Download or read book Carbonyl Sulfide Exchange Between Soils and the Atmosphere Observations and Modeling written by Wu Sun and published by . This book was released on 2017 with total page 183 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS) is a trace gas participating in key processes of the terrestrial carbon cycle. Despite its low mixing ratio in the troposphere (400-550 pmol mol-1), the amplitude of seasonal variability of COS greatly exceeds that of CO2 and is in phase with the gross photosynthesis of the terrestrial biosphere. Over the recent decade, COS has emerged as a promising tracer for quantifying terrestrial gross primary productivity (GPP) independently from respiration across the ecosystem to the global scales, because of the parallel uptake of COS and CO2 through leaf stomata. While leaf uptake of COS dominates surface COS flux on land in the absence of industrial and biomass burning emissions, soil COS flux is another smaller but significant component. Neglecting the soil component in ecosystem COS budget may bias GPP estimates derived from COS measurements. Soil may also vary from a sink to a source of COS depending on temperature and microbial sulfur metabolism. Due to the presence of potential interference from soil COS activities, using COS as a photosynthetic tracer requires soil COS flux to be separated from the net ecosystem COS exchange. This dissertation is dedicated to the mechanistic understanding of the soil-atmosphere exchange of COS using process-oriented modeling and field observations. A reactive transport model for soil COS processes is constructed to simulate soil-atmosphere COS flux from environmental variables. This model takes into account the dual-phase diffusive transport and the microbial sources and sinks of COS in the soil column. COS uptake and production rates are parameterized with enzyme kinetics and thermodynamics, consistent with lab incubation data. Leaf litter layer is explicitly resolved to account for litter COS uptake, whenever a litter layer is present. The model is evaluated against published field data of COS flux and demonstrates good skill in predicting both soil uptake and emission of COS. Model simulations further confirm that COS flux dependence on soil moisture is a result of two rivaling controls--the diffusive limitation on COS supply and the water limitation on microbial activity. Field observations on soil COS exchange have been conducted at an oak woodland in southern California and a boreal pine forest in southern Finland using automated soil chambers and mid-infrared quantum cascade laser spectrometer. Soils at both sites show consistent uptake behavior related to soil moisture and respiration. At the semi-arid oak woodland in California, microbial COS uptake is strongly limited by water availability in the dry season. The intact leaf litter layer contributes a significant portion to the overall soil COS uptake. Litter COS uptake increases with moisture content and shows a strong pulse immediately after the rain event, indicating a rapid reactivation of litter microbial activity following alleviated water stress. In the Finnish pine forest, soil COS uptake is limited by the diffusional supply of COS to soil microbes, according to the negative correlation with soil moisture. The contrasting responses of soil COS uptake to moisture in semi-arid and humid ecosystems reflect the coupling of diffusion and microbial uptake controls on COS flux. At both sites, soil COS uptake correlates well with respiration and the COS : CO2 flux ratio varies with temperature. The temperature dependence of COS : CO2 flux ratio may be a common feature of soils and indicate underlying shifts in active microbial groups. This dissertation advances knowledge of the physical and biological drivers of soil-atmosphere exchange of COS. Anticipated applications of the findings will be to better constrain global soil COS flux and derive COS-based estimates of GPP, which will be useful in understanding the responses of photosynthesis to climate variability.

Download or read book Carbonyl Sulfide Exchange in Soils for Better Estimates of Ecosystem Carbon Uptake written by and published by . This book was released on 2016 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Diffusivity and Enzymatic Activity Control the Exchange of Carbonyl Sulfide COS Between Soils and the Atmosphere written by Heidi Van Diest and published by . This book was released on 2007 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Quantifying Carbon Climate Processes at the Regional Scale Using Atmospheric Carbonyl Sulfide written by and published by . This book was released on 2013 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric carbonyl sulfide (COS) analysis has the potentially transformative capability for partitioning the regional carbon flux into respiration and photosynthesis components. This emerging approach is based on the observation that continental atmospheric CO2 gradients are dominated by net ecosystem fluxes while continental atmospheric COS gradients are dominated by photosynthesis-related plant uptake. Regional flux partitioning represents a critical knowledge gap due to a lack of robust methods for regional-scale flux partitioning and large uncertainties in forecasting carbon-climate feedbacks. Our completed project characterized the relationship between COS and CO2 surface fluxes using a novel measurement and modeling system in a winter wheat field at the U.S. Department of Energy?s Atmospheric and Radiation Measurement program Central Facility (DOE-ARM CF). The scope of this project included canopy flux measurements, soil flux measurements, regional atmospheric modeling, and analysis of COS and CO2 airborne observations at SGP. Three critical discoveries emerged from this investigation: (1) the new measurement system provided the first field evidence of a robust relationship between COS leaf fluxes and GPP; (2) a previously unknown seasonal soil source of COS was observed and characterized; (3) the regional atmospheric analysis of airborne measurements provided the first COS-based constraints on GPP parameterizations used in earth systems models. Dissemination of these results includes three publications [Billesbach et al., In Press; Campbell et al., In Preparation; Seibt et al., In Review], three presentations at the AGU Fall Meeting (2012), and four invited presentations to department seminars. We have leveraged this foundational project to continue our work on understanding carbon cycle processes at large scales through one funded project (DOE Lab Fee, 2012-2015) and one proposal that is under review (DOE/NASA/USDA/NOAA, 2014-2016).

Download or read book Anthropogenic Sources of Carbonyl Sulfide written by and published by . This book was released on 2017 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS or OCS) is emerging as a potentially important tracer of terrestrial biological carbon fluxes. Anthropogenic sources of atmospheric COS are a first order uncertainty for utilizing COS as a tracer of the carbon cycle. As anthropogenic COS is a confounding source of atmospheric COS when interpreting COS observations, incorrect estimates of anthropogenic COS sources can introduce large interpretation bias when attempting to infer carbon cycle fluxes. However, the current gridded estimate of anthropogenic sources of atmospheric COS is largely derived from data over three decades old and therefore is not likely to be representative of current atmospheric conditions. Here I address this critical knowledge gap by providing a new gridded estimate of anthropogenic COS sources derived from the most current industry activity and emissions factor data available and employ a more sophisticated approach for the spatial distribution of sources than presented in previous work. This new data set results in a very different picture of the spatial distribution of anthropogenic sources of COS and in a large upward revision in total global sources than estimated in previous work. The large missing source of atmospheric COS needed to balance the global budget of atmospheric COS has largely been attributed to an unknown ocean source in previous work. However, considering the large upward revision of anthropogenic COS sources estimated here, I present the hypothesis that anthropogenic sources may be a key component of the missing source of atmospheric COS. I present subsequent modeling scenarios to test this hypothesis and show that anthropogenic COS sources can explain observations of atmospheric COS as well as or better than enhanced ocean sources. Therefore, the data set of anthropogenic sources of COS presented here emerges as a key component of reducing interpretation bias when inferring carbon cycle fluxes using COS and for explaining the missing source of atmospheric COS and balancing the global COS budget (which has previously not been considered).

Download or read book Tropical Sources and Sinks of Carbonyl Sulfide Constrained by Atmospheric Observations written by James Robert Stinecipher and published by . This book was released on 2020 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (OCS or COS) is the most common sulfur-containing species in the atmosphere and has the potential to function as a proxy for photosynthetic carbon uptake (gross primary productivity, GPP). In order to expand this technique to regional and global scales, additional questions about poorly constrained aspects of the carbonyl sulfide budget must be resolved. The first section of this work is devoted to developing a new, spatially resolved and temporally varying inventory of carbonyl sulfide emissions from biomass burning. By leveraging long-term, in situ observations of atmospheric carbonyl sulfide, we demonstrate that biomass burning emissions are heavily dependent on biome and are not sufficient to close the overall flux budget. The second section of this dissertation uses this biomass burning inventory in conjunction with a global chemical transport model in order to constrain plant fluxes in the Amazon basin. Using satellite data from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument, I show that downstream observations of carbonyl sulfide in the upper troposphere retain useful information about surface processes and can provide an independent constraint on gross primary production given sufficient convective transport. Finally, I conduct an observing system simulation experiment (OSSE) to investigate how future remote-sensing campaigns could yield more information and better constrain GPP using carbonyl sulfide. In addition to considering sampling density, sampling height and instrument noise in satellite observations, I address potential challenges in future aircraft sampling campaigns.

Download or read book Carbonyl Sulfide for Tracing Carbon Fluxes Field Campaign Report written by and published by . This book was released on 2016 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: The April-June 2012 campaign was located at the U.S. Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site Central Facility and had three purposes. One goal was to demonstrate the ability of current instrumentation to correctly measure fluxes of atmospheric carbonyl sulfide (COS). The approach has been describe previously as a critical approach to advancing carbon cycle science1,2, but requires further investigation at the canopy scale to resolve ecosystem processes. Previous canopy-scale efforts were limited to data rates of 1Hz. While 1 Hz measurements may work in a few ecosystems, it is widely accepted that data rates of 10 to 20 Hz are needed to fully capture the exchange of traces gases between the atmosphere and vegetative canopy. A second goal of this campaign was to determine if canopy observations could provide information to help interpret the seasonal double peak in airborne observations at SGP of CO2 and COS mixing ratios. A third goal was to detect potential sources and sinks of COS that must be resolved before using COS as a tracer of gross primary productivity (GPP).

Download or read book Biosphere Atmosphere Exchange of Pollutants and Trace Substances written by Sjaak Slanina and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 562 pages. Available in PDF, EPUB and Kindle. Book excerpt: The biosphere is the ultimate sink for air pollutants and is also the source of many precursors for the formation of photo-oxidants. In any analysis of air pollution and for determining source-receptor relationships, reliable emission and pollutant concentrations or depositions must be taken into account, together with their interactions between the atmosphere and the biosphere. This book presents a number of authoritative review articles covering topics which include biosphere-atmosphere exchange of ammonia, nitrogen oxides, ozone and sulfur-containing gases, the biological mechanisms involved in the exchange of trace gases, as well as generalizations of deposition over Europe.

Download or read book Biogeochemistry written by W.H. Schlesinger and published by Academic Press. This book was released on 2013-01-14 with total page 689 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the past 4 billion years, the chemistry of the Earth's surface, where all life exists, has changed remarkably. Historically, these changes have occurred slowly enough to allow life to adapt and evolve. In more recent times, the chemistry of the Earth is being altered at a staggering rate, fueled by industrialization and an ever-growing human population. Human activities, from the rapid consumption of resources to the destruction of the rainforests and the expansion of smog-covered cities, are all leading to rapid changes in the basic chemistry of the Earth. The Third Edition of Biogeochemistry considers the effects of life on the Earth's chemistry on a global level. This expansive text employs current technology to help students extrapolate small-scale examples to the global level, and also discusses the instrumentation being used by NASA and its role in studies of global change. With the Earth's changing chemistry as the focus, this text pulls together the many disparate fields that are encompassed by the broad reach of biogeochemistry. With extensive cross-referencing of chapters, figures, and tables, and an interdisciplinary coverage of the topic at hand, this text will provide an excellent framework for courses examining global change and environmental chemistry, and will also be a useful self-study guide. Emphasizes the effects of life on the basic chemistry of the atmosphere, the soils, and seawaters of the EarthCalculates and compares the effects of industrial emissions, land clearing, agriculture, and rising population on Earth's chemistrySynthesizes the global cycles of carbon, nitrogen, phosphorous, and sulfur, and suggests the best current budgets for atmospheric gases such as ammonia, nitrous oxide, dimethyl sulfide, and carbonyl sulfideIncludes an extensive review and up-to-date synthesis of the current literature on the Earth's biogeochemistry.

Download or read book Treatise on Estuarine and Coastal Science written by and published by Academic Press. This book was released on 2012-03-06 with total page 4604 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of estuaries and coasts has seen enormous growth in recent years, since changes in these areas have a large effect on the food chain, as well as on the physics and chemistry of the ocean. As the coasts and river banks around the world become more densely populated, the pressure on these ecosystems intensifies, putting a new focus on environmental, socio-economic and policy issues. Written by a team of international expert scientists, under the guidance of Chief Editors Eric Wolanski and Donald McClusky, the Treatise on Estuarine and Coastal Science, Ten Volume Set examines topics in depth, and aims to provide a comprehensive scientific resource for all professionals and students in the area of estuarine and coastal science Most up-to-date reference for system-based coastal and estuarine science and management, from the inland watershed to the ocean shelf Chief editors have assembled a world-class team of volume editors and contributing authors Approach focuses on the physical, biological, chemistry, ecosystem, human, ecological and economics processes, to show how to best use multidisciplinary science to ensure earth's sustainability Provides a comprehensive scientific resource for all professionals and students in the area of estuarine and coastal science Features up-to-date chapters covering a full range of topics

Download or read book Treatise on Geochemistry written by and published by Newnes. This book was released on 2013-10-19 with total page 14787 pages. Available in PDF, EPUB and Kindle. Book excerpt: This extensively updated new edition of the widely acclaimed Treatise on Geochemistry has increased its coverage beyond the wide range of geochemical subject areas in the first edition, with five new volumes which include: the history of the atmosphere, geochemistry of mineral deposits, archaeology and anthropology, organic geochemistry and analytical geochemistry. In addition, the original Volume 1 on "Meteorites, Comets, and Planets" was expanded into two separate volumes dealing with meteorites and planets, respectively. These additions increased the number of volumes in the Treatise from 9 to 15 with the index/appendices volume remaining as the last volume (Volume 16). Each of the original volumes was scrutinized by the appropriate volume editors, with respect to necessary revisions as well as additions and deletions. As a result, 27% were republished without major changes, 66% were revised and 126 new chapters were added. In a many-faceted field such as Geochemistry, explaining and understanding how one sub-field relates to another is key. Instructors will find the complete overviews with extensive cross-referencing useful additions to their course packs and students will benefit from the contextual organization of the subject matter Six new volumes added and 66% updated from 1st edition. The Editors of this work have taken every measure to include the many suggestions received from readers and ensure comprehensiveness of coverage and added value in this 2nd edition The esteemed Board of Volume Editors and Editors-in-Chief worked cohesively to ensure a uniform and consistent approach to the content, which is an amazing accomplishment for a 15-volume work (16 volumes including index volume)!

Download or read book Energy Research Abstracts written by and published by . This book was released on 1994-06 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Air Pollution Abstracts written by and published by . This book was released on 1976 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Annual Report and Findings Update written by National Acid Precipitation Assessment Program (U.S.). Office of the Director and published by . This book was released on 1989 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1994 with total page 892 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemistry of the Natural Atmosphere written by Peter Warneck and published by Elsevier. This book was released on 1999-10-29 with total page 947 pages. Available in PDF, EPUB and Kindle. Book excerpt: Knowledge of thc chemical behavior of trace compounds in the atmosphere has grown steadily, and sometimes even spectacularly, in recent decades. These developments have led to the emergence of atmospheric chemistry as a new branch of science. This book covers all aspects of atmospheric chemistry on a global scale, integrating information from chemistry and geochemistry, physics, and biology to provide a unified account. For each atmospheric constituent of interest, the text summarizes the principal observations on global distribution, chemical reactions, natural and anthropogenic sources, and physical removal processes. Coverage includes processes in the gas phase, in aerosols and c1ouds, and in precipitation, as well as biogeochemical cycles and the evolution of the atmosphere. Chemistry of the Natural Atmosphere, Second Edition, will serve as a textbook for senior undergraduate and graduate courses, and as an essential reference for atmospheric chemists, meteorologists, and anyone studying the biogeochemical cycles of trace gases.* Updated extensively from the highly respected first edition * Treats the global-scale chemistry and distribution of atmospheric trace constituents * Emphasizes observations and their interpretation* Provides background on transport and reaction kinetics for interpretation of observational data* Includes chemistry in the gas phase and in aerosols and clouds* Details chemical reaction pathways for the most important trace constituents* Describes pertinent biogeochemical cycles* Written by an author with more than 40 years of research experience in atmospheric chemistry

Download or read book Issues in Extreme Conditions Technology Research and Application 2011 Edition written by and published by ScholarlyEditions. This book was released on 2012-01-09 with total page 673 pages. Available in PDF, EPUB and Kindle. Book excerpt: Issues in Extreme Conditions Technology Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Extreme Conditions Technology Research and Application. The editors have built Issues in Extreme Conditions Technology Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Extreme Conditions Technology Research and Application in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Issues in Extreme Conditions Technology Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.