Download or read book Organometallic Bonding and Reactivity written by J.M. Brown and published by Springer Science & Business Media. This book was released on 1999-09-20 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by experts and pioneers in the field, the volume addresses state-of-the-art theoretical and experimental methodologies applicable to fundamental problems of structure and reactivity of organometallic compounds. The principles of ab initio and density functional theory, as well as integrated force field/quantum chemistry approaches are outlined, with particular emphasis on their applicability to transition metal organometallic molecules and their reactions. Specific case studies, spanning a range from static structural aspects to molecular structure dynamics, reaction mechanisms and catalytic cycles illustrate the power of modern quantum chemistry for organometallics. Experimental properties of organometallic systems, derived from gas phase organometallic chemistry as well as solid state structural chemistry provide deep and complementary insights into the fundamentals of the chemistry of the metal-carbon bond.
Download or read book Organometallic Compounds written by B. J. Aylett and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Download or read book Principles of Organometallic Chemistry written by G. E. Coates and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of Organometallic Compounds (1960) was used not only by specialists but also as an undergraduate textbook. The third edition, recently published in two volumes, is about three times the length of the second and contains considerably more factual material than is appropriate for a student textbook. Therefore we believe that a shorter treatment would be welcome. In planning this book the authors have emphasized matters more of prin ciple than of detail, and have included in the first two chapters some general discussion of the properties and syntheses of organometallic compounds that is not to be found in the larger work. Some aspects of the organic chemistry of arsenic, and of silicon with particular reference to silicone polymers, are also included. Most university teachers of chemistry are becoming seriously concerned about the relentless increase in the amount and complexity of the material that is squeezed into undergraduate chemistry courses. With this in mind the authors have tried to cut detail to a minimum, but readers will find that the relative amount presented varies considerably between the various topics discussed. In general the treatment is more extensive than usual only if either or both of these conditions are met: (1), the subject has significant bearing on other major branches of chemistry including im portant industrial processes; (2), the topic is commonly misunderstood or found to be confusing.
Download or read book Bonding Energetics in Organometallic Compounds written by American Chemical Society. Meeting and published by . This book was released on 1990 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Papers of a symposium of the Div. of Inorganic Chemistry at the ACS meeting in Miami Beach, Sept. 1989. They present an overview of our knowledge of metal-ligand bond energies in organometallic chemistry. Annotation copyrighted by Book News, Inc., Portland, OR
Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Download or read book Handbook of Bond Dissociation Energies in Organic Compounds written by Yu-Ran Luo and published by CRC Press. This book was released on 2002-12-26 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: So many compounds, so many experiments reported by so many researchers using so many methods Finding reliable data on bond dissociation energies (BDEs) can be like looking for a needle in a haystack. But these data are crucial to work in chemical kinetics, free radical chemistry, organic thermochemistry, and physical organic chemistry-so where does
Download or read book Bonding energetics in organometallic compounds developed from a symposium sponsored by the Division of Inorganic Chemistry at the 198th national meeting of the American Chemical Society Miami Beach Florida September 10 15 1989 written by Tobin J. Marks and published by . This book was released on 1990 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Chemistry written by Shay Beck and published by Scientific e-Resources. This book was released on 2019-09-06 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry is the study of chemical compounds containing bonds between carbon and metal. The term "e;Metal"e; is defined deliberately broadly in this context and may include elements, such as silicon or boron, which are not metallic but are considered to be metalloids. Almost all branches of chemistry and material science now interface with organometallic chemistry. Organometallics find practical uses in stoichiometric and catalytic processes, especially processes involving carbon monoxide and alkene-derived polymers. Organometallic (OM) chemistry is the study of compounds containing, and reactions involving, metal-carbon bonds. The metal-carbon bond may be transient or temporary, but if one exists during a reaction or in a compound of interest, we're squarely in the domain of organometallic chemistry. Despite the denotational importance of the M-C bond, bonds between metals and the other common elements of organic chemistry also appear in OM chemistry: metal-nitrogen, metal-oxygen, metal-halogen, and even metal-hydrogen bonds all play a role. Metals cover a vast swath of the periodic table and include the alkali metals (group 1), alkali earth metals (group 2), transition metals (groups 3-12), the main group metals (groups 13-15, "e;under the stairs"e;), and the lanthanides and actinides. The principal idea of this book is to offer a comprehensive coverage of unconventional and thought-provoking topics in organometallic chemistry. It also supplies practical information about reaction mechanisms, along with the descriptions of contemporary applications to organic synthesis, organized by mechanism and kinetic. It will serve as a valuable reference tool for students and professional of organic and post organic chemistry, who need to become better acquainted with the subject.
Download or read book Advances in Organometallic Chemistry written by and published by Elsevier. This book was released on 2003-10-02 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Volume 49 provides an authorititative, definitive review addressing all aspects of organometallic chemistry Useful to all researchers within this active field and is a must for every modern library of chemistry High quality research book within this active field
Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by Wiley-Interscience. This book was released on 1994-04 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: Later chapters discuss applications of organometallics such as: catalytic uses of transition metals; activation of small molecules; applications to organic synthesis; and carbenes, metathesis, and polymerization. Also discussed are the role of organometallics in biochemical areas, clusters, metal-metal bonds, and high-oxidation-state complexes.
Download or read book Advances in Organometallic Chemistry written by Robert C. West and published by Elsevier. This book was released on 2006-05-23 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. The widely acclaimed serial Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Provides an authoritative, definitive review addressing all aspects of organometallic chemistry Useful to researchers within this active field and is a must for every modern library of chemistry High quality research book within this rapidly developing field
Download or read book Organometallic Reaction Mechanisms Of The Nontransition Elements written by Donald Matteson and published by Elsevier. This book was released on 2012-12-02 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Reaction Mechanisms of the Nontransition Elements provides selected significant developments in organometallic reaction mechanisms and outlines a self-consistent set of interpretations of these mechanisms. This book is organized into eight chapters and begins with discussions on bonding in theoretically important types of organometallic compounds and the potential surfaces and their relation to mechanisms. This is followed by significant chapters on electrophilic displacement reactions. Polar 1,2-addition and elimination reactions are covered in a separate chapter. Radical and photochemical reactions are described in the concluding chapters of the book, including the reverse reaction involving incorporation of a free metal and an organic halide into an organometallic compound. Organic chemists and researchers will find this book invaluable.
Download or read book Ionization Bonding and Solvation Energetics of Organometallic Complexes written by Matthew F. Ryan and published by . This book was released on 1993 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energetics of Stable Molecules and Reactive Intermediates written by M.E. Minas da Piedade and published by Springer. This book was released on 1999-05-31 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the major experimental and theoretical methods currently used to study the energetics of stable molecules and reactive intermediates. Reviews the ate of the art and shows the interplay of experimental and theoretical methods used to probe bonding energetics and reactivity and a wide range of chemical species. A modern and invaluable introduction to the study of molecular energetics. A reference for workers currently involved in the field.
Download or read book Energetics of Organometallic Species written by José A. Martinho Simões and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: An overview of modern organometallic thermochemistry, made by some of the most active scientists in the area, is offered in this book. The contents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with several techniques. It is therefore considered appropriate to add a few preliminary words, attempting to bring some unity out of that diversity. In the first three chapters, results obtained by classical calorimetric methods are described. Modern organometallic thermochemistry started in Manchester, with Henry Skinner, and his pioneering work is briefly surveyed in the first chapter. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies. Geoff Pilcher, another Manchester thermochemist, makes, in chapter 2, a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic compounds. Finally, results from another classical technique, reaction-solution calorimetry, are reviewed in the third chapter, by Tobin Marks and coworkers. More than anybody else, Tobin Marks has used thermochemical values to define synthetic strategies for organometallic compounds, thus indicating an application of thermochemical data of which too little use has been made so far.
Download or read book Fundamental Transition Metal Organometallic Chemistry written by Charles M. Lukehart and published by Thomson Brooks/Cole. This book was released on 1985 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Comprehensive Handbook of Chemical Bond Energies written by Yu-Ran Luo and published by CRC Press. This book was released on 2007-03-09 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials, bioengineering, environmental chemistry, and space science. Reflecting the frequent additions and updates of bond dissociation energy (BDE) data throughout the literature, the Comprehensive Handbook of Chemical Bond Energies compiles the most recent experimental BDE data for more than 19,600 bonds of 102 elements. The author organizes the data by bond type, functional group, bond order, bond degree, molecular size, and structure for ease of use. Data can also be located using the Periodic table. The book presents data for organic molecules, biochemicals, and radicals as well as clusters, ions, hydrogen- and surface-bonded species, van der Waals complexes, isotopic species, and halogen-clusters/complexes. It also introduces entirely new data for inorganics and organometallics. The final chapter summarizes the heats of formation for atoms, inorganic/organic radicals, and monoatomic ions in the gas phase. The Comprehensive Handbook of Chemical Bond Energies offers quick access to experimental BDE data in the most inclusive, well-organized, and up-to-date collection available today.
