Download or read book A Textbook of Organic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2019-01-01 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of organic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of the four-volume series, entitled “A Textbook of Organic Chemistry – Volume I, II, III, IV”. CONTENTS: CHAPTER 1. Nature of Bonding in Organic molecules: Delocalized Chemical Bonding; Conjugation; Cross Conjugation; Resonance; Hyperconjugation; Tautomerism; Aromaticity in Benzenoid and Nonbenzenoid Compounds; Alternant and Non-Alternant Hydrocarbons; Huckel’s Rule: Energy Level of p-Molecular Orbitals; Annulenes; Antiaromaticity; Homo-Aromaticity; PMO Approach; Bonds Weaker than Covalent; Addition Compounds: Crown Ether Complexes and Cryptands, Inclusion Compounds, Cyclodextrins; Catenanes and Rotaxanes CHAPTER 2. Stereochemistry: Chirality; Elements of symmetry; Molecules with more than one chiral centre: diastereomerism; Determination of relative and absolute configuration (octant rule excluded) with special reference to lactic acid, alanine & mandelic acid; Methods of resolution; Optical purity; Prochirality; Enantiotopic and diastereotopic atoms, groups and faces; Asymmetric synthesis: cram’s rule and its modifications, prelog’s rule; Conformational analysis of cycloalkanes (upto six membered rings); Decalins; Conformations of sugars; Optical activity in absence of chiral carbon (biphenyls, allenes and spiranes); Chirality due to helical shape; Geometrical isomerism in alkenes and oximes; Methods of determining the configuration CHAPTER 3. Reaction Mechanism: Structure and Reactivity: Types of mechanisms; Types of reactions; Thermodynamic and kinetic requirements; Kinetic and thermodynamic control; Hammond’s postulate; Curtin-Hammett principle; Potential energy diagrams: Transition states and intermediates; Methods of determining mechanisms; Isotope effects; Hard and soft acids and bases; Generation, structure, stability and reactivity of carbocations, carbanions, free radicals, carbenes and nitrenes; Effect of structure on reactivity; The Hammett equation and linear free energy relationship; Substituent and reaction constants; Taft equation CHAPTER 4. Carbohydrates: Types of naturally occurring sugars; Deoxy sugars; Amino sugars; Branch chain sugars; General methods of determination of structure and ring size of sugars with particular reference to maltose, lactose, sucrose, starch and cellulose. CHAPTER 5. Natural and Synthetic Dyes: Various classes of synthetic dyes including heterocyclic dyes; Interaction between dyes and fibers; Structure elucidation of indigo and Alizarin CHAPTER 6. Aliphatic Nucleophilic Substtitution: The SN2, SN1, mixed SN1 and SN2, SNi , SN1’, SN2’, SNi’ and SET mechanisms; The neighbouring group mechanisms; neighbouring group participation by p and s bonds; anchimeric assistance; Classical and nonclassical carbocations; Phenonium ions; Common carbocation rearrangements; Applications of NMR spectroscopy in the detection of carbocations; Reactivity- effects of substrate structure, attacking nucleophile, leaving group and reaction medium; Ambident nucleophiles and regioselectivity; Phase transfer catalysis. CHAPTER 7. Aliphatic Electrophilic Substitution: Bimolecular mechanisms – SE2 and SEi; The SE1 mechanism; Electrophilic substitution accompained by double bond shifts; Effect of substrates, leaving group and the solvent polarity on the reactivity CHAPTER 8. Aromatic Electrophilic Substitution: The arenium ion: mechanism, orientation and reactivity, energy profile diagrams; The ortho/para ratio, ipso attack, orientation in other ring systems; Quantitative treatment of reactivity in substrates and electrophiles; Diazonium coupling; Vilsmeir reaction; Gattermann-Koch reaction CHAPTER 9. Aromatic Nucleophilic Substitution: The ArSN1, ArSN2, Benzyne and SRN1 mechanisms; Reactivity – effect of substrate structure, leaving group and attacking nucleophile; The von Richter, Sommelet-Hauser, and Smiles rearrangements CHAPTER 10. Elimination Reactions: The E2, E1 and E1cB mechanisms; Orientation of the double bond; Reactivity –effects of substrate structures, attacking base, the leaving group and the medium; Mechanism and orientation in pyrolytic elimination CHAPTER 11. Addition to Carbon-Carbon Multiple Bonds: Mechanistic and stereochemical aspects of addition reactions involving electrophiles, nucleophiles and free radicals; Regio–and chemoselectivity: orientation and reactivity; Addition to cyclopropane ring; Hydrogenation of double and triple bonds; Hydrogenation of aromatic rings; Hydroboration; Michael reaction; Sharpless asymmetric epoxidation. CHAPTER 12. Addition to Carbon-Hetero Multiple Bonds: Mechanism of metal hydride reduction of saturated and unsaturated carbonyl compounds, acids, esters and nitriles; Addition of Grignard reagents, organozinc and organolithium; Reagents to carbonyl and unsaturated carbonyl compounds; Wittig reaction; Mechanism of condensation reactions involving enolates – Aldol, Knoevenagel, Claisen, Mannich, Benzoin, Perkin and Stobbe reactions; Hydrolysis of esters and amides; Ammonolysis of esters.
Download or read book A Textbook of Organic Chemistry Vol 1 written by Dr. Akshay Kumar Shukla and published by Bhartiya Sahitya Inc.. This book was released on 2020-06-22 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Knowledge of organic chemistry continues to move ahead in the many fronts. This Competitor's Organic Chemistry has been thoroughly covering the subject to reflect this growth. Competitor's Organic Chemistry has been divided in three volumes, I, II and III for the study of organic chemistry to the students of B. Sc. I, II and III, respectively. These books have been written according to UGC curriculum and cover full syllabus. The series of books are basically designed for the study of organic chemistry of graduate level students but these books will also be helpful and useful for many competitive examinations. The books describe the basic and fundamental concepts, basic structures, reactions and mechanisms of organic chemistry. An effort has also been made to guide the students for reaction based numerical problems of organic chemistry. The readers will observe that this text contains much and sufficient material and it goes more deeply into the subject. It is our request that readers will provide their valuable feedback about books.
Download or read book Organic Chemistry Volume 1 written by Roger Macomber and published by University Science Books. This book was released on 1996-04-26 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first of a two-volume set designed for a course focused on the fundamentals of organic chemistry for pre-meds, and chemistry/bioscience students. It covers the major aspects of molecular structure, followed by an introduction to the techniques of physical and organic chemistry.
Download or read book Organic Chemistry Volume 1 6 E written by Finar and published by Pearson Education India. This book was released on 1973-09 with total page 984 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Textbook of Organic Chemistry written by K. S. Tewari and published by . This book was released on 1976 with total page 1394 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Textbook of Organic Chemistry written by V. K. Ahluwalia and published by Alpha Science Int'l Ltd.. This book was released on 2000 with total page 1012 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emphasis on structure activity relationship, molecules in 3-D and spectroscopic methods based on homologous series. Provides a comprehensive coverage of nomenclature, structure and properties of organic compounds including aromaticity, aromatic substitution and orientation and natural products. Also intorduces the reader to pharmaceuticals, pesticides and enzymes. Each chapter accompanied with problems.
Download or read book Organic Chemistry 1 written by Martin Walker and published by State University of New York Oer Services. This book was released on 2018-08-11 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Chemistry written by Robert J. Ouellette and published by Elsevier. This book was released on 2014-06-06 with total page 1241 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry provides a comprehensive discussion of the basic principles of organic chemistry in their relation to a host of other fields in both physical and biological sciences. This book is written based on the premise that there are no shortcuts in organic chemistry, and that understanding and mastery cannot be achieved without devoting adequate time and attention to the theories and concepts of the discipline. It lays emphasis on connecting the basic principles of organic chemistry to real world challenges that require analysis, not just recall. This text covers topics ranging from structure and bonding in organic compounds to functional groups and their properties; identification of functional groups by infrared spectroscopy; organic reaction mechanisms; structures and reactions of alkanes and cycloalkanes; nucleophilic substitution and elimination reactions; conjugated alkenes and allylic systems; electrophilic aromatic substitution; carboxylic acids; and synthetic polymers. Throughout the book, principles logically evolve from one to the next, from the simplest to the most complex examples, with abundant connections between the text and real world applications. There are extensive examples of biological relevance, along with a chapter on organometallic chemistry not found in other standard references. This book will be of interest to chemists, life scientists, food scientists, pharmacists, and students in the physical and life sciences. Contains extensive examples of biological relevance Includes an important chapter on organometallic chemistry not found in other standard references Extended, illustrated glossary Appendices on thermodynamics, kinetics, and transition state theory
Download or read book Organic Chemistry written by David R. Klein and published by John Wiley & Sons. This book was released on 2017-08-14 with total page 1312 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Organic Chemistry, 3rd Edition, Dr. David Klein builds on the phenomenal success of the first two editions, which presented his unique skills-based approach to learning organic chemistry. Dr. Klein’s skills-based approach includes all of the concepts typically covered in an organic chemistry textbook, and places special emphasis on skills development to support these concepts. This emphasis on skills development in unique SkillBuilder examples provides extensive opportunities for two-semester Organic Chemistry students to develop proficiency in the key skills necessary to succeed in organic chemistry.
Download or read book March s Advanced Organic Chemistry written by Michael B. Smith and published by John Wiley & Sons. This book was released on 2007-01-29 with total page 2379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations
Download or read book Organic Chemistry written by Kyle J Mickelson and published by . This book was released on 2020-12-28 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook that will aid in proficiency of the basics of organic reactions, mechanisms, and processes through which chemical compounds form and react. The first volume in this series covers much of the reactions of alkenes and alkynes, as well as several other key functional groups in organic chemistry. This resource provides tools and study guides for each topic, featuring a variety of problems and common mistakes to help readers build fluency in solving problems. Topics covered include: bonding & resonance, orbital hybridization, stereochemistry, organic nomenclature, the chemistry of alkenes and alkynes, SN1/E1 and SN2/E2 reactions, acid-base chemistry, as well as choice components of the reactions of alcohols. The topics and ideas covered in this volume are identical to those covered in a first year organic chemistry course. It is complete with many graphical depictions of reactions and their mechanisms, with their processes well-explained, as well as end of chapter problems for you to try on your own after mastering the material in the chapter. Whether it be for a course at university or for a general love of learning, this book will help you to master key principles when it comes to understanding and deciphering organic chemistry. A keen awareness of these ideas is useful even in everyday life, on the back of a bottle of shampoo or in the foods that we eat everyday. The importance of this topic cannot be understated and it would be beneficial to anyone to develop this awareness. Overall, this textbook is a tool on your path to mastering organic chemistry!
Download or read book Problems Book for Organic Chemistry First Edition written by Robert Engel and published by Cognella Academic Publishing. This book was released on 2019-04-17 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed to supplement standard organic chemistry textbooks used in two-semester courses, Problems Book for Organic Chemistry is a practical and highly applicable study aid that increases students' problem-solving abilities and effectively prepares them for exams. The book challenges students to participate in a series of timed examinations, replicating the real conditions under which exams are generally given to effectively prepare students to problem-solve under pressure. After completing each exam, students are provided with detailed answers and encouraged to self-grade their work to better understand their individual mastery of the material. The concepts in each exam, as well as their order, mirror the progression of a standard two-semester organic chemistry course. Innovative in approach, Problems Book for Organic Chemistry is an ideal resource for students enrolled in organic chemistry courses.
Download or read book Organic Chemistry written by Francis A. Carey and published by McGraw-Hill Science, Engineering & Mathematics. This book was released on 1996 with total page 1151 pages. Available in PDF, EPUB and Kindle. Book excerpt: "A Market Leading, Traditional Approach to Organic Chemistry" Throughout all seven editions, Organic Chemistry has been designed to meet the needs of the "mainstream," two-semester, undergraduate organic chemistry course. This best-selling text gives students a solid understanding of organic chemistry by stressing how fundamental reaction mechanisms function and reactions occur. With the addition of handwritten solutions, new cutting-edge molecular illustrations, updated spectroscopy coverage, seamless integration of molecular modeling exercises, and state-of-the-art multimedia tools, the 7th edition of Organic Chemistry clearly offers the most up-to-date approach to the study of organic chemistry.
Download or read book Principles of Asymmetric Synthesis written by Robert E. Gawley and published by Elsevier. This book was released on 2012-07-16 with total page 569 pages. Available in PDF, EPUB and Kindle. Book excerpt: The world is chiral. Most of the molecules in it are chiral, and asymmetric synthesis is an important means by which enantiopure chiral molecules may be obtained for study and sale. The aim of this book is to present a detailed analysis of the factors that govern stereoselectivity in organic reactions.
Download or read book Organic Chemistry I as a Second Language written by David R. Klein and published by Wiley. This book was released on 2007-06-22 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Get a Better Grade in Organic Chemistry Organic Chemistry may be challenging, but that doesn't mean you can't get the grade you want. With David Klein's Organic Chemistry as a Second Language: Translating the Basic Concepts, you'll be able to better understand fundamental principles, solve problems, and focus on what you need to know to succeed. Here's how you can get a better grade in Organic Chemistry: Understand the Big Picture. Organic Chemistry as a Second Language points out the major principles in Organic Chemistry and explains why they are relevant to the rest of the course. By putting these principles together, you'll have a coherent framework that will help you better understand your textbook. Study More Efficiently and Effectively Organic Chemistry as a Second Language provides time-saving study tips and a clear roadmap for your studies that will help you to focus your efforts. Improve Your Problem-Solving Skills Organic Chemistry as a Second Language will help you develop the skills you need to solve a variety of problem types-even unfamiliar ones! Need Help in Your Second Semester? Get Klein's Organic Chemistry II as a Second Language! 978-0-471-73808-5
Download or read book Encyclopedia of Physical Organic Chemistry 6 Volume Set written by Zerong Wang and published by John Wiley & Sons. This book was released on 2017-04-17 with total page 4542 pages. Available in PDF, EPUB and Kindle. Book excerpt: Winner of 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE This encyclopedia offers a comprehensive and easy reference to physical organic chemistry (POC) methodology and techniques. It puts POC, a classical and fundamental discipline of chemistry, into the context of modern and dynamic fields like biochemical processes, materials science, and molecular electronics. Covers basic terms and theories into organic reactions and mechanisms, molecular designs and syntheses, tools and experimental techniques, and applications and future directions Includes coverage of green chemistry and polymerization reactions Reviews different strategies for molecular design and synthesis of functional molecules Discusses computational methods, software packages, and more than 34 kinds of spectroscopies and techniques for studying structures and mechanisms Explores applications in areas from biology to materials science The Encyclopedia of Physical Organic Chemistry has won the 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE. The PROSE Awards recognize the best books, journals and digital content produced by professional and scholarly publishers. Submissions are reviewed by a panel of 18 judges that includes editors, academics, publishers and research librarians who evaluate each work for its contribution to professional and scholarly publishing. You can find out more at: proseawards.com Also available as an online edition for your library, for more details visit Wiley Online Library
Download or read book Organic Chemistry written by Henry Enfield Roscoe and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
