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Book Removal of Heavy Metals from Industrial Wastewater Using Activated Carbon

Download or read book Removal of Heavy Metals from Industrial Wastewater Using Activated Carbon written by Nor Shahirah Mohd Nasir and published by . This book was released on 2010 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt: The presence of heavy metals in wastewater is known to cause severe damage to aquatic life, beside the fact that these metals kill microorganism during biological treatment of wastewater with a consequent time delay of the treatment process. Chromium is one of the major heavy metals present in wastewater which has toxic effect and is a strong oxidizing agent capable of being absorbed through the skin. Palm oil mills in Malaysia produce about 4.3 million tones of shell and the significant problems in the palm fruit processing is managing the wastes generated during the process. The palm shell can be converted into useful products such as activated carbon. So, this method will reduce industrial wastewater problem and will bring benefits to society. Hence, this research aims to use activated carbon produced from palm shell to remove Chromium from industrial wastewater. Pyrolysis was applied for the preparation of activated carbon from palm shell using furnace at 600oC. The treatment of activated carbon was carried out by oxidizing it with sulphuric acid and coating with chitosan. Two adsorbents namely Palm Shell Activated Carbon (PSAC) and Palm Shell Activated Carbon coated with Chitosan (PSACC) were used to remove chromium from aqueous solution. The effects of pH of the solution, adsorbent dosage, agitation speed, and contact time on adsorption of chromium were studied. The experimental results proved that the chromium removal efficiency of PSACC was better compared PSAC. Freundlich and Langmuir isotherms were used to analyze the adsorption of chromium from aqueous solution. The results concluded that Freundlich isotherm captured the adsorption of Chromium better compared to Langmuir isotherm as the former have higher correlation regression coefficient.

Book Heavy Metal Ion Adsorption by Coconut Shell Activated Carbon

Download or read book Heavy Metal Ion Adsorption by Coconut Shell Activated Carbon written by Deepak Kumar Dawar and published by Mohammed Abdul Malik. This book was released on 2024-03-20 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a molecular or atomic film (the adsorbate). Adsorption is operative in most natural physical, biological and chemical system and is widely used in industrial application such as activated charcoal, synthetic resins and water purification. Among these methods, adsorption is currently considered to be very suitable for waste water treatment because of its simplicity and cost effectiveness. Adsorption is commonly used technique for the removal of metal ions from various industrial effluents. It is a physicochemical process in which dissolved molecules are attached to the surface of an adsorbent by physical or chemical forces. The substance which adsorbs another substance on its surface is called as adsorbent while the substance which itself get adsorbed on the surface of another substance is called adsorbate. All adsorption performance processes are depends on solid-liquid equilibria and on mass transfer rates. If the mass transfer is in opposite direction then it is called as Desorption. Most adsorbents are highly porous materials, and adsorption takes place primarily on the walls of the pores or at the specific sites inside the particle. An adsorbent material must have a high internal volume, which is accessible to the components being removed from the solvent. Surface area and the distribution of area with respect to pore size are two very important factors in determining extent of adsorption. The overall rate of adsorption is controlled by the rate of diffusion of solute within the capillary pores of the adsorbent and varies with square root of the contact time with the adsorbent.

Book Remediation of Heavy Metals

Download or read book Remediation of Heavy Metals written by Inamuddin and published by Springer Nature. This book was released on 2021-11-10 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book presents recent remediation techniques for heavy metal contamination in wastewater, with a focus on recently-developed and sustainable materials such as metal oxides and their composites, two-dimensional materials, organic-inorganic ion exchange materials, nanomaterials, bagasse, and olive-oil waste chelating materials. Chapters also describe the analysis of heavy metals, membranes for water treatment, sources and impact of heavy metals and opportunities and challenges in heavy metal remediation.

Book Kinetic Study of Activated Carbon from Palm Kernel Shell for Copper Removal

Download or read book Kinetic Study of Activated Carbon from Palm Kernel Shell for Copper Removal written by Nur Hidayu Binti Misran and published by . This book was released on 2016 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt: The production of alternative activated carbon has been resolved to replace the costly activated carbon to remove unwanted heavy metals from contaminated water at low cost. Heavy metals are very toxicity and can harm human body. The environmental pollution became increase due to the discharge of wastewater including heavy metals and toxic nature of copper affects water resources. In this study, activated carbon produced locally from palm kernel shell was examined for the copper removal from aqueous solution by using adsorption process. Palm kernel shell not just available to get but inexpensive material that have ash content, fixed carbon, high carbon and low inorganic content. Adsorption studies conducted in completely to shown the ability of the produced activated carbon to remove copper from aqueous solutions in certain range of pH. The investigation was carried out by studying the influence of pH (1-5), adsorbent dosage (0.3-1.5 g) and initial concentration (150-350 mg/L). The result of the study shown that activated carbon from palm kernel shell with large surface area has high percentage capacity of copper removal compared to small surface area. From the result showed that the optimum parameters for maximum removal efficiency were follows as adsorbent dose (1.5 g), pH (5) and initial concentration (150 mg/L). Based on the batch adsorption experiment, the adsorption isotherm studies indicated that Langmuir model fits better for the present case. While adsorption kinetic indicated that pseudo second order model is the best for the present case.

Book Recent Progress in Desalination  Environmental and Marine Outfall Systems

Download or read book Recent Progress in Desalination Environmental and Marine Outfall Systems written by Mahad Baawain and published by Springer. This book was released on 2015-08-31 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book collects current scientific information on advanced technologies and management practices associated with the desalination industry in the Middle East and elsewhere around the world. The book opens with introductory chapter which briefly recounts the history of desalination, and describes the current state of development in the field. Part I: Desalination Systems includes ten chapters which describe a variety of techniques and designs intended not only to minimize the impact of desalination, but also to save energy and use natural resources to maximize the output of integrated desalination systems. Among the highlights are a chapter on the use of ceramic membrane technology for sustainable oil water production; a case study on the use of solar heating systems in desalination technology in Oman; discussion of fouling and its effect on design and performance of desalination systems; a review of shore approaches and sea-lines with case studies from Australia and Germany; and a discussion of the integration of desalination technology with renewable energy for climate change abatement in the Middle East and North Africa region. Part II: Environmental Systems includes among others a chapter on regulating the use of water resources and desalination technology on a regional scale reducing the carbon footprint of desalination, with examples from Australia; a description of desalination for irrigation in the Souss Massa region in the south of Morocco; a study of the impact of the coastal intake environment on operating conditions of thermal desalination plants in the United Arab Emirates; a discussion of hydrodynamic and thermal dispersion modeling of the effluent in a coastal channel, with a case study from Oman; and a mathematical model study of effluent disposal from a desalination plant in the marine environment at Tuticorin in India. The book aims to inspire developments in desalination technologies which are specifically aimed at reducing energy consumption and cost, and minimizing environmental impact.

Book Equilibrium and Kinetics of Cadmium and Zink Adsorption on Activated Carbon from Palm Kernel Shell

Download or read book Equilibrium and Kinetics of Cadmium and Zink Adsorption on Activated Carbon from Palm Kernel Shell written by Muhammad and published by . This book was released on 2006 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: A series of batch laboratory studies were conducted in order to investigate the suitability of palm kernel shell (PKS)-based activated carbon for the removal of cadmium (cadmium ions) and zinc (zinc ions) from their aqueous solutions. Single and binary adsorption isotherms and kinetics were investigated. All batch experiments were carried out at a constant temperature of 30±1oC using an incubator shaker that operated at 150 rpm. A concentration ratio of cadmium and zinc used in the adsorption of binary system is 1:1. Batch equilibrium studies showed that adsorption of cadmium and zinc were highly pH dependent. Uptake of cadmium and zinc increased with pH with maximum removal observed at pH 7.0, and decreased thereafter with further increase in the initial pH. In a single component system, the adsorption capacity of cadmium was higher than zinc, whilst in a binary component system, the adsorption capacity of zinc was higher than cadmium. The single component equilibrium data was analyzed using the Langmuir, Freundlich and Redlich-Peterson isotherms. Overall, the Redlich-Peterson isotherm showed the best fit for all adsorption under investigation in terms of correlation coefficient as well as error analysis. For all the systems studied, the analysis of isotherm shape factor showed that the adsorption was favorable. Equilibrium isotherms for the binary adsorption of cadmium (II) and zinc (II) ions onto PKS-base activated carbon have been analyzed by using the ideal adsorbed solution (IAS) theory, extended Langmuir (EL), modified extended Langmuir (MEL), modified extended Freundlich (MEF) and modified extended Redlich-Peterson (MERP) models. The binary isotherm data could be described reasonably well by the modified extended Langmuir model. The kinetics of single and binary systems describing the sorption of cadmium and zinc have been investigated. The rate models evaluated include the pseudo first order, the pseudo-second order and the intraparticle diffusion models. Kinetic data showed that the adsorption rates were a function of initial adsorbate concentration. For both single and binary systems, the pseudo-second order model correlate excellently the experimental data, suggesting that chemisorption processes could be the rate-limiting step.

Book Biosorption Processes for Heavy Metal Removal

Download or read book Biosorption Processes for Heavy Metal Removal written by Saini, Pinki and published by IGI Global. This book was released on 2024-03-11 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Persistent and non-degradable, heavy metals stand as pollutants with the potential for severe ecological repercussions when released into the environment. Municipal and industrial wastewater face a high risk of contamination by these hazardous substances, posing a formidable challenge to water treatment technologies. The imperative is clear: effective and affordable methods for effluent treatment and metal recovery are essential for meeting regulatory standards and unlocking the latent value of valuable metals within the waste. However, new methods of accomplishing this challenge are necessary for increasing the effectiveness in both cost and application Biosorption Processes for Heavy Metal Removal comprehensively explores the imperative to remove heavy metals from waste streams. It provides an insightful overview of biosorbents and biosorption technology, focusing on their underlying biosorption features. The compilation within this book comprises of a series of review articles delving into the current understanding of biosorption mechanisms and biochemistry, the efficacy of bacterial, fungal, and algal biomass, and practical considerations for biosorbent preparation and engineering. The physicochemical evaluations of biosorbents, process optimization, and factors influencing biosorption efficiency are also covered. Furthermore, the book explores biosorption applications for removing nutrients, organic pollutants, and metals in wastewater treatment across diverse contexts. Geared towards administrators, policymakers, consultants, industry professionals, academicians, scientists, researchers, and graduate and post-graduate students in environmental sciences and related fields, this book serves as their comprehensive reference.

Book Adsorption of Heavy Metals by Using Activated Carbon

Download or read book Adsorption of Heavy Metals by Using Activated Carbon written by Mohamed El Zayat and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this Book, The utilization of agricultural waste to produce valuable products has been investigated to minimize serious public health risks from exposure to dangerous fumes that come from burning the agricultural wastes in open fields. In this study, activated carbon produced from cotton stalks was examined for the removal of target heavy metal contaminants from water and wastewater. Adsorption studies conducted in completely mixed batch reactors and continuous flow columns showed a good affinity of the produced activated carbon to remove heavy metals, namely lead, cadmium and copper from aqueous solutions compared to other commercial adsorbents. The highest adsorption capacity was for lead, followed by copper and then cadmium. Multicomponent metal adsorption experiments indicated a competition for the available surface sites. Adsorption capacities in the mixture were reduced from their single-solute values for all metals.

Book Biosorption of Heavy Metals

Download or read book Biosorption of Heavy Metals written by Bohumil Volesky and published by CRC Press. This book was released on 1990-08-15 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: This state-of-the-art volume represents the first comprehensively written book which focuses on the new field of biosorption. This fascinating work conveys essential fundamental information and outlines the perspectives of biosorption. It summarizes the metal-sorbing properties of nonliving bacterial, fungal, and algal biomass, plus highlights relevant metal-binding mechanisms. This volume also discusses the aspects of obtaining and processing microbial biomass and metal-chelating chemicals into industrially applicable biosorbent products. Microbiologists, chemists, and engineers with an interest in new technological and scientific horizons will find this reference indispensable.

Book Development and Characterization of a Peanut shell Based Activated Carbon and the Outcomes of a Hands on Approach to Chemical Education

Download or read book Development and Characterization of a Peanut shell Based Activated Carbon and the Outcomes of a Hands on Approach to Chemical Education written by Danielle Pitre and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heavy metals are a recognized toxic environmental contaminant, even at very low concentrations. There have been well-known events in the last decade within the US of high amounts of lead in the drinking water supplies of cities, leading to detrimental effects within its population. Ways have been found to remove this metal, and others, from water with expensive adsorbents. The aim of the first part of this research was to create an inexpensive adsorbent from a waste material and modify it in such a way that it would be adept at removing heavy metals from water. In Chapter I, we were able to remove lead, copper, and cadmium using our peanut shell-based activated carbon, getting a high amount of metal adsorption when the activated carbon was activated with phosphoric acid, pyrolyzed, and then cooled under a nitrogen atmosphere. The activated carbon was characterized and found to have a BET surface area of 781 m2g-1 and a Langmuir maximum isotherm capacity of 100.2 mg/g. By using the data obtained in this work, it could lead to the development of further economically made adsorbents to be used to provide more people with clean drinking water. The second part of our work focused on the benefit of a hands-on approach to chemical education. In Chapter IV, we discuss the development and implementation of our NSF-funded summer research experience for undergraduates program, as well as the student-reported results from their 10-week research experience. These surveys showed consistent self-reported growth among the student cohort in the skill sets that were focused on during the program. Chapter V focuses on the development, application, and analysis of results for a novel home-based laboratory component for a semester-long organic chemistry course. It featured 12 lab activities: 8 hands-on experiments and 4 online modeling exercises. By developing and sharing this off-campus approach, we hope to provide an option for other universities that are looking for at-home laboratory experiences for their own students. Overall, we found that these approaches to experiencing chemistry in a hands-on way were beneficial to students and provided them with a greater interest in chemistry.

Book Production of Activated Carbon from Oil Palm Empty Fruit Bunches for Removal of Cadmium

Download or read book Production of Activated Carbon from Oil Palm Empty Fruit Bunches for Removal of Cadmium written by Amode Jeminat Omotayo and published by . This book was released on 2010 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Different method of preparations had been proposed by prior research studies to remove heavy metals from industrial wastewater. In this research, various PAC samples from oil palm empty fruit bunches have been prepared by physical activation using steam to study the varying operating parameters of activation temperature, activation time and steam flow rate using 2- level full factorial experimental design to screen for the best quality adsorbent. The prepared EFB samples were carbonized for 30 minutes using nitrogen gas, followed by activation with steam gas at different thermal activation temperature of 600, 750 and 900°C with steam flow rates 2.0, 3.0, 4.0 mL/min, and contact time at 15, 30 and 45 minutes respectively for the production of activated carbon. Series of batch laboratory experiments were conducted in order to investigate the feasibility of activated carbon -derived from oil palm empty fruit bunches for the removal cadmium from aqueous solution through the adsorption process. Assessment was carried out by studying the influence of removal of Cadmium due to pH, adsorbent dosage and agitation rate to select the optimum production conditions for the novel PACs. Based on the analysis of variance (ANOVA) and batch adsorption test, the results indicated that activated carbon derived from 900°C, steam flow rate- 2ml/min and activation time of 15 minutes had maximum adsorption capacity at 2 mins (0.273 mg/g) for the removal of cadmium (97.2 %), R2 = 0.999 in the aqueous solutions with a yield of 21.8% and correlation coefficient R2 = 0.992. The optimum PAC sample selected was investigated through adsorption tests on aqueous solution of cadmium using the adsorption isotherms such as Langmuir and Freundlich to evaluate or predict the adsorption characteristics. In the isotherm studies, the trend of Langmuir and Freundlich coefficients ( , , and n) were in agreement with cadmium initial concentration trend. Batch adsorption studies showed that equilibrium time of 2 mins of agitation at 150 rpm was needed for the adsorption of cadmium on the activated carbon during experiment. The regression coefficient (R2) showed that Langmuir isotherm (R2= 0.984) fits the result better than Freundlich isotherms (R2 = 0.950). The characterization of PACs produced was measured to evaluate its quality and the results showed that 900°C activation temperature, 15 minutes activation time and 2.0 ml/mins steam flow rate had a high surface area of 635.16m2/g. These characteristics were observed to have favoured 900°C activated temperature, 15 mins activation time and 2.0 ml/mins steam flow rate with respect to adsorption of cadmium. EFB based- PAC would be promising in such a way that the industrial oil palm solid residue would.

Book Sustainable Agriculture Reviews 40

Download or read book Sustainable Agriculture Reviews 40 written by Eric Lichtfouse and published by Springer Nature. This book was released on 2020-02-12 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews recent research advances in sustainable agriculture, with focus on crop production, biodiversity and biofuels in Africa and Asia.

Book Activated Carbon From Shells of Walnut Almond Poplar Tree Wood for Phenolics and Heavy Metals Adsorption From Contaminated Water

Download or read book Activated Carbon From Shells of Walnut Almond Poplar Tree Wood for Phenolics and Heavy Metals Adsorption From Contaminated Water written by Ripu Daman Kumar and published by Independent Author. This book was released on 2023-02-20 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The utilisation of activated carbon derived from the shells of walnut, almond, and poplar trees for the adsorption of phenolics and heavy metals from tainted water is examined in the book.