Download or read book Trinuclear Compounds b written by Springer and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Trinuclear Compounds b written by E. A. Lampe and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Trinuclear Compounds b written by and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Osmium Binuclear and polynuclear compounds sect 3 4a 5 6 Trinuclear compounds cont d written by Gertraud Wieghardt Wieghardt and published by . This book was released on 1994 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trinuclear Compounds a written by E. A. Lampe and published by Springer. This book was released on 1991-10-10 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume begins to close the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging arbon groups. Other trinuclear compounds with nL ligands of higher order (n
Download or read book Gmelin Handbook of Inorganic and Organometallic Chemistry written by Karin Greiner and published by . This book was released on 1997 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Os Organoosmium Compounds written by Kerstin Behrends and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume, "Organoosmium Compounds" 8 6, systematically covers the litera ture through 1992, including many later references. This volume is the first published of Series 8. This series is devoted to compounds containing two or more osmium atoms. The volume forms a unit with" Organoosmium Compounds" 8 5 (in preparation). 80th volumes deal with trinuclear compounds with ligands other than CO which are bonded to Os by one carbon atom ("1L ligands "), regardless of whether the ligand is additionally coordinated to Os by heteroatoms. Generally CO groups are additional ligands. As is usual in the organometallic Gmelin series, the term "trinuclear" means three osmium atoms in the molecule without regard to any additional metals that may be present. The content and the subdivision of both volumes are described on p. 1. Volume 85 will deal with homometallic compounds in which the bonding C atom of the leading 1L ligand is bonded to Os by one non-bridging Os-C bond. The first part of the present volume, 86, is devoted to homometallic compounds in which the bonding C atom of the 1L ligand bridges two or three Os atoms. A second part deals with all heterometallic compounds with 1L ligands other than CO. An Empirical Formula Index and a Ligand Formula Index for both volumes 8 5 and 86 will be included in volume 8 5. For abbreviations and dimensions used throughout this volume, see p. X.
Download or read book Trinuclear Compounds b written by and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Gmelin Handbook of Inorganic and Organometallic Chemistry written by Leopold Gmelin and published by . This book was released on 1997 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trinuclear Compounds b written by Ulrich Krüerke and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Os Organoosmium Compounds written by Karin Greiner and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organoosmium Compounds B Dinuclear and Polynuclear Compounds V written by and published by . This book was released on 1994-01 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trinuclear Compounds b written by and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Boron and Nitrogen Boron and Fluorine written by Eva-Maria Lampe and published by . This book was released on 1991-01-01 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume begins to close the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging arbon groups. Other trinuclear compounds with nL ligands of higher order (n
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by G. Davidson and published by Royal Society of Chemistry. This book was released on 2003-02-09 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Download or read book Trinuclear Compounds b written by Gertraud Wieghardt and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
