Download or read book Advances in Linear Free Energy Relationships written by N. Chapman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: Louis P. Hammett Mitchill Professor Emeritus of Chemistry, Columbia University My interest in linear free energy relationships began when, just out of graduate school, I read in 1924 the article by Bmnsted and Pedersen which for the first time reported the existence of such a relationship. That interest continues to be an active one and, to judge merely by the extensive biblio graphies contained in the present volume, it is widely shared. To my mind a particularly happy aspect of the existence of linear free energy relationships has been the proof it supplies that one need not suppose that the behavior of nature is hopelessly complicated merely because one cannot find a theoretical reason for supposing it to be otherwise. The effect of a substituent in an organic molecule on rate or equilibrium of reaction involves a fourfold difference between relatively large quantities, a situation which always makes for difficult theory. Yet systematic organic chemistry could hardly have existed were it not true that like changes in structure lead to like changes in reactivity. Linear free energy relationships constitute the quantitative specialisation of this fundamental principle, and they stand indeed more in the office of teacher to theory than in that of learner from it.
Download or read book Free Energy Relationships in Organic and Bio organic Chemistry written by Andrew Williams and published by Royal Society of Chemistry. This book was released on 2003 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.
Download or read book Chemical Kinetics and Process Dynamics in Aquatic Systems written by PatrickL. Brezonik and published by Routledge. This book was released on 2018-05-08 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Process Dynamics in Aquatic Systems is devoted to chemical reactions and biogeochemical processes in aquatic systems. The book provides a thorough analysis of the principles, mathematics, and analytical tools used in chemical, microbial, and reactor kinetics. It also presents a comprehensive, up-to-date description of the kinetics of important chemical processes in aquatic environments. Aquatic photochemistry and correlation methods (e.g., LFERs and QSARs) to predict process rates are covered. Numerous examples are included, and each chapter has a detailed bibliography and problems sets. The book will be an excellent text/reference for professionals and students in such fields as aquatic chemistry, limnology, aqueous geochemistry, microbial ecology, marine science, environmental and water resources engineering, and geochemistry.
Download or read book Free Energy Relationships in Organic and Bio Organic Chemistry written by Andrew Williams and published by Royal Society of Chemistry. This book was released on 2019-05-16 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.
Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2007-06-13 with total page 1213 pages. Available in PDF, EPUB and Kindle. Book excerpt: The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.
Download or read book March s Advanced Organic Chemistry written by Michael B. Smith and published by John Wiley & Sons. This book was released on 2007-01-29 with total page 2379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations
Download or read book Advanced Physical Chemistry written by Mehra Harish C and published by Krishna Prakashan Media. This book was released on 1978 with total page 1484 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advanced Organic Chemistry written by Francis Carey and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 601 pages. Available in PDF, EPUB and Kindle. Book excerpt: Of Part A.- 1. Chemical Bonding and Molecular Structure.- 1.1. Valence-Bond Approach to Chemical Bonding.- 1.2. Bond Energies, Lengths, and Dipoles.- 1.3. Molecular Orbital Theory.- 1.4. Hückel Molecular Orbital Theory.- General References.- Problems.- 2. Stereochemical Principles.- 2.1. Enantiomeric Relationships.- 2.2. Diastereomeric Relationships.- 2.3. Dynamic Stereochemistry.- 2.4. Prochiral Relationships.- General References.- Problems.- 3. Conformational and Other Steric Effects.- 3.1. Steric Strain and Molecular Mechanics.- 3.2. Conformations of Acyclic Molecules.- 3.3. Conformations o.
Download or read book Progress in Physical Organic Chemistry written by Robert W. Taft and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Progress in Physical Organic Chemistry are not only of interest to scientists working in physical organic chemistry, but also scientists working in the many subdisciplines of chemistry in which physical organic chemistry approaches are now applied, such as biochemistry, pharmaceutical chemistry, and materials and polymer science. Among the topics explored in this series are reaction mechanisms; reactive intermediates; combinatorial strategies; novel structures; spectroscopy; chemistry at interfaces; stereochemistry; conformational analysis; quantum chemical studies; structure-reactivity relationships; solvent, isotope and solid-state effects; long-lived charged, sextet or open-shell species; magnetic, non-linear optical and conducting molecules; and molecular recognition.
Download or read book Advanced Sorption Process Applications written by Serpil Edebali and published by BoD – Books on Demand. This book was released on 2019-02-20 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the beginning of the twenty-firstst century, separation processes presented a comprehensive application of the major operations performed by various industries, such as chemical, food, environmental, and biotechnology. Sorption, one of the preferred separation processes because of its effectiveness at different interfaces, has caught the attention of many scientists. This book is aimed at gaining a general knowledge of sorption and a number of extremely important applications, as well as recognizing its functions and paramount importance in chemical and biochemical plants, including environmental treatment. Moreover, progress in the phenomenon is highlighted in this book. To help provide instruction in the important sorption processes, we have chosen authors who have extensive industrial and academic experience in closing the gap between theory and practice. Crucial progress in the theoretical information section of sorption has been achieved, mainly through the development of new techniques that examine the usage of various sorbents, including nanomaterials for the removal of various pollutants. We have subdivided the book into several sections, one of which is focused on applications of the sorption process, which presents real results of the recent studies and gives a source of up-to-date literature. The relationship between the sorption process and isotherm and kinetics modeling is analyzed in another chapter. This book will be a reference book for those who are interested in sorption techniques from various industries.
Download or read book Correlation Analysis in Chemistry written by N. Chapman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Correlation Analysis in Chemistry: Recent Advances, is a sequel to our Advances in Linear Free Energy Relationships. t The change in the title is designed to reflect more accurately the nature of the field and the contents of the volume. The term LFER is still widely used, but it is often applied rather loosely to correlation equations that are not LFER in the restricted sense of a relationship involving logarithms of rate or equili brium constants on each side of the equation. The term "correlation analysis" seems to us more appropriate for the whole subject. The use of this term has compelled us also to introduce "chemistry" into the title; we have preferred not to prefix this with "organic" on the grounds that several areas of interest are not "organic chemistry" as usually understood, al though, of course, traditional applications of the basic relationships asso ciated with the names of Hammett and of Taft continue to be of interest. In the first volume we sought through our authors to provide a series of general articles covering the various aspects of the field as they seemed to us. Since the book was the first international research monograph in its field, each chapter, while giving prominence to recent developments, did not neglect earlier work, so that each article presented a comprehensive account of its own area.
Download or read book Advances in Clean Hydrocarbon Fuel Processing written by M. Rashid Khan and published by Elsevier. This book was released on 2011-09-23 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conventional coal, oil and gas resources used worldwide for power production and transportation are limited and unsustainable. Research and development into clean, alternative hydrocarbon fuels is therefore aimed at improving fuel security through exploring new feedstock conversion techniques, improving production efficiency and reducing environmental impacts.Advances in clean hydrocarbon fuel processing provides a comprehensive and systematic reference on the range of alternative conversion processes and technologies.Following introductory overviews of the feedstocks, environmental issues and life cycle assessment for alternative hydrocarbon fuel processing, sections go on to review solid, liquid and gaseous fuel conversion. Solid fuel coverage includes reviews of liquefaction, gasification, pyrolysis and biomass catalysis. Liquid fuel coverage includes reviews of sulfur removal, partial oxidation and hydroconversion. Gaseous fuel coverage includes reviews of Fischer-Tropsch synthesis, methanol and dimethyl ether production, water-gas shift technology and natural gas hydrate conversion. The final section examines environmental degradation issues in fuel processing plants as well as automation, advanced process control and process modelling techniques for plant optimisationWritten by an international team of expert contributors, Advances in clean hydrocarbon fuel processing provides a valuable reference for fuel processing engineers, industrial petrochemists and energy professionals, as well as for researchers and academics in this field. - A comprehensive reference on the range of alternative conversion processes and technologies - Provides an overview of the feedstocks, environmental issues and life cycle assessments for alternative hydrocarbon fuel processing, including a review of the key issues in solid, liquid and gaseous fuel conversion - Examines automation, advanced process control and process modelling techniques for plant optimisation
Download or read book Advances in Physical Organic Chemistry written by John P. Richard and published by Elsevier. This book was released on 2005-11-15 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding applications from biology to solid state physics. This text is ideal for those interested in the relationship between the structure and function of organic compounds, including physical and theoretical chemists as well as organic and bioorganic chemists.
Download or read book Transition Elements Advances in Research and Application 2011 Edition written by and published by ScholarlyEditions. This book was released on 2012-01-09 with total page 1063 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Elements: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Transition Elements. The editors have built Transition Elements: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Transition Elements in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Transition Elements: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Download or read book Advanced Organic Chemistry Structure and mechanisms written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2000 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt: The material in this book is organized on the basis of fundamental structural topics such as structure, stereochemistry conformation and aromaticity and basic mechanistic types, including nucleophilic substitution, addition reactions, carbonyl chemistry, aromatic substitution and free radical reactions.
Download or read book Advances in Physical Organic Chemistry written by Ian Williams and published by Academic Press. This book was released on 2019-10-25 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Physical Organic Chemistry, Volume 53, presents the latest reviews of recent work in physical organic chemistry. It provides a valuable source of information that is ideal not only for physical organic chemists applying their expertise to both novel and traditional problems, but also for non-specialists across diverse areas who identify a physical organic component in their approach to research. Its hallmark is a quantitative, molecular level understanding of phenomena across a diverse range of disciplines. Chapters in this updated release include Theoretical models for activation and reaction energies in chemical reactions, Chiral induction in asymmetric dual catalysis, and The transition state. - Reviews the application of quantitative and mathematical methods to help readers understand chemical problems - Provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry - Covers organic, organometallic, bioorganic, enzymes and materials topics - Presents the only regularly published resource for reviews in physical organic chemistry - Written by authoritative experts who cover a wide range of topics that require a quantitative, molecular-level understanding of phenomena across a diverse range of disciplines
Download or read book Advanced Organic Chemistry written by Bernard Miller and published by . This book was released on 1998 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text covers the principles of mechanisms of organic reactions in a qualitative way and features a chapter on heterocyclic chemistry. End of chapter exercises feature references to current literature
