Download or read book Understanding Ferroelectricity in Nylon Homopolymers Copolymers and Terpolymers written by Zhongbo Zhang and published by . This book was released on 2018 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the past half century, there has been tremendous growth in exploring the chemistry, physics and material science of poly(vinylidene fluoride) (PVDF)-based ferroelectric polymers. With high breakdown strength, easy processing, and outstanding insulating features, these all-organic electrically active materials are attractive for many advanced electrical (e.g., pyroelectric and piezoelectric) applications. Concurrently, the research about ferroelectricity in polymers also began for energy storage applications through controlling crystalline structure and tuning the corresponding ferroelectric properties, e.g., novel relaxor ferroelectricity with slim double- or single- hysteresis-loop (DHL and SHL) behavior in PVDF copolymers and terpolymers. On the other hand, research activities also focused on searching for other classes of ferroelectric polymers, such as ferroelectric polyamides, cyanopolymers, polyureas, and polyuerathane. However, not much progress has been achieved as considerable as what has been achieved for PVDF-based polymers. In this thesis, we focus on the novel ferroelectric behaviors in polyamide-based polymers, trying to deeply understand the origin of ferroelectricity in aliphatic and aromatic nylons, and generalize the relaxor ferroelectric behavior into this hydrogen-bonding system. It has been commonly considered that only odd-numbered nylons, which prefer polar crystalline structure, are able to show ferroelectric hysteresis loops. In contrast, even-numbered nylons, such as nylon-12 and nylon-6 should not exhibit any ferroelectricity due to their nonpolar crystalline structure. However, in our study, ferroelectric properties are also reported for mesomorphic even-numbered nylons. The structure of the mesophases in quenched samples was considered to contain multiple twists in the chain conformation and dangling/weak hydrogen bonds, which enabled dipolar switching, forming electric-field-induced ferroelectric domains. This study shows that different from ferroelectric PVDF-based polymers, the polar crystalline structure is not the prerequisite for ferroelectricity in nylons. Instead, mesophases with enlarged interchain spacing and disordered hydrogen bonds are the key to ferroelectricity. With the understanding of ferroelectricity in n-nylons, further weakened hydrogen bonding and more twisted chain conformation (e.g., the all-trans conformation of nylon-12 under poling) are expected to facilitate dipolar relaxation and prevent the large ferroelectric domain from growing up. The simplest way to weaken hydrogen bonds is to raise the temperature. Upon increasing temperature to 100 °C, the D-E loops became increasingly narrower, finally leading to slim DHLs for nylon-6 and nylon-12. The observed DHL behavior was attributed to the electric-field-induced reversible transitions between the paraelectric (less twisted chains) and ferroelectric (more twisted chains) states in the mesomorphic crystal of even-numbered nylons. Furthermore, the SHL relaxor ferroelectric property was successfully achieved in a polyamide terpolymer, PA(11-co-12-co-NM11) based on 11-aminoundecanoic acid (AUA), 12-aminododecanoic acid (ADA), and N-methyl-11-aminoundecanoic acid (NM11), utilizing the principle of nanosized ferroelectric domains (or nanodomains). The hydrogen-bonding interaction was intentionally weakened by chemically introducing defects in the crystalline phase of nylon terpolymers. More importantly, the N-CH3 groups were expected to participate in the isomorphic crystals, blocking the formation of hydrogen bonds and inducing chain twisted in the mesophase. Finally, the ferroelectric switching behavior in the amorphous phase of a nearly 100% amorphous nylon, Selar, was investigated. Similarly, ferroelectricity in the glassy phase was also highly dependent upon hydrogen-bonding interaction. When the hydrogen-bonding was weak such as in the quenched film, significant ferroelectric switching took place. Otherwise, the quenched and annealed films did not exhibit any ferroelectric switching. High-voltage broadband dielectric spectroscopy was used to study chain segmental motion in Selar. The result indicated that it was the cooperative short-range segmental motions in the main-chain dipolar glass polymer that primarily contributed to the observed ferroelectricity.

Download or read book Organic Ferroelectric Materials and Applications written by Kamal Asadi and published by Woodhead Publishing. This book was released on 2021-10-27 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Ferroelectric Materials and Applications aims to bring an up-to date account of the field with discussion of recent findings. This book presents an interdisciplinary resource for scientists from both academia and industry on the science and applications of molecular organic piezo- and ferroelectric materials. The book addresses the fundamental science of ferroelectric polymers, molecular crystals, supramolecular networks, and other key and emerging organic materials systems. It touches on important processing and characterization methods and provides an overview of current and emerging applications of organic piezoelectrics and ferroelectrics for electronics, sensors, energy harvesting, and biomedical technologies. Organic Ferroelectric Materials and Applications will be of special interest to those in academia or industry working in materials science, engineering, chemistry, and physics. Provides an overview of key physical properties of the emerging piezoelectric and ferroelectric molecular and supramolecular systems Discusses best practices of processing, patterning, and characterization methods and techniques Addresses current and emerging applications for electronics, materials development, sensors, energy harvesting, and biomedical technologies

Download or read book Electromechanically Active Polymers written by Federico Carpi and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Polymer Synthesis written by and published by Springer Science & Business Media. This book was released on 2004-10-08 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. T. Takata, N. Kihara, Y. Furusho: Polyrotaxanes and Polycatenanes: Recent Advances in Syntheses and Applications of Polymers Comprising of Interlocked Structures.- 2. M. Suginome, Y. Ito: Transition Metal-Mediated Polymerization of Isocyanides.- 3. K. Osakada, D. Takeuchi: Coordination Polymerization of Dienes, Allenes and Methylenecycloalkanes.

Download or read book Film Properties of Plastics and Elastomers written by Laurence W. McKeen and published by William Andrew. This book was released on 2012-04-25 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Preface -- 1. Introduction to Plastics and Polymers -- 2. Chapter 2 - Introduction to the Mechanical, Thermal and Permeation Properties of Plastics and Elastomers -- 3. Production of films -- 4. Markets and Applications for films -- 5. Styrenic Plastics -- 6. Polyesters -- 8. Polyamides (Nylons) -- 9. Polyolefins -- 10. Polyvinyls & Acrylics -- 11. Fluoropolymers -- 12. High Temperature/High Performance Polymers -- 13. Elastomers and rubbers -- 14. Renewable Resource or biodegradable polymers -- Appendices -- Permeation Unit Conversion Factors -- Vapor Transmission rate Conversion factors.

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1990 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Characterisation of Polymers by Thermal Analysis written by W.M. Groenewoud and published by Elsevier. This book was released on 2001-05-21 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermal Analysis (TA) has become an indispensable family of analytical techniques in the polymer research. The increased importance of these techniques can be seen as the result of three more or less parallel developments:• a tempestuous development of TA measuring techniques in combination with a high degree of automation,• the strongly increased understanding of the underlaying theory and,• the increasing knowledge of the relation between the polymers' chemical structure and their physical properties. These areas are still in their developmental stages, especially the third area. The increasing knowledge of the dependence of physical properties on chemical structure just accentuated more and more the need for accurate thermoanalytical measurements, and this knowledge is very important for the first stages of the development of new polymeric systems. Besides, the contribution of TA remains necessary for the technical and commercial development of such a new polymer system. The use of the various TA techniques in these processes is described in this book in nine chapters, while chapter ten illustrates the information obtained about different polymers during special case studies. This book illustrates in this way, applications of a wide variety of TA techniques whilst it is written from a materials characterisation rather than from a TA point of view with attention being paid to the chemical structure/physical properties correlations.

Download or read book Chemistry of Polymeric Metal Chelates written by Gulzhian I. Dzhardimalieva and published by Springer. This book was released on 2018-02-13 with total page 1036 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the chemistry of polymeric metal chelates. The main results and the production and chemical structure of polymers with chelate units as well as the specificity of metal complex binding of different structure are presented here. This book also reveals the transformations which components undergo in the course of chelation. Special attention is paid not only to synthetic but also to natural (including living) systems. The usage of polymeric metal chelates and their development are examined. The related research was performed for chelates with chain structure. This book is useful to researchers being active in synthesis and design of macromolecular metal chelates

Download or read book Dielectric Polymer Materials for High Density Energy Storage written by Zhi-Min Dang and published by William Andrew. This book was released on 2018-06-13 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dielectric Polymer Materials for High-Density Energy Storage begins by introducing the fundamentals and basic theories on the dielectric behavior of material. It then discusses key issues on the design and preparation of dielectric polymer materials with strong energy storage properties, including their characterization, properties and manipulation. The latest methods, techniques and applications are explained in detail regarding this rapidly developing area. The book will support the work of academic researchers and graduate students, as well as engineers and materials scientists working in industrial research and development. In addition, it will be highly valuable to those directly involved in the fabrication of capacitors in industry, and to researchers across the areas of materials science, polymer science, materials chemistry, and nanomaterials. Focuses on how to design and prepare dielectric polymer materials with strong energy storage properties Includes new techniques for adjusting the properties of dielectric polymer materials Presents a thorough review of the state-of-the-art in the field of dielectric polymer materials, providing valuable insights into potential avenues of development

Download or read book Industrial Applications for Intelligent Polymers and Coatings written by Majid Hosseini and published by Springer. This book was released on 2016-05-14 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a comprehensive collaboration on intelligent polymers and coatings for industrial applications by worldwide researchers and specialists. The authors cover the basis and fundamental aspects of intelligent polymers and coatings, challenges, and potential mechanisms and properties. They include recent and emerging industrial applications in medical, smart textile design, oil and gas, electronic, aerospace, and automobile industries as well as other applications including microsystems, sensors, and actuators, among others. The authors discuss the potential for future research in these areas for improvement and growth of marketable applications of intelligent polymers and coatings.

Download or read book Organic and Physical Chemistry of Polymers written by Yves Gnanou and published by John Wiley & Sons. This book was released on 2008-03-03 with total page 629 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic and Physical Chemistry of Polymers provides a thorough introduction to the fundamentals of polymers, including their structure and synthesis as well as their chemical and physical properties. This accessible guide illuminates the increasingly important role of polymers in modern chemistry, beginning with the essentials, then covering thermodynamics, conformation, morphology, and measurements of molar masses; polymerization mechanisms, reaction of polymers, synthesis of block and graft polymers, and complex topologies; and the mechanical properties, rheology, polymer processing, and fabrication of fibers and films.

Download or read book Controlled and Living Polymerizations written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2009-09-28 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Download or read book Polymer based Nanocomposites for Energy and Environmental Applications written by Mohammad Jawaid and published by Woodhead Publishing. This book was released on 2018-01-03 with total page 702 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer-Based Nanocomposites for Energy and Environmental Applications provides a comprehensive and updated review of major innovations in the field of polymer-based nanocomposites for energy and environmental applications. It covers properties and applications, including the synthesis of polymer based nanocomposites from different sources and tactics on the efficacy and major challenges associated with successful scale-up fabrication. The chapters provide cutting-edge, up-to-date research findings on the use of polymer based nanocomposites in energy and environmental applications, while also detailing how to achieve material’s characteristics and significant enhancements in physical, chemical, mechanical and thermal properties. It is an essential reference for future research in polymer based nanocomposites as topics such as sustainable, recyclable and eco-friendly methods for highly innovative and applied materials are current topics of importance. Covers a wide range of research on polymer based nanocomposites Provides updates on the most relevant polymer based nanocomposites and their prodigious potential in the fields of energy and the environment Demonstrates systematic approaches and investigations from the design, synthesis, characterization and applications of polymer based nanocomposites Presents a useful reference and technical guide for university academics and postgraduate students (Masters and Ph.D.)

Download or read book Plastics Technology Handbook Fourth Edition written by Manas Chanda and published by CRC Press. This book was released on 2006-12-19 with total page 890 pages. Available in PDF, EPUB and Kindle. Book excerpt: Because the field of plastics is one of the fastest changing areas today, the need arises to offer relevant, comprehensive material on polymers. An established source of information on modern plastics, the Plastics Technology Handbook continues to provide up-to-date coverage on the properties, processing methods, and applications of polymers. Retaining the easy-to-follow structure of the previous editions, this fourth edition includes new topics of interest that reflect recent developments and lead to better insights into the molecular behavior of polymers. New to the Fourth Edition Advances in supramolecular polymerization, flame retardancy, polymer-based nanomedicines, and drug delivery The new concept of oxo-biodegradable polymers Broadened discussion on plastic foams and foam extrusion processes More information on the processing and applications of industrial polymers, including the emerging field of nanoblends Developments in polymer synthesis and applications, such as polymeric sensors, hydrogels and smart polymers, hyperbranched polymers, shape memory polymers, polymeric optical fibers, scavenger resins, polymer nanocomposites, polymerization-filled composites, and wood-polymer composites A state-of-the-art account of the various available methods for plastics recycling Advances in the use of polymers in packaging, construction, the automotive and aerospace industries, agriculture, electronics and electrical technology, biomedical applications, corrosion prevention, and sports and marine applications Plastics Technology Handbook, Fourth Edition thoroughly covers traditional industrial polymers and their processing methods as well as contemporary polymeric materials, recent trends, and the latest applications.

Download or read book Electrocaloric Materials written by Tatiana Correia and published by Springer Science & Business Media. This book was released on 2013-11-29 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the 1997 Kyoto protocol of reduction of greenhouse gas emissions, the development of novel refrigerators has been a priority within the scientific community. Although magnetocaloric materials are promising candidates, they still need a large magnetic field to induce a giant ΔT as well as powerful and costly magnets. However, in electrocaloric materials (ECMs) a temperature change may be achieved by applying or removing an electric field. Since a giant electrocaloric effect on ferroelectric thin films was reported in Science in 2006, researchers have been inspired to explore such effect in different ferroelectric thin films. This book reviews electrocaloric effects observed in bulk materials as well as recent promising advances in thin films, with special emphasis on the ferroelectric, antiferroelectric and relaxor nature of ECMs. It reports a number of considerations about the future of ECMs as a means of achieving an efficient, ecologically sustainable and low cost refrigerator.

Download or read book Introduction to Fluoropolymers written by Sina Ebnesajjad and published by William Andrew. This book was released on 2013-05-11 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to Fluoropolymers demystifies fluoropolymers for a wide audience of designers, engineers, sales staff and managers. This important group of high-performance polymers has applications across a wide range of market sectors, including automotive, aerospace, medical devices, high performance apparel, oil & gas, renewable energy / solar photovoltaics, electronics / semiconductor, pharmaceuticals, and chemical processing. Dr. Ebnesajjad covers the history and applications of a wide variety of materials, including expanded polytetrafluoroethylene, polyvinyl fluoride, vinylidene fluoride polymers and fluoroelastomers, just to name a few. Properties and applications are illustrated by real-world examples as diverse as waterproof clothing, vascular grafts and coatings for aircraft interiors. The different applications of fluoropolymers show the benefits of a group of materials that are highly water-repellant and flame-retardant, with unrivalled lubrication properties and a high level of biocompatibility. Health and safety and environmental aspects are also covered throughout the book. Demystifies fluoropolymers for a broad audience of engineers in areas such as product design and manufacturing, as well as for non-engineers such as technical sales and management professionals Explains the potential of fluoropolymers for a wide range of applications across sectors such as aerospace, energy and medical devices Ideal for both recently qualified engineers and engineers with limited experience of fluoropolymers

Download or read book Engineered Materials Abstracts written by and published by . This book was released on 1994-02 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: