Download or read book VALORISATION CHIMIQUE DU METHANE PAR OXYDATION CATALYTIQUE SELECTIVE written by Nicolas Gueritey and published by . This book was released on 1996 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt: LA CONVERSION DU METHANE, PRINCIPAL CONSTITUTANT DU GAZ NATUREL, EN PRODUITS VALORISABLES ET FACILEMENT TRANSPORTABLES CONSTITUE UN ENJEU ECONOMIQUE IMPORTANT. LA REACTION DE COUPLAGE OXYDANT DU METHANE EST UNE DES VOIES LES PLUS ETUDIEES POUR SA TRANSFORMATION DIRECTE EN HYDROCARBURES SUPERIEURS. LE RENDEMENT OBTENU ETANT TROP FAIBLE POUR ENVISAGER UNE EXPLOITATION INDUSTRIELLE, IL EST NECESSAIRE DE MIEUX COMPRENDRE LA REACTION AFIN DE POUVOIR OPTIMISER LES PARAMETRES PHYSIQUES ET CINETIQUES. CETTE REACTION EST EN EFFET COMPLEXE CAR ELLE COMPORTE DES REACTIONS CATALYTIQUES ET DES REACTIONS RADICALAIRES EN PHASE GAZEUSE. C'EST POURQUOI NOTRE OBJECTIF ETAIT DE PROGRESSER DANS LA CONNAISSANCE DU MECANISME PAR UNE ETUDE EXPERIMENTALE METTANT EN JEU TROIS REACTEURS DIFFERENTS PERMETTANT DE FAIRE VARIER SEPAREMENT LES PARAMETRES LIES AU CATALYSEUR OU A LA PHASE GAZEUSE. NOUS AVONS PAR AILLEURS FAIT UNE ETUDE DES PHENOMENES DE DIFFUSION INTERVENANT DANS CES REACTEURS. LA COMPARAISON DES RESULTATS OBTENUS AVEC CES DIFFERENTS REACTEURS A FOURNI DES INFORMATIONS ORIGINALES. NOUS AVONS ALORS PROPOSE UN MECANISME SUSCEPTIBLE DE RENDRE COMPTE DE CETTE REACTION, CE QUI PERMET D'ADAPTER LES PARAMETRES ET LE REACTEUR A LA REACTION ET D'ENVISAGER UNE MODELISATION. NOUS AVONS AINSI MIS AU POINT UN REACTEUR CAPABLE DE DONNER DE BONS RENDEMENT EN COUPLAGE OXYDANT COMME EN GAZ DE SYNTHESE

Download or read book CONTRIBUTION A LA VALORISATION CHIMIQUE DIRECTE DU GAZ NATUREL written by PATRICE.. FRANCO and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: INJECTE DANS DES GAZ DE COMBUSTION CHAUDS, LE METHANE REAGIT SELON DEUX VOIES PRINCIPALES: FORMATION D'HYDROCARBURES SUPERIEURS (PRINCIPALEMENT DE L'ACETYLENE) ET REFORMAGE (FORMATION PRINCIPALEMENT D'OXYDE DE CARBONE). DES SUIES ET DES HYDROCARBURES AROMATIQUES POLYCYCLIQUES SONT EGALEMENT OBSERVES EN FAIBLES PROPORTIONS. LA MISE AU POINT D'UN MODELE DE CINETIQUE CHIMIQUE DETAILLE VIENT COMPLETER L'ETUDE EXPERIMENTALE. LE MODELE DECRIT L'OXYDATION ET LA PYROLYSE DU METHANE PAR UN ENSEMBLE DE 461 REACTIONS ELEMENTAIRES. LA FORMATION DES SUIES EST REPRESENTEE PAR UN INDICE DE SUIE EGAL A LA FRACTION DE CARBONE PRESENT SOUS FORME DE BENZENE ET DE CYCLOPENTADIENE. LA VALIDATION DU MODELE A ETE FAITE PAR COMPARAISON AVEC DES RESULTATS EXPERIMENTAUX PUBLIES. CE MODELE CONFIRME LES RESULTATS OBTENUS AU PLAN EXPERIMENTAL ET PERMET DE SIMULER DES CONFIGURATIONS IMPOSSIBLES A ATTEINDRE SUR UNE INSTALLATION DE LABORATOIRE. IL PERMET EGALEMENT DE COMPARER DIVERS MODES DE PYROLYSE ET, EN PARTICULIER, DE CONFIRMER L'INTERET DE L'INJECTION DANS DES GAZ CHAUDS PAR RAPPORT A L'ECHANGE DE CHALEUR A TRAVERS UNE PAROI POUR REALISER LA CONVERSION DIRECTE DU METHANE. LE RENDEMENT EN ACETYLENE AUGMENTE AVEC LA TENEUR EN HYDROGENE DES GAZ CHAUDS. L'INDICE DE SUIE PEUT ETRE REDUIT EN CONTROLANT LE TEMPS DE SEJOUR ET EN AUGMENTANT LA TENEUR EN HYDROGENE DES GAZ CHAUDS

Download or read book Methane Conversion by Oxidative Processes written by Wolf and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.

Download or read book Methane Conversion by Oxidative Processes written by Eduardo E. Wolf and published by Springer. This book was released on 1992 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.

Download or read book VALORISATION DU METHANE PAR UN PLASMA D AIR OU D AZOTE COUPLAGE AVEC LA CATALYSE HETEROGENE written by AHMED.. OUMGHAR and published by . This book was released on 1992 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: LES RESERVES DU GAZ NATUREL MISES A JOUR CROISSENT REGULIEREMENT ALORS QUE CELLES DU PETROLE SEMBLENT ATTEINDRE UN PALIER. CECI DONNE UNE IMPORTANCE CROISSANTE AU GAZ NATUREL COMME MATIERE PREMIERE DES INDUSTRIES CHIMIQUES. LA TRANSFORMATION DU GAZ NATUREL EN PRODUITS PLUS LOURDS EST REALISEE A L'AIDE DE L'ENERGIE ELECTRIQUE: LE METHANE COMPOSANT MAJORITAIRE DU GAZ NATUREL REAGIT AVEC UN PLASMA D'AIR OU D'AZOTE CREE PAR UN GENERATEUR DE MICRO-ONDES A 2450 MHZ. LA REACTION ABOUTIT A LA FORMATION PRINCIPALEMENT DES PRODUITS EN C#2(C#2H#6, C#2H#4, C#2H#2), DE PRODUIT EN C#3(C#3H#8), DU MONOXYDE DE CARBONE ET DE L'HYDROGENE. L'OPTIMISATION DE CE PROCEDE EST REALISEE EN FAISANT VARIER PLUSIEURS PARAMETRES EXPERIMENTAUX A SAVOIR: STCHIOMETRIE DE LA REACTION D'OXYDATION DU METHANE, TEMPS DE SEJOUR, TEMPS AU BOUT DUQUEL LE PLASMA AGIT SUR LE METHANE, PRESSION DU MILIEU REACTIONNEL, PUISSANCE. LA FORMATION DES PRODUITS FAIT L'OBJET D'UNE DISCUSSION DES MECANISMES REACTIONNELS. PLUSIEURS CATALYSEURS ONT ETE INTRODUITS DANS LA POST-DECHARGE ET LEURS PERFORMANCES ONT ETE COMPAREES

Download or read book VALORISATION CHIMIQUE DU METHANE PAR PLASMA FROID MICROONDES written by NATHALIE.. KOPYTKO and published by . This book was released on 1993 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: LE BUT DE CE TRAVAIL DE THESE ETAIT D'ETUDIER LES REACTIONS CHIMIQUES DU METHANE EXCITE DANS UNE DECHARGE MICRO-ONDES, A BASSE PRESSION, DE MANIERE A FORMER UN PLASMA FROID. NOUS NOUS SOMMES PRINCIPALEMENT INTERESSES AUX PRODUITS OBTENUS PAR LA REACTION CHIMIQUE DU METHANE, EN PARTICULIER LES HYDROCARBURES EN C#2. NOUS AVONS ETUDIE D'ABORD LE PLASMA DE METHANE PUR. APRES LA MISE AU POINT DE L'INSTALLATION, NOUS AVONS EFFECTUE UNE ETUDE PARAMETRIQUE (INFLUENCE DU TEMPS DE PASSAGE DES GAZ DANS LE REACTEUR DE LA PUISSANCE MICRO-ONDES INCIDENTE, DU DEBIT ET DE LA PRESSION DE METHANE). NOUS AVONS ENSUITE EXAMINE DANS QUELLE MESURE LES MECANISMES REACTIONNELS SIMPLIFIES PROPOSES DANS LA LITTERATURE POUVAIENT CORRESPONDRE A NOS RESULTATS EXPERIMENTAUX. NOUS AVONS ENSUITE BRIEVEMENT ETUDIE LES PLASMAS METHANE-HYDROGENE, METHANE-OXYGENE ET METHANE-DIOXYDE DE CARBONE. NOUS AVONS COMPARE NOS RESULTATS AVEC CEUX OBTENUS PAR UNE AUTRE METHODE PLASMA DE TRANSFORMATION DU METHANE AINSI QU'AVEC CEUX RESULTANT D'AUTRES PROCEDES DE VALORISATION DIRECTE DU METHANE ACTUELLEMENT A L'ETUDE. NOUS AVONS DETERMINE QUELLES ETAIENT LES DIRECTIONS DE RECHERCHE A ENVISAGER POUR UNE SUITE DE CE TRAVAIL

Download or read book Methane Combustion over Lanthanum based Perovskite Mixed Oxides written by Hamidreza Arandiyan and published by Springer. This book was released on 2015-05-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents current research into the catalytic combustion of methane using perovskite-type oxides (ABO3). Catalytic combustion has been developed as a method of promoting efficient combustion with minimum pollutant formation as compared to conventional catalytic combustion. Recent theoretical and experimental studies have recommended that noble metals supported on (ABO3) with well-ordered porous networks show promising redox properties. Three-dimensionally ordered macroporous (3DOM) materials with interpenetrated and regular mesoporous systems have recently triggered enormous research activity due to their high surface areas, large pore volumes, uniform pore sizes, low cost, environmental benignity, and good chemical stability. These are all highly relevant in terms of the utilization of natural gas in light of recent catalytic innovations and technological advances. The book is of interest to all researchers active in utilization of natural gas with novel catalysts. The research covered comes from the most important industries and research centers in the field. The book serves not only as a text for researcher into catalytic combustion of methane, 3DOM perovskite mixed oxide, but also explores the field of green technologies by experts in academia and industry. This book will appeal to those interested in research on the environmental impact of combustion, materials and catalysis.

Download or read book Valorisation catalytique du biogaz CH4 CO2 par reformage sec written by Maryam Safariamin and published by . This book was released on 2010 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dans cette étude, la réaction de reformage du méthane par le CO2 a été étudiée en présence de catalyseurs à base de ruthénium et cuivre déposés sur Al2O3, CeO2 et oxydes binaires CeO2-Al2O3 ainsi que oxyde mixtes issus de précurseurs hydrotalcites. Le but de ce travail est la réduction des gaz à effet de serre (CH4 + CO2) afin d’obtenir le gaz de synthèse (H2 + CO) qui sera utilisé pour différentes applications dont l’énergie propre. Les catalyseurs ont été préparés par imprégnation à sec et caractérisés par différentes méthodes physico-chimique (BET, DRX, IR-FT, UV-Visible, TPR, ATD/TG et RPE) afin de dégager des corrélations entre leurs propriétés physico-chimique et leurs performances catalytiques. Les influences sur l’activité catalytique des différentes conditions et du prétraitement des solides ont été étudiées. La production d'hydrogène est fortement influencée par la nature de la phase métallique et des supports utilisés. Il est remarquable que les deux types de catalyseurs (Ru et Cu/support) n’ont pas des activités similaires pour la réaction étudiée. Les catalyseurs à base de ruthénium sont beaucoup plus actifs que ceux à base de cuivre. Les hydrotalcites se sont montrés performant pour la réaction de reformage, mais ils produisent une grande quantité du coke qui désactive facilement le catalyseur. Parmi tous les catalyseurs étudiés, le solide contenant 5% de RuO2 sur le support d’oxydes binaires CeO2-Al2O3 s'est avéré le plus actif et le plus stable. L’importante réactivité de ce catalyseur est associée d’une part à la bonne dispersion des espèces de ruthénium métallique et d’autre part à la très faible quantité de coke observé sur le catalyseur après 14 jours de vieillissement.

Download or read book Valorisation du m thane en hydrog ne par reformage catalytique written by Abdelmajid Rakib and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ce travail a porté sur la conversion du méthane en hydrogène par les procédés de vaporeformage et reformage à sec, utilisant de nouvelles formulations de catalyseurs afins d'augmenter la sélectivité en produit désiré (H2), de réduire la production du monoxyde de carbone (CO) et défavoriser la formation de coke. Deux familles de catalyseurs, à base de nickel et de ruthénium supportés par la cérine et/ou l'alumine, ont été évaluées dans ces réactions. Il a été montré que les catalyseurs à base de ruthénium supportés par l'alumine présente une bonne activité catalytique et une très bonne résistance au dépôt de coke dans les réactions de reformage du méthane. La cérine joue un rôle déterminant dans les catalyseurs à base de nickel en favorisant la dispersion de la phase active et évitant la formation des agglomérats. Parallèlement, une inhibition de la formation de coke est observée grâce aux propriétés redox du solide. Les travaux ont porté également sur l'amélioration de la formulation des catalyseurs monométalliques, et un catalyseur bimétallique (Ru-Ni/CeO2-Al2O3) actif, sélectif et stable pour la production d'hydrogène à partir du méthane a été mis au point. L'ajout d'un deuxième métal en faible teneur (0,5%) aide à maintenir le Ni sous sa forme actif empêchant la formation de coke sur la surface du catalyseur. Pour les deux réactions étudiées, les excellentes performances obtenues proviennent essentiellement de l'ajustement des paramètres de réaction et les paramètres de préparation des catalyseurs, ce qui ouvre de réelles perspectives d'application industrielle.

Download or read book Catalyst for Utilization of Methane in Selective Catalytic Reduction of NOx Task 2 6 written by and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Oxydation catalytique du m thane sur l oxyde de cobalt written by Paul Spender and published by . This book was released on 1964 with total page 92 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Sustainable Industrial Chemistry written by Fabrizio Cavani and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 621 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years the need for sustainable process design and alternative reaction routes to reduce industry?s impact on the environment has gained vital importance. The book begins with a general overview of new trends in designing industrial chemical processes which are environmentally friendly and economically feasible. Specific examples written by experts from industry cover the possibilities of running industrial chemical processes in a sustainable manner and provide an up-to-date insight into the main concerns, e.g., the use of renewable raw materials, the use of alternative energy sources in chemical processes, the design of intrinsically safe processes, microreactor and integrated reaction/ separation technologies, process intensification, waste reduction, new catalytic routes and/or solvent and process optimization.

Download or read book ICREEC 2019 written by Ahmed Belasri and published by Springer Nature. This book was released on 2020-06-10 with total page 659 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights peer reviewed articles from the 1st International Conference on Renewable Energy and Energy Conversion, ICREEC 2019, held at Oran in Algeria. It presents recent advances, brings together researchers and professionals in the area and presents a platform to exchange ideas and establish opportunities for a sustainable future. Topics covered in this proceedings, but not limited to, are photovoltaic systems, bioenergy, laser and plasma technology, fluid and flow for energy, software for energy and impact of energy on the environment.

Download or read book Chemicals and Fuels from Bio Based Building Blocks written by Fabrizio Cavani and published by John Wiley & Sons. This book was released on 2016-05-16 with total page 761 pages. Available in PDF, EPUB and Kindle. Book excerpt: An up-to-date and two volume overview of recent developments in the field of chemocatalytic and enzymatic processes for the transformation of renewable material into essential chemicals and fuels. Experts from both academia and industry discuss catalytic processes currently under development as well as those already in commercial use for the production of bio-fuels and bio-based commodity chemicals. As such, they cover drop-in commodity chemicals and fuels, as well as bio-based monomers and polymers, such as acrylic acid, glycols, polyesters and polyolefins. In addition, they also describe reactions applied to waste and biomass valorization and integrated biorefining strategies. With its comprehensive coverage of the topic, this is an indispensable reference for chemists working in the field of catalysis, industrial chemistry, sustainable chemistry, and polymer synthesis.

Download or read book Green Carbon Dioxide written by Gabriele Centi and published by John Wiley & Sons. This book was released on 2014-01-17 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: PROMISING NEW APPROACHES TO RECYCLE CARBON DIOXIDE AND REDUCE EMISSIONS With this book as their guide, readers will learn a variety of new approaches and methods to recycle and reuse carbon dioxide (CO2) in order to produce green fuels and chemicals and, at the same time, minimize CO2 emissions. The authors demonstrate how to convert CO2 into a broad range of essential products by using alternative green energy sources, such as solar, wind, and hydro-power as well as sustainable energy sources. Readers will discover that CO2 can be a driving force for the sustainable future of both the chemical industry and the energy and fuels industry. Green Carbon Dioxide features a team of expert authors, offering perspectives on the latest breakthroughs in CO2 recycling from Asia, Europe, and North America. The book begins with an introduction to the production of CO2-based fuels and chemicals. Next, it covers such topics as: Transformation of CO2 to useable products through free-radical-induced reactions Hydrogenation of CO2 to liquid fuels Direct synthesis of organic carbonates from CO2 and alcohols using heterogeneous oxide catalysts Electrocatalytic reduction of CO2 in methanol medium Fuel production from photocatalytic reduction of CO2 with water using TiO2-based nanocomposites Use of CO2 in enhanced oil recovery and carbon capture and sequestration More than 1,000 references enable readers to explore individual topics in greater depth. Green Carbon Dioxide offers engineers, chemists, and managers in the chemical and energy and fuel industries a remarkable new perspective, demonstrating how CO2 can play a significant role in the development of a sustainable Earth.

Download or read book The Fischer Tropsch Synthesis written by Robert Bernard Anderson and published by . This book was released on 1984 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Heterogeneous Catalysis for the Synthetic Chemist written by Robert L. Augustine and published by CRC Press. This book was released on 2020-08-11 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work delineates the effect of different reaction variables on the outcome of heterogeneously catalyzed reactions, and explains how to optimize the product yield of specific compounds. Metal catalysis, simple and complex oxides, zeolites and clays are discussed, both as catalysts and as potential supports for catalytically active metals.