Download or read book Catalysts Deactivation Poisoning and Regeneration written by Luciana Lisi and published by MDPI. This book was released on 2019-10-01 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.
Download or read book Deactivation and Poisoning of Catalysts written by J. Oudar and published by CRC Press. This book was released on 1985-07-02 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Deactivation and Poisoning of Catalysts presents the most current research in the area of heterogeneous catalysis. It focuses on the chemically induced effects associated with bonded surface species that cause catalyst activity decline -- and in some cases a change in catalyst specificity. In addition, this volume examines poisoning of dispersed metal catalysts ... the thermodynamics of sulfur-metal and carbon-metal interactions ... model poisoning reactions on single crystals ... deactivation in petroleum refining and petrochemical processes ... coking of metal catalysts ... and more. The new approaches and solutions to catalyst deactivation and poisoning presented in this guide are invaluable to all heterogeneous catalysis specialists, including chemical and petroleum engineers, and surface, synthetic, physical, and industrial chemists. Book jacket.
Download or read book Activation Deactivation and Poisoning of Catalysts written by John Butt and published by Elsevier. This book was released on 2012-12-02 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activation, Deactivation, and Poisoning of Catalysts deals with the circumstances and mechanisms underlying catalyst activation, deactivation, and poisoning. The emphasis is on the techniques for handling deactivating systems, not on results per se. Deactivation by fouling and sintering is given consideration. This book is organized into three sections and consists of 12 chapters. The first part is devoted to a systematic development of the manner in which catalysts are activated, deactivated, poisoned, and in some cases reactivated on a microscopic basis. The first chapter explains the concept of the active center as utilized in catalysis, along with catalyst regeneration, rejuvenation, and detoxification. In the second part, the reader is introduced to the problem of heat transfer as well as the transport of reactants and products in the interior of the particle coupled with chemical reaction therein. The macroscopic deactivation behavior of the catalyst particle is described in terms of fundamental kinetic deactivation phenomena and of parameters governing heat and mass transfer. The last part is primarily concerned with a collection of catalyst particles within the reactor, with emphasis on the global activity of the reactor. In the last chapter, a pragmatic approach is presented to predict the design and performance of chemical reactors containing a deactivating catalyst. This book is written for catalytic chemists, researchers, reactor designers, and students interested in catalyst activation, deactivation, and poisoning.
Download or read book Catalyst Poisoning written by L. Louis Hegedus and published by . This book was released on 1984 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Catalyst Poisoning written by L. Louis Hegedus and published by . This book was released on with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Catalyst Deactivation 1994 written by G.F. Froment and published by Elsevier. This book was released on 1994-09-08 with total page 699 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst Deactivation 1994 was an expansion of earlier, highly successful symposia. The objective of the symposium was to promote a scientific approach of the phenomenon of catalyst deactivation which will contribute to the development of catalysts which are less subject to structural transformations and more resistant to poisons and coke formation. These aspects are dealt with in 12 plenary lectures, 48 oral presentations and 35 poster papers, which were critically selected from an impressive response from some 30 countries. Both fundamental and applied aspects were covered. The deactivation of catalysts in important industrial processes like fluid bed catalytic cracking hydrotreatment, hydrodesulfurization, catalytic reforming, hydrodenitrogenation, steam reforming, hydrodemetallization, hydrocracking, Fischer-Tropsch synthesis, propane dehydrogenation, phthalic anhydride synthesis received considerable attention. Mechanisms of poisoning, sintering and coking were further investigated and modelled and new experimental techniques for the characterization and the quantification of deactivation were also introduced.
Download or read book Catalyst Deactivation 1991 written by C.H. Bartholomew and published by Elsevier. This book was released on 1991-06-03 with total page 841 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst Deactivation 1991 was an expanded version of earlier, highly successful symposia. The symposium featured invited and solicited papers including 4 plenary lectures, 78 oral presentations and 23 poster papers. Most of the papers are contained in this volume. The eight main topics emphasised at this most recent symposium were: deactivation mechanisms/phenomena (carbon deposition, poisoning, and sintering), methods (modeling and techniques), and important catalysts (hydrotreating, oxides, and zeolites). All of these areas were well represented as attested by the substantial number of papers contained in these proceedings. Four review papers based on the plenary lectures provide state-of-the-art perspectives on new thrusts in deactivation research and development.
Download or read book Progress in Catalyst Deactivation written by J.L. Figueiredo and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most catalysts used in the chemical and petrochemical indus tries are strongly affected by one or another form of deactivation, leading to poor performances and reduced life. The increasing num ber of scientific communications devoted to the subject in recent years, and culminating with an International Symposium held in Antwerp in October 1980, is a measure of the interest it arouses in both the industrial and academic communities. A stage has been reached whereby it was thought that a NATO Advanced Study Institute on "Catalyst Deactivation" might be fruit ful in establishing the state of the art and in stimulating a more systematic research on the phenomenon. Such a meeting was held ~n Lagos, Portugal, from 18 to 29 May 1981. The purpose of the Institute was to present and discuss in a didatic and systematic way the various processes that lead to cata lyst deactivation, namely coking, poisoning and solid state trans formations, and at the same time to promote the exchange of ideas and experiences among the participants, drawn from industry and uni versity. The lectures presented at the Institute are collected in this volume with the exception of Dr. L.L.Hegedus "Catalyst Poisoning", which has been previously published (Catalysis Reviews, Science md Engineering, 23, 377-476, 1981).
Download or read book Advances in Catalyst Deactivation written by Calvin H. Bartholomew and published by MDPI. This book was released on 2018-10-01 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Advances in Catalyst Deactivation" that was published in Catalysts
Download or read book Deactivation of Catalysts written by Ronald Hughes and published by . This book was released on 1984 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book An Experimental and Theoretical Study of the Poisoning of Catalysts in a Single pellet Diffusion Reactor written by L. Louis Hegedus and published by . This book was released on 1972 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ammonia written by Anders Nielsen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ammonia is one of the 10 largest commodity chemicals produced. The editor, Anders Nielsen, is research director with one of the largest industrial catalyst producers. He has compiled a complete reference on all aspects of catalytical ammonia production in industry, from thermodynamics and kinetics to reactor and plant design. One chapter deals with safety aspects of ammonia handling and storage.
Download or read book Poisoning and Promotion in Catalysis based on Surface Science Concepts and Experiments written by M.P. Kiskinova and published by Elsevier. This book was released on 1991-11-29 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: The topics covered in this book include a variety of adsorption and model reaction studies on clean and modified single crystal metal surfaces obtained by means of properly selected surface sensitive techniques. The accent is on the revelation of the physics and chemistry involved in the effects of various modifiers on the adsorptive and reactivity properties of the surface with respect to different reactants. In this book current information that contributes to the fundamental understanding of the effect of additives is summarized. Some of the additives act as promoters, others as poisons, in a number of important catalytic reactions. A description of single- and double-component systems has been obtained by using surface-sensitive techniques, particularly suited for this purpose. For the benefit of the reader, a short summary of the main surface science techniques has been given in Chapter 2. Three general and interrelated topics are reviewed. The first concerns the interaction of electronegative (Cl, S, Se, C, N, O, P) and electropositive (alkali metals) atoms with metal surfaces (Chapter 4). The second topic covers the chemisorptive properties of metal surfaces modified by varying amounts of additives with respect to different reactants (CO, NO, N2, O2, H2, CO2, NH3, H2O and hydrocarbons) (Chapters 5 and 6). In particular the adsorption kinetics and energetics, and the electronic, structural and reactive properties of the coadsorbate systems are considered, whereby particular attention is given to recent surface science studies with well-characterized, single crystal, metal surfaces. In these chapters, special attention is paid to showing the contribution of different factors (the nature and adsorption state of the modifier and the coadsorbed molecule, the structure of the adsorbed layer, the type of interactions in the mixed overlayers, etc.) to the modifier effects. In the discussion of the third topic, model studies of several important catalytic reactions (Fischer-Tropsch synthesis, ammonia synthesis, CO oxidation, water-gas shift synthesis) on modified metal surfaces (Chapter 8) are considered. The book will be particularly useful to scientists who are interested in adsorption phenomena, surface properties and catalysis. It should also prove invaluable to those addressing the questions of condensed matter (surfaces and interfaces), materials science (e.g. corrosion of metals) and electrochemistry.
Download or read book Catalyst Deactivation 1987 written by G.F. Froment and published by Elsevier. This book was released on 1987-09-01 with total page 681 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Symposium on Catalyst Deactivation ensues those held at Berkeley (1985), Antwerp (1980) and Berkeley (1978).The three main topics emphasised at this most recent symposium were: the techniques used in deactivation studies, the mechanisms of catalyst deactivation, and modelling. With respect to the first, it became apparent that the study of deactivation faces even more difficulties than the characterization of fresh catalysts and the measurement of activity or selectivity, due to the multiplicity of interacting processes occurring during deactivation. Quite substantial progress has been made recently in the understanding of the mechanisms of various deactivation processes, particularly coking, and extra time was accorded to these topics at the symposium. The third topic corresponds to a problem which is very central to development studies and to the chemical engineering aspect of catalysis: it deals with the representativity of accelerated tests and the modelling of the deactivation phenomena.
Download or read book Sulfur Poisoning of Catalysts written by and published by . This book was released on 1978 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Catalysts Deactivation Poisoning and Regeneration written by Luciana Lisi and published by . This book was released on 2019 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.
Download or read book Models for Catalyst Poisoning written by Ravindra S. Dixit and published by . This book was released on 1977 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: