperature ceramic (UHTC)-based materials, fluorescent glasses, ultraviolet photosensors, and photocatalysts have been discussed in detail by the experts in the field. The usefulness of sol-gel materials as active GRIN, as textile finisher, and as leather modifier with water-repellent and oil-resistive properties would be an incentive for researchers keen to pursue the field.
Download or read book Hierarchical Nanostructures for Energy Devices written by Seung H Ko and published by Royal Society of Chemistry. This book was released on 2014-10-29 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface area has a directly relationship with the efficiency of energy devices. Hierarchical nanostructuring has the potential to greatly increase surface area, and their electrical properties are favourable, not only to energy generation and storage, but also energy-consuming electronic circuits. This book provides systematic coverage of how nanostructured materials can be applied to energy devices, with an emphasis on the process of generation to storage and consumption. The fundamentals (including properties, characterisation and synthesis) are clearly presented across the first chapters of the book, providing readers new to the field with a clear overview of this expanding topic. The detailed discussion of applications will be an inspiration to those already well-versed in the field. The editors have more than a decade of experience in working on all aspects of energy generation and storage - in academia, national laboratories and industry. The book presents a balanced view from all sectors and is presented in a format accessible by postgraduate students and professional researchers alike.
Download or read book TiO2 Nanoparticles written by Aiguo Wu and published by John Wiley & Sons. This book was released on 2020-06-02 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique book that summarizes the properties, toxicology, and biomedical applications of TiO2-based nanoparticles Nanotechnology is becoming increasingly important for products used in our daily lives. Nanometer-sized titanium dioxide (TiO2) are widely used in industry for different purposes, such as painting, sunscreen, printing, cosmetics, biomedicine, and so on. This book summarizes the advances of TiO2 based nanobiotechnology and nanomedicine, covering materials properties, toxicological research, and biomedical application, such as antibacter, biosensing, and cancer theranostics. It uniquely integrates the TiO2 applications from physical properties, toxicology to various biomedical applications, and includes black TiO2 based cancer theranostics. Beginning with a comprehensive introduction to the properties and applications of nanoparticles, TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine offers chapters on: Toxicity of TiO2 Nanoparticles; Antibacterial Applications of TiO2 Nanoparticles; Surface Enhanced Raman Spectrum of TiO2 Nanoparticle for Biosensing (TiO2 Nanoparticle Served as SERS Sensing Substrate); TiO2 as Inorganic Photosensitizer for Photodynamic Therapy; Cancer Theranostics of Black TiO2 Nanoparticles; and Neurodegenerative Disease Diagnostics and Therapy of TiO2-Based Nanoparticles. This title: -Blends the physical properties, toxicology of TiO2 nanoparticles to the many biomedical applications -Includes black TiO2 based cancer theranostics in its coverage -Appeals to a broad audience of researchers in academia and industry working on nanomaterials-based biosensing, drug delivery, nanomedicine TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine is an ideal book for medicinal chemists, analytical chemists, biochemists, materials scientists, toxicologists, and those in the pharmaceutical industry.
Download or read book Book of Abstracts written by and published by . This book was released on 2000 with total page 778 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 702 pages. Available in PDF, EPUB and Kindle. Book excerpt:
