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Book The Oceanic Biogeochemical Cycling of Copper and Zinc and Their Isotopes

Download or read book The Oceanic Biogeochemical Cycling of Copper and Zinc and Their Isotopes written by Susan H. Little and published by . This book was released on 2013 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Marine Biogeochemistry of Zinc Isotopes

Download or read book The Marine Biogeochemistry of Zinc Isotopes written by Seth G. John and published by . This book was released on 2007 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Cont.) Seawater dissolved Zn isotopes also reflect the chemical and biological cycling of Zn. The [delta]66Zn of deep seawater in the North Pacific and North Atlantic is about 0.5%0, and the dissolved [delta]66Zn gets lighter in the upper water column. This is unexpected based our observations of a biological preference for uptake of light Zn isotopes, and suggests that Zn transport to deep waters may occur by Zn adsorption to sinking particles rather than as primary biological Zn. The thesis, by presenting data on several important aspects of Zn isotope cycling in the oceans, lays the groundwork for further use of Zn isotopes as a marine biogeochemical tracer.

Book Copper and Zinc Stable Isotope Ratios as Tracers of Biogeochemical Processes  Sources and Transport of Cu and Zn in Soils

Download or read book Copper and Zinc Stable Isotope Ratios as Tracers of Biogeochemical Processes Sources and Transport of Cu and Zn in Soils written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper and Zn are essential micronutrients for plants, animals, and humans; however, they may also be pollutants if they occur at high concentrations in soil. Therefore, knowledge of Cu and Zn cycling in soils is required both for guaranteeing proper nutrition and to control possible risks arising from pollution.rnThe overall objective of my study was to test if Cu and Zn stable isotope ratios can be used to investigate into the biogeochemistry, source and transport of these metals in soils. The use of stable isotope ratios might be especially suitable to trace long-term processes occurring during soil genesis and transport of pollutants through the soil. In detail, I aimed to answer the questions, whether (1) Cu stable isotopes are fractionated during complexation with humic acid, (2) d65Cu values can be a tracer for soil genetic processes in redoximorphic soils (3) d65Cu values can help to understand soil genetic processes under oxic weathering conditions, and (4) d65Cu and d66Zn values can act as tracers of sources and transport of Cu and Zn in polluted soils.rnTo answer these questions, I ran adsorption experiments at different pH values in the laboratory and modelled Cu adsorption to humic acid. Furthermore, eight soils were sampled representing different redox and weathering regimes of which two were influenced by stagnic water, two by groundwater, two by oxic weathering (Cambisols), and two by podzolation. In all horizons of these soils, I determined selected basic soil properties, partitioned Cu into seven operationally defined fractions and determined Cu concentrations and Cu isotope ratios (d65Cu values). Finally, three additional soils were sampled along a deposition gradient at different distances to a Cu smelter in Slovakia and analyzed together with bedrock and waste material from the smelter for selected basic soil properties, Cu and Zn concentrations and d65Cu and d66Zn values.rnMy results demonstrated that (1) Copper was fractionated during adsorpti.

Book Investigations Into Isotope Biogeochemistry of Zn in Coastal Areas and Mangroves

Download or read book Investigations Into Isotope Biogeochemistry of Zn in Coastal Areas and Mangroves written by Daniel Ferreira Araujo and published by . This book was released on 2016 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coastal areas worldwide are under strong pressure from anthropogenic contamination, as most of the global population and of economic activities are concentrated along the coasts and estuaries. The threaten of contaminant releasing into these ecosystems makes imperative the development of tools capable of detecting biogeochemical changes in order to help prevention, monitoring and prediction of risks in environmental studies. In this way, this thesis investigates the isotope biogeochemistry of Zinc (Zn) in order to develop a tool capable of tracing natural and anthropogenic sources, identifying biogeochemical processes and enabling the biomonitoring of metal contamination in coastal areas and mangroves. To this end, Zn isotopes compositions were determined in several natural samples collected from Sepetiba bay (southeastern Brazil), an estuarine-lagoon impacted by an industrialized coastal area near Rio de Janeiro. This bay constitutes an ideal natural laboratory for evaluating the Zn isotopic system to environmental issues, since it hosts important ecosystems of commercial and ecological interest - estuaries, mangroves and tidal flats - threaten by the metal contamination resultant of old electroplating activity and other anthropogenic diffuse sources. The collected samples include sediment cores, surface mangrove sediments, suspended particulate matter (SPM), leaves of mangrove's trees, tissues of bivalve mollusks (oysters and mussels) and rocks. Ores from Vazante deposit, Brazil were collected to represent the raw material used in the old electroplating industry. Firstly, an initial laboratory work established a method for accurate and precise determinations of Zn isotope compositions in natural samples by multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). Spatial and temporal analysis of Zn isotope compositions of sediment and rock samples fits well in a model of mixing between three main end-members: i) continental materials brought via rivers; ii) marine sources; and iii) a major anthropogenic source associated to the old electroplating wastes released into the bay. Sediment cores collected in the mud flat showed high correlation between Zn isotope compositions and Zn enrichment factors, suggesting (i) good preservation of isotopic records of natural and anthropogenic sources and (ii) no significant isotopic fractionation during sediment transport or as a result of diagenetic reactions post-deposition in the estuarine system. The sediment core sampled from a mangrove located in the zone impacted by the old electroplating activity presented levels of Zn up to 4% (dry weight) and preserved the isotopic signatures of electroplating wastes. However, there is evidence that biogeochemical processes triggered by hydrodynamics, bioturbation or rhizosphere processes slightly changed the isotopic signatures in some layers. Calculations based in this mixing model quantified contributions of the major anthropogenic source of Zn, ranging from negligible values in the pre-industrial period to nearly 80% during periods of electroplating activities between the 60's and 90's.

Book Marine Biogeochemical Cycling of Cadmium and Its Isotopes

Download or read book Marine Biogeochemical Cycling of Cadmium and Its Isotopes written by Ejin George and published by . This book was released on 2017 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface Cd concentrations are enriched in the Mediterranean Sea compared to the surface concentrations of the Atlantic and Pacific Oceans. The depth distribution of Cd in the northern Mediterranean Sea shows significant variations between the eastern and western Mediterranean basins (EMED and WMED, respectively). In the WMED, Cd follows a nutrient-type depth distribution. However, a better correlation of Cd with salinity compared to the major nutrient PO4 suggests that mixing is likely to be the main factor controlling the vertical Cd distribution in the WMED. In contrast, the Cd depth distribution is homogenous in the EMED and dissolved Cd does not show any significant correlation with either salinity or PO4. The similar endmember Cd concentrations of different deep water masses existing in the EMED might explain the homogenous dissolved Cd distribution. These results will inform a planned Cd isotope study of the Mediterranean Sea.

Book Ore Deposits

    Book Details:
  • Author : Sophie Decree
  • Publisher : John Wiley & Sons
  • Release : 2019-04-23
  • ISBN : 1119290538
  • Pages : 272 pages

Download or read book Ore Deposits written by Sophie Decree and published by John Wiley & Sons. This book was released on 2019-04-23 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: The latest knowledge on mineral ore genesis and the exploration of ore deposits Global demand for metals has risen considerably over the past decade. Geologists are developing new approaches for studying ore deposits and discovering new sources. Ore Deposits: Origin, Exploration, and Exploitation is a compilation of diverse case studies on new prospects in ore deposit geology including atypical examples of mineral deposits and new methods for ore exploration. Volume highlights include: Presentation of the latest research on a range of ore deposit types Application of ore deposits to multiple areas of geology and geophysical exploration Emphasis on diverse methods and tools for the study of ore deposits Useful case studies for geologists in both academia and industry Ore Deposits: Origin, Exploration, and Exploitation is a valuable resource for economic geologists, mineralogists, petrologists, geochemists, mining engineers, research professionals, and advanced students in relevant areas of academic study. Read an interview with the editors to find out more: https://eos.org/editors-vox/developments-in-the-continuing-search-for-new-mineral-deposits

Book Geochemistry of Non Traditional Stable Isotopes

Download or read book Geochemistry of Non Traditional Stable Isotopes written by Clark M. Johnson and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: The goal for Volume 55 of Reviews in Mineralogy and Geochemistry was to bring together a summary of the isotope geochemistry of non-traditional stable isotope systems as is known through 2003 for those elements that have been studied in some detail, and which have a variety of geochemical properties. In addition, recognizing that many of these elements are of interest to workers who are outside the traditional stable isotope fields, we felt it was important to include discussions on the broad isotopic variations that occur in the solar system, theoretical approaches to calculating isotopic fractionations, and the variety of analytical methods that are in use. We hope, therefore, that this volume proves to be useful to not only the isotope specialist, but to others who are interested in the contributions that these non-traditional stable isotopes may make toward understanding geochemical and biological cycles. The review chapters in this volume were the basis for a two-day short course on nontraditional stable isotopes held prior (May 15-16, 2004) to the spring AGU/CGU Meeting in Montreal, Canada.

Book Introduction to Geochemical Modeling

Download or read book Introduction to Geochemical Modeling written by Francis Albarède and published by Cambridge University Press. This book was released on 1995-04-13 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: An introduction to quantitative geochemical modeling for the researcher and advanced student.

Book Geochemical Signals in Dynamic Sedimentary Systems Along Continental Margins

Download or read book Geochemical Signals in Dynamic Sedimentary Systems Along Continental Margins written by Natascha Riedinger and published by Frontiers Media SA. This book was released on 2022-05-04 with total page 165 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Stable Isotope Geochemistry

Download or read book Stable Isotope Geochemistry written by Jochen Hoefs and published by Springer Nature. This book was released on 2021-10-08 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: This classic textbook is an introduction to the systematics and the use of stable isotopes in geosciences. It is subdivided into three parts: i) theoretical and experimental principles, ii) fractionation processes of light and heavy elements, iii) the natural variations of geologically important reservoirs. Since the publication of the previous edition improvements in multi-collector ICP mass-spectrometry have increased the ability to measure isotope ratios with very high precision for many elements of the periodic table. The amount of published data has increased tremendously in the last years; thus, conclusions based on a limited database are now better constrained. In this new edition, therefore, 47 elements with resolvable natural variations in isotope composition are discussed. This increase of elements, together with advances in the calculation of equilibrium isotope fractionation using ab initio methods, has led to an unbelievable rise of publications, making substantial major revisions and extensions of the last edition necessary. Many new references have been added, which enable quick access to recent literature.

Book The Anthropocene as a Geological Time Unit

Download or read book The Anthropocene as a Geological Time Unit written by Jan Zalasiewicz and published by Cambridge University Press. This book was released on 2019-03-07 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews the evidence underpinning the Anthropocene as a geological epoch written by the Anthropocene Working Group investigating it. The book discusses ongoing changes to the Earth system within the context of deep geological time, allowing a comparison between the global transition taking place today with major transitions in Earth history.

Book The Biological Chemistry of the Elements

Download or read book The Biological Chemistry of the Elements written by J. J. R. Frausto da Silva and published by Oxford University Press. This book was released on 2001-08-16 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text describes the functional role of the twenty inorganic elements essential to life in living organisms.

Book Geology of the Mineral Deposits of Australia and Papua New Guinea

Download or read book Geology of the Mineral Deposits of Australia and Papua New Guinea written by Francis Everard Hughes and published by . This book was released on 1990 with total page 1054 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Isotopes in the Water Cycle

Download or read book Isotopes in the Water Cycle written by Pradeep K. Aggarwal and published by Springer Science & Business Media. This book was released on 2006-01-16 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental isotope and nuclear techniques provide unmatched insights into the processes governing the water cycle and its variability. This monograph presents state of the art applications and new developments of isotopes in hydrology, environmental disciplines and climate change studies. Coverage ranges from the assessment of groundwater resources in terms of recharge and flow regime to studies of the past and present global environmental and climate changes.

Book Biogeochemistry of Wetlands

Download or read book Biogeochemistry of Wetlands written by K. Ramesh Reddy and published by CRC Press. This book was released on 2022-09-10 with total page 926 pages. Available in PDF, EPUB and Kindle. Book excerpt: The globally important nature of wetland ecosystems has led to their increased protection and restoration as well as their use in engineered systems. Underpinning the beneficial functions of wetlands are a unique suite of physical, chemical, and biological processes that regulate elemental cycling in soils and the water column. This book provides an in-depth coverage of these wetland biogeochemical processes related to the cycling of macroelements including carbon, nitrogen, phosphorus, and sulfur, secondary and trace elements, and toxic organic compounds. In this synthesis, the authors combine more than 100 years of experience studying wetlands and biogeochemistry to look inside the black box of elemental transformations in wetland ecosystems. This new edition is updated throughout to include more topics and provide an integrated view of the coupled nature of biogeochemical cycles in wetland systems. The influence of the elemental cycles is discussed at a range of scales in the context of environmental change including climate, sea level rise, and water quality. Frequent examples of key methods and major case studies are also included to help the reader extend the basic theories for application in their own system. Some of the major topics discussed are: Flooded soil and sediment characteristics Aerobic-anaerobic interfaces Redox chemistry in flooded soil and sediment systems Anaerobic microbial metabolism Plant adaptations to reducing conditions Regulators of organic matter decomposition and accretion Major nutrient sources and sinks Greenhouse gas production and emission Elemental flux processes Remediation of contaminated soils and sediments Coupled C-N-P-S processes Consequences of environmental change in wetlands# The book provides the foundation for a basic understanding of key biogeochemical processes and its applications to solve real world problems. It is detailed, but also assists the reader with box inserts, artfully designed diagrams, and summary tables all supported by numerous current references. This book is an excellent resource for senior undergraduates and graduate students studying ecosystem biogeochemistry with a focus in wetlands and aquatic systems.