Download or read book Understanding the Global Sources and Sinks of Atmospheric Carbonyl Sulfide in Order to Provide Insights Into Carbon Cycle Processes written by Michael P. Cartwright and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Atmospheric Carbonyl Sulfide Sources from Anthropogenic Activity written by and published by . This book was released on 2015 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS) has recently emerged as an atmospheric tracer of gross primary production. All modeling studies of COS air-monitoring data rely on a climatological anthropogenic inventory that does not reflect present conditions or support interpretation of ice core and firn trends. Here we develop a global anthropogenic inventory for the years 1850 to 2013 based on new emission measurements and material-specific data. By applying methods from a recent regional inventory to global data, we find that the anthropogenic source is similar in magnitude to the plant sink, confounding carbon cycle applications. However, a material-specific approach results in a current anthropogenic source that is only one third of plant uptake and is concentrated in Asia, supporting carbon cycle applications of global air-monitoring data. As a result, changes in the anthropogenic source alone cannot explain the century-scale mixing ratio growth, which suggests that ice and firn data may provide the first global history of gross primary production.
Download or read book Anthropogenic Sources of Carbonyl Sulfide written by and published by . This book was released on 2017 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS or OCS) is emerging as a potentially important tracer of terrestrial biological carbon fluxes. Anthropogenic sources of atmospheric COS are a first order uncertainty for utilizing COS as a tracer of the carbon cycle. As anthropogenic COS is a confounding source of atmospheric COS when interpreting COS observations, incorrect estimates of anthropogenic COS sources can introduce large interpretation bias when attempting to infer carbon cycle fluxes. However, the current gridded estimate of anthropogenic sources of atmospheric COS is largely derived from data over three decades old and therefore is not likely to be representative of current atmospheric conditions. Here I address this critical knowledge gap by providing a new gridded estimate of anthropogenic COS sources derived from the most current industry activity and emissions factor data available and employ a more sophisticated approach for the spatial distribution of sources than presented in previous work. This new data set results in a very different picture of the spatial distribution of anthropogenic sources of COS and in a large upward revision in total global sources than estimated in previous work. The large missing source of atmospheric COS needed to balance the global budget of atmospheric COS has largely been attributed to an unknown ocean source in previous work. However, considering the large upward revision of anthropogenic COS sources estimated here, I present the hypothesis that anthropogenic sources may be a key component of the missing source of atmospheric COS. I present subsequent modeling scenarios to test this hypothesis and show that anthropogenic COS sources can explain observations of atmospheric COS as well as or better than enhanced ocean sources. Therefore, the data set of anthropogenic sources of COS presented here emerges as a key component of reducing interpretation bias when inferring carbon cycle fluxes using COS and for explaining the missing source of atmospheric COS and balancing the global COS budget (which has previously not been considered).
Download or read book Tropical Sources and Sinks of Carbonyl Sulfide Constrained by Atmospheric Observations written by James Robert Stinecipher and published by . This book was released on 2020 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (OCS or COS) is the most common sulfur-containing species in the atmosphere and has the potential to function as a proxy for photosynthetic carbon uptake (gross primary productivity, GPP). In order to expand this technique to regional and global scales, additional questions about poorly constrained aspects of the carbonyl sulfide budget must be resolved. The first section of this work is devoted to developing a new, spatially resolved and temporally varying inventory of carbonyl sulfide emissions from biomass burning. By leveraging long-term, in situ observations of atmospheric carbonyl sulfide, we demonstrate that biomass burning emissions are heavily dependent on biome and are not sufficient to close the overall flux budget. The second section of this dissertation uses this biomass burning inventory in conjunction with a global chemical transport model in order to constrain plant fluxes in the Amazon basin. Using satellite data from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument, I show that downstream observations of carbonyl sulfide in the upper troposphere retain useful information about surface processes and can provide an independent constraint on gross primary production given sufficient convective transport. Finally, I conduct an observing system simulation experiment (OSSE) to investigate how future remote-sensing campaigns could yield more information and better constrain GPP using carbonyl sulfide. In addition to considering sampling density, sampling height and instrument noise in satellite observations, I address potential challenges in future aircraft sampling campaigns.
Download or read book The Ocean Carbon Cycle and Climate written by Mick Follows and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our desire to understand the global carbon cycle and its link to the climate system represents a huge challenge. These overarching questions have driven a great deal of scientific endeavour in recent years: What are the basic oceanic mechanisms which control the oceanic carbon reservoirs and the partitioning of carbon between ocean and atmosphere? How do these mechanisms depend on the state of the climate system and how does the carbon cycle feed back on climate? What is the current rate at which fossil fuel carbon dioxide is absorbed by the oceans and how might this change in the future? To begin to answer these questions we must first understand the distribution of carbon in the ocean, its partitioning between different ocean reservoirs (the "solubility" and "biological" pumps of carbon), the mechanisms controlling these reservoirs, and the relationship of the significant physical and biological processes to the physical environment. The recent surveys from the JGOFS and WOCE (Joint Global Ocean Flux Study and World Ocean Circulation Ex periment) programs have given us a first truly global survey of the physical and biogeochemical properties of the ocean. These new, high quality data provide the opportunity to better quantify the present oceans reservoirs of carbon and the changes due to fossil fuel burning. In addition, diverse process studies and time-series observations have clearly revealed the complexity of interactions between nutrient cycles, ecosystems, the carbon-cycle and the physical envi ronment.
Download or read book Carbon Disulfide Carbonyl Sulfide written by Thomas O. Peyton and published by . This book was released on 1978 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Quantifying Carbon Climate Processes at the Regional Scale Using Atmospheric Carbonyl Sulfide written by and published by . This book was released on 2013 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric carbonyl sulfide (COS) analysis has the potentially transformative capability for partitioning the regional carbon flux into respiration and photosynthesis components. This emerging approach is based on the observation that continental atmospheric CO2 gradients are dominated by net ecosystem fluxes while continental atmospheric COS gradients are dominated by photosynthesis-related plant uptake. Regional flux partitioning represents a critical knowledge gap due to a lack of robust methods for regional-scale flux partitioning and large uncertainties in forecasting carbon-climate feedbacks. Our completed project characterized the relationship between COS and CO2 surface fluxes using a novel measurement and modeling system in a winter wheat field at the U.S. Department of Energy?s Atmospheric and Radiation Measurement program Central Facility (DOE-ARM CF). The scope of this project included canopy flux measurements, soil flux measurements, regional atmospheric modeling, and analysis of COS and CO2 airborne observations at SGP. Three critical discoveries emerged from this investigation: (1) the new measurement system provided the first field evidence of a robust relationship between COS leaf fluxes and GPP; (2) a previously unknown seasonal soil source of COS was observed and characterized; (3) the regional atmospheric analysis of airborne measurements provided the first COS-based constraints on GPP parameterizations used in earth systems models. Dissemination of these results includes three publications [Billesbach et al., In Press; Campbell et al., In Preparation; Seibt et al., In Review], three presentations at the AGU Fall Meeting (2012), and four invited presentations to department seminars. We have leveraged this foundational project to continue our work on understanding carbon cycle processes at large scales through one funded project (DOE Lab Fee, 2012-2015) and one proposal that is under review (DOE/NASA/USDA/NOAA, 2014-2016).
Download or read book Carbonyl Sulfide Exchange in Soils for Better Estimates of Ecosystem Carbon Uptake written by and published by . This book was released on 2016 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Carbonyl Sulfide for Tracing Carbon Fluxes Field Campaign Report written by and published by . This book was released on 2016 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: The April-June 2012 campaign was located at the U.S. Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site Central Facility and had three purposes. One goal was to demonstrate the ability of current instrumentation to correctly measure fluxes of atmospheric carbonyl sulfide (COS). The approach has been describe previously as a critical approach to advancing carbon cycle science1,2, but requires further investigation at the canopy scale to resolve ecosystem processes. Previous canopy-scale efforts were limited to data rates of 1Hz. While 1 Hz measurements may work in a few ecosystems, it is widely accepted that data rates of 10 to 20 Hz are needed to fully capture the exchange of traces gases between the atmosphere and vegetative canopy. A second goal of this campaign was to determine if canopy observations could provide information to help interpret the seasonal double peak in airborne observations at SGP of CO2 and COS mixing ratios. A third goal was to detect potential sources and sinks of COS that must be resolved before using COS as a tracer of gross primary productivity (GPP).
Download or read book The Oceanic Cycle and Global Atmospheric Budget of Carbonyl Sulfide written by and published by . This book was released on 1994 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: A significant portion of stratospheric air chemistry is influenced by the existence of carbonyl sulfide (COS). This ubiquitous sulfur gas represents a major source of sulfur to the stratosphere where it is converted to sulfuric acid aerosol particles. Stratospheric aerosols are climatically important because they scatter incoming solar radiation back to space and are able to increase the catalytic destruction of ozone through gas phase reactions on particle surfaces. COS is primarily formed at the surface of the earth, in both marine and terrestrial environments, and is strongly linked to natural biological processes. However, many gaps in the understanding of the global COS cycle still exist, which has led to a global atmospheric budget that is out of balance by a factor of two or more, and a lack of understanding of how human activity has affected the cycling of this gas. The goal of this study was to focus on COS in the marine environment by investigating production/destruction mechanisms and recalculating the ocean-atmosphere flux.
Download or read book Carbon in the Geobiosphere written by Fred T. Mackenzie and published by Springer Science & Business Media. This book was released on 2006-12-29 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book covers the fundamentals of the biogeochemical behavior of carbon near the Earth’s surface. It is mainly a reference text for Earth and environmental scientists. It presents an overview of the origins and behavior of the carbon cycle and atmospheric carbon dioxide, and the human effects on them. The book can also be used for a one-semester course at an intermediate to advanced level addressing the behavior of the carbon and related cycles.
Download or read book The Phanerozoic Carbon Cycle written by Robert A. Berner and published by Oxford University Press. This book was released on 2004-08-19 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term "carbon cycle" is normally thought to mean those processes that govern the present-day transfer of carbon between life, the atmosphere, and the oceans. This book describes another carbon cycle, one which operates over millions of years and involves the transfer of carbon between rocks and the combination of life, the atmosphere, and the oceans. The weathering of silicate and carbonate rocks and ancient sedimentary organic matter (including recent, large-scale human-induced burning of fossil fuels), the burial of organic matter and carbonate minerals in sediments, and volcanic degassing of carbon dioxide contribute to this cycle. In The Phanerozoic Carbon Cycle, Robert Berner shows how carbon cycle models can be used to calculate levels of atmospheric CO[2 and O[2 over Phanerozoic time, the past 550 million years, and how results compare with independent methods. His analysis has implications for such disparate subjects as the evolution of land plants, the presence of giant ancient insects, the role of tectonics in paleoclimate, and the current debate over global warming and greenhouse gases
Download or read book Changes in the Global Carbon Cycle and the Biosphere written by Jerry S. Olson and published by . This book was released on 1978 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2007 with total page 1044 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Carbon Cycle written by Elizabeth H. Marlies and published by . This book was released on 1993 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Global Carbon Cycle on Geologic Timescales written by John Andrew Higgins and published by . This book was released on 2009 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: We also explore the effects of the progressive oxidation of the ocean and atmosphere on the distribution of carbonate mineral saturation in the water column and sediments. Finally, we try to understand the global magnesium cycle using measurements of magnesium isotopes in deep-sea pore fluids and pelagic carbonates. Because the global magnesium cycle is intimately tied to the global carbon cycle, reconstructions of the global magnesium cycle in seawater provide unique insights into how processes responsible for observed changes in the global carbon cycle over the Cenozoic. Our results indicate a dynamic magnesium cycle in the Cenozoic driven by changes in the rates of continental weathering and/or the formation of dolomite (Ca,Mg)CO 3 .
Download or read book Deep Carbon written by Beth N. Orcutt and published by Cambridge University Press. This book was released on 2019-10-17 with total page 687 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive guide to carbon inside Earth - its quantities, movements, forms, origins, changes over time and impact on planetary processes. This title is also available as Open Access on Cambridge Core.
