Download or read book Trinuclear Compounds b written by and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Trinuclear Compounds b written by Springer and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Boron and Nitrogen Boron and Fluorine written by Eva-Maria Lampe and published by . This book was released on 1991-01-01 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume begins to close the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging arbon groups. Other trinuclear compounds with nL ligands of higher order (n
Download or read book Trinuclear Compounds b written by E. A. Lampe and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Gmelin Handbook of Inorganic and Organometallic Chemistry written by Leopold Gmelin and published by . This book was released on 1997 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trinuclear Compounds a written by and published by Springer. This book was released on 1991-10-10 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume begins to close the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging arbon groups. Other trinuclear compounds with nL ligands of higher order (n
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Trinuclear Compounds b written by and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book The Reactivity of Trinuclear Metal Cluster Compounds with Protic Acid written by David M. Skinner and published by . This book was released on 1986 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trinuclear Compounds a written by E. A. Lampe and published by Springer. This book was released on 1991-10-10 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume begins to close the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging arbon groups. Other trinuclear compounds with nL ligands of higher order (n
Download or read book The Cyanine Dyes and Related Compounds Volume 18 written by Frances M. Hamer and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 830 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.
Download or read book Lanthanide Single Molecule Magnets written by Jinkui Tang and published by Springer. This book was released on 2015-04-24 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book begins by providing basic information on single-molecule magnets (SMMs), covering the magnetism of lanthanide, the characterization and relaxation dynamics of SMMs and advanced means of studying lanthanide SMMs. It then systematically introduces lanthanide SMMs ranging from mononuclear and dinuclear to polynuclear complexes, classifying them and highlighting those SMMs with high barrier and blocking temperatures – an approach that provides some very valuable indicators for the structural features needed to optimize the contribution of an Ising type spin to a molecular magnet. The final chapter presents some of the newest developments in the lanthanide SMM field, such as the design of multifunctional and stimuli-responsive magnetic materials as well as the anchoring and organization of the SMMs on surfaces. In addition, the crystal structure and magnetic data are clearly presented with a wealth of illustrations in each chapter, helping newcomers and experts alike to better grasp ongoing trends and explore new directions. Jinkui Tang is a professor at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Peng Zhang is currently pursuing his PhD at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, with a specific focus on the molecular magnetism of lanthanide compounds under the supervision of Prof. Jinkui Tang.
Download or read book Sb Organoantimony Compounds written by Marlies Mirbach and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatment of pentavalent compounds with three Sb-C bonds began in Part 4 with the RSbX type and is now completed with types RSb(X)Y, RR'SbX, RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX (Section 2.5.1) and the corresponding bi- and trinuclear compounds (Sec 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote different organic groups bonded through carbon to the antimony atom. X and Y represent inorganic or organic groups that are bonded to antimony by an atom other than carbon. R, X, and/or Y can also be chelating ligands. The remaining part of the volume completeLy covers all pentavalent antimony compounds containing two Sb-C bonds (RSbX, RSb(X)Y, RR'SbX, RR'Sb(X)Y, bi- and tetranucLear 2 3 2 2 3 2 compounds, Chapter 2.6, p. 134) and those containing one Sb-C bond (RSbX, RSb(X)Y, 4 3 RSb(X)Y, bi- and trinucLear compounds, Chapter 2.7, p. 237). These compounds form ad 2 2 ducts with Lewis bases (symbol D) and form many ionic compLexes by the addition of saLts such as amine hydrochLorides (symbol MZ). The adducts and ionic compLexes are described immediately after the parent substances. The volume concludes with an Empirical Formula Index (p. 318) and a Ligand Formula Index (p. 357).
Download or read book Osmium Binuclear and polynuclear compounds sect 3 4a 5 6 Trinuclear compounds cont d written by Gertraud Wieghardt Wieghardt and published by . This book was released on 1994 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trinuclear Compounds b written by Gertraud Wieghardt and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Gmelin Handbook of Inorganic and Organometallic Chemistry written by and published by . This book was released on with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Compounds of the Transition Elements Involving Metal Metal Bonds written by D. L. Kepert and published by Elsevier. This book was released on 2016-06-06 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compounds of the Transition Elements Involving Metal-Metal Bonds focuses on compounds of the transition elements involving metal-metal bonds. Emphasis is on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemistry, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.
