Download or read book Treatment of Brines Using Commercial Zeolites and Zeolites Synthesized from Fly Ash Derivative written by Thantaswa Millicent Sonqishe and published by . This book was released on 2008 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objectives of this project was to ameroliate two waste materials, namely Acid Mine Drainage and Fly Ash and recover the solid residues for conversion into an adsorbent to treat brine. The solid residues were then converted into zeolite P through low temperature hydrothermal treatment. The adsorption capacity of the solid residues, zeolite P derived from the solid residues was compared to the commercial zeolite Y and fresh Arnot fly ash. The quality of the resulting water was assessed using different analytical methods before the reaction with adsorbents and after the reaction and a comparison was done based on the removal efficiency of elements Zeolite P from solid residues was successfully synthesized as confirmed by XRD, BET and FTIR. Brine treatment with fly ash, solid residues, zeolite P and commercial zeolite Y adsorbents was done concentration on the following major elements Na, K, Mg, Ca and Si. Zeolite P had higher or similar removal efficiency that the commercial zeolite Y for the following elements K, Ca and Mg. Fly ash is the only adsorbent that managed to reduce the concentration of Na in brine and also had a good removal efficiency of Mg. Si leached out of all the adsorbents which could be ascribed to Si being the major component of these adsorbents which could indicate some dissolution of these adsorbents under the conditions tested. Overall, zeolite P did not completely remove the major elements, especially for Na, but did result in a cleaner waste stream which would improve brine processing.
Download or read book Fly Ash Zeolites written by Bhagwanjee Jha and published by Springer. This book was released on 2016-05-27 with total page 233 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a thorough review of the state-of-knowledge and recent innovations in the synthesis of pure and improved grades of fly ash zeolites (FAZ). Addressing improvements to conventional methods, it also showcases a novel technique for the synthesis of high cation exchangers from fly ash and detailed characterization techniques for the products obtained. In addition, it examines in detail various areas of specific applications of fly ash zeolites. Over the years, several methods such as hydrothermal, fusion prior to hydrothermal, microwave assisted hydrothermal and molten salt techniques for producing FAZ have been developed. However, one-step and two-step reactions between the fly ash and alkali usually generate alkaline wastes that may cause environmental contamination. In addition, the separation of FAZ from the partially activated fly ash (the impurities) remains a major concern for researchers and industrialists alike. /divIn view of these challenges, this book presents a novel technique for three-step activation (TSA), which focuses on recycling the fly ash-NaOH-water reaction by-products until zeolitic residue is formed. The FAZ (the final residue after third step reactions) synthesized in this manner exhibits exceptionally high cation exchange capacity, specific surface area and pore area. This book offers a comprehensive compendium of reading material on fly ash and its recycled product, the zeolites. Students at both undergraduate and graduate levels, researchers, and practicing engineers will all find this book to be a valuable guide in their respective fields.
Download or read book Solid stabilisation of Industrial Brines by Zeolite and Sodalite Formation written by and published by . This book was released on 2000 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: The recovery of water from industrial effluents by reverse osmosis and other methods is important in arid countries such as South Africa. However, these processes generate brines that usually contain high concentrations of soluble ions (Na, K, Cl, SO4). The brines require either further treatment or must be stored in expensive lined dams to minimise their environmental impact. Once such treatment option for brines is their stabilisation within mineral phases that immobilise the soluble components.^L^LThe zeolite and sodalite groups of minerals show potential to stabilise these components. Both consist of an alumino-silicate framework structure. While zeolites have an open structure of cages and channels that can accommodate cations, the cage structure of sodalites is more compact and can contain both cations and anions.^L^LThe synthesis of zeolites under hydrothermal conditions from local fly ashes has been studied at various temperatures, reaction times and alkalinity. The solids formed have been characterised by X-ray diffraction When caustic soda was used for the alkaline activation of the fly ash, various zeolitic phases such as zeolite P, zeolite 4A, and analcime formed as major phases, depending on the reaction conditions. The possibility of using less expensive reagents than caustic soda, i.e. lime, was also investigated, but no zeolitic phases were formed in these instances. The availability of Ca, Al and Si caused the formation of insoluble calcium aluminium silicates and prevented zeolite formation.^L^LThe addition of solid NaCl to the zeolites and heating the mixture to 1000 degrees Celsius resulted in the formation of sodalite (Na4Al3Si3O12Cl). When zeolite samples were calcined with a brine that contained Na, K, So4 and Cl ions, the formation of nosean (Na8Al6Si6O24SO4), a member of the sodalite group of minerals, as the main mineral phase was observed. Leaching tests conducted on these solids indicated up to 99% immobilisation of Na, K and Cl, and up to 70% immobilisation of SO4. The reasons for the lower SO4 immobilisation may lie in the difference in size between Cl and SO4 and should be further investigated.^L^LThe results of this study indicate that sodalites are a suitable reservoir mineral to immobilise the soluble ions Na, K, Cl and, to certain degree, also SO4, that are present in the brine. The potential industrial applications of this work are also discussed briefly.
Download or read book Production and Utilisation of Synthetic Zeolites from Fly Ash written by Herry Prijatama and published by . This book was released on 2000 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Official Gazette of the United States Patent and Trademark Office written by and published by . This book was released on 2003 with total page 914 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Natural Microporous Materials in Environmental Technology written by P. Misaelides and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop on the Application of Natural Microporous Materials for Environmental Technology, Smolenice Castle, Slovakia, 26-30 October 1998
Download or read book Handbook of Alkali Activated Cements Mortars and Concretes written by F. Pacheco-Torgal and published by Elsevier. This book was released on 2014-11-20 with total page 855 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an updated state-of-the-art review on new developments in alkali-activation. The main binder of concrete, Portland cement, represents almost 80% of the total CO2 emissions of concrete which are about 6 to 7% of the Planet's total CO2 emissions. This is particularly serious in the current context of climate change and it could get even worse because the demand for Portland cement is expected to increase by almost 200% by 2050 from 2010 levels, reaching 6000 million tons/year. Alkali-activated binders represent an alternative to Portland cement having higher durability and a lower CO2 footprint. - Reviews the chemistry, mix design, manufacture and properties of alkali-activated cement-based concrete binders - Considers performance in adverse environmental conditions. - Offers equal emphasis on the science behind the technology and its use in civil engineering.
Download or read book Advances in Carbon Capture written by Mohammad Reza Rahimpour and published by Woodhead Publishing. This book was released on 2020-08-04 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Carbon Capture reviews major implementations of CO2 capture, including absorption, adsorption, permeation and biological techniques. For each approach, key benefits and drawbacks of separation methods and technologies, perspectives on CO2 reuse and conversion, and pathways for future CO2 capture research are explored in depth. The work presents a comprehensive comparison of capture technologies. In addition, the alternatives for CO2 separation from various feeds are investigated based on process economics, flexibility, industrial aspects, purification level and environmental viewpoints. - Explores key CO2 separation and compare technologies in terms of provable advantages and limitations - Analyzes all critical CO2 capture methods in tandem with related technologies - Introduces a panorama of various applications of CO2 capture
Download or read book Green Chemical Engineering written by S. Suresh and published by CRC Press. This book was released on 2014-12-18 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores a balance between energy and material, applied to chemical reactors with catalysis, to achieve a given purpose. It includes the fundamentals of chemical reaction engineering and explains reactor design fundamentals. The book spans the full range-from the fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies-to their equivalent large-scale industrial production processes. It also includes significant developments, with recent research case studies and literature.
Download or read book Natural Zeolites written by G. Gottardi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites form a family of minerals which have been known since the 18th century, but they remained a curiosity for scientists and collectors until 60 years ago, when their unique physicochemical properties attracted the attention of many researchers. In the past 30 years there has been an ex traordinary development in zeolite science; six International Conferences on Zeolites have been held every 3 years since 1967, and a large number of interesting contributions have been published in their proceedings. Many books, written either by individual authors or by several authors under a leading editor, have been published on these interesting silicate phases, but none has been devoted specifically to natural zeolites, even though this theme may be of interest not only to earth scientists, but also to chemists, as the in formation obtained from natural samples completes and in tegrates the characterization of many zeolites. We are trying to fill this gap on the basis of 20 years of research on natural zeolites, which we performed at the University of Modena together with many friends and colleagues. If it is in general difficult to write a scientific book with out upsetting somebody, this is particularly true for a book on natural crystals, because mineralogy is an interdisciplin ary science which covers some fields of physics, chemistry, it is almost impossible to meet every petrology, geology, and requirement.
Download or read book Waste Production and Utilization in the Metal Extraction Industry written by Sehliselo Ndlovu and published by CRC Press. This book was released on 2017-06-27 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: Increasingly stringent environmental regulations and industry adoption of waste minimization guidelines have thus, stimulated the need for the development of recycling and reuse options for metal related waste. This book, therefore, gives an overview of the waste generation, recycle and reuse along the mining, beneficiation, extraction, manufacturing and post-consumer value chain. This book reviews current status and future trends in the recycling and reuse of mineral and metal waste and also details the policy and legislation regarding the waste management, health and environmental impacts in the mining, beneficiation, metal extraction and manufacturing processes. This book is a useful reference for engineers and researchers in industry, policymakers and legislators in governance, and academics on the current status and future trends in the recycling and reuse of mineral and metal waste. Some of the key features of the book are as follows: Holistic approach to waste generation, recycling and reuse along the minerals and metals extraction. Detailed overview of metallurgical waste generation. Practical examples with complete flow sheets, techniques and interventions on waste management. Integrates the technical issues related to efficient resources utilization with the policy and regulatory framework. Novel approach to addressing future commodity shortages.
Download or read book Introduction to Zeolite Molecular Sieves written by Jiri Cejka and published by Elsevier. This book was released on 2007-10-02 with total page 1095 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to Zeolite Molecular Sieves, 3rd Edition presents a collection of the most important results and ideas in the field of molecular sieve chemistry and technology, the most important experimental techniques related to the research activities in molecular sieves, and identifies new areas of molecular sieve chemistry. Chapters start at a reasonably simple entry level, but also covers the present state-of-the-art in the field. Topics covered include structure, synthesis, characterization, ion exchange, adsorption, diffusion, separations, and natural zeolites.* 6 years since the last edtion this book brings together the rapid development within the field of molecular sieve chemistry and applications * Accessible to newcomers to the field, also containing valuable information for experienced researchers * 27 chapters written by renowned scientists in their field, including updates on some 2nd edition chapters
Download or read book Handbook of Hydrothermal Technology written by K. Byrappa and published by William Andrew. This book was released on 2012-12-31 with total page 796 pages. Available in PDF, EPUB and Kindle. Book excerpt: Quartz, zeolites, gemstones, perovskite type oxides, ferrite, carbon allotropes, complex coordinated compounds and many more -- all products now being produced using hydrothermal technology. Handbook of Hydrothermal Technology brings together the latest techniques in this rapidly advancing field in one exceptionally useful, long-needed volume.The handbook provides a single source for understanding how aqueous solvents or mineralizers work under temperature and pressure to dissolve and recrystallize normally insoluble materials, and decompose or recycle any waste material. The result, as the authors show in the book, is technologically the most efficient method in crystal growth, materials processing, and waste treatment. The book gives scientists and technologists an overview of the entire subject including: À Evolution of the technology from geology to widespread industrial use. À Descriptions of equipment used in the process and how it works.À Problems involved with the growth of crystals, processing of technological materials, environmental and safety issues.À Analysis of the direction of today's technology. In addition, readers get a close look at the hydrothermal synthesis of zeolites, fluorides, sulfides, tungstates, and molybdates, as well as native elements and simple oxides. Delving into the commercial production of various types, the authors clarify the effects of temperature, pressure, solvents, and various other chemical components on the hydrothermal processes. - Gives an overview of the evolution of Hydrothermal Technology from geology to widespread industrial use - Describes the equipment used in the process and how it works - Discusses problems involved with the growth of crystals, processing of technological materials, and environmental and safety issues
Download or read book Zeolites Science and Technology written by Fernando Ramôa Ribeiro and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites have been the focus of intensive activity and growth in applications over the past 25 years in ion exchange, in adsorp tion and in catalytic process technology. Beginning with the syn thetic zeolites A,X and Y, continuing into the emerging ZSM series, and including selected natural zeolites, applications span the range from large-scale purification and separation to such major petroleum and petrochemical processes as catalytic cracking and aromatics alkylation. The future promises several new areas of signiciant use as our energy resource base is expanded. As a result, a NATO Advanced Study Institute on Zeolites was held in Alcabideche, Portugal, May 1-12, 1983. Its purpose was to summarize the state-of-the-art in zeolite science and technology, with particular emphasis on recent developments. This summary is intended to complement presentations of the latest research results at the 1983 International Zeolites Association meeting in .Reno, Nevada - USA. Both the fundamentals concepts and industrial applications are addressed in the lectures of the Institute. Individual chapters cover historical development, structure, crystallography and synthesis techniques. Basic principles of adsorption, diffusion, ion exchange and acidity are reviewed. A section on catalysis addresses shape selectivity, transition metals, bifunctional catalysis and "methanol to-gasoline". Included in the section on industrial applications are chapters on reactor and adsorber design, catalytic cracking, xylene and n -paraffins isomerization, as well as ion exchange and adsorption.
Download or read book Alkali Activated Materials written by John L. Provis and published by Springer Science & Business Media. This book was released on 2013-11-19 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a State of the Art Report resulting from the work of RILEM Technical Committee 224-AAM in the period 2007-2013. The Report summarises research to date in the area of alkali-activated binders and concretes, with a particular focus on the following areas: binder design and characterisation, durability testing, commercialisation, standardisation, and providing a historical context for this rapidly-growing research field.
Download or read book Verified Synthesis of Zeolitic Materials written by H. Robson and published by Gulf Professional Publishing. This book was released on 2001-06-26 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolite synthesis is an active field of research. As long as this continues, new phases will be discovered and new techniques for preparing existing phases will appear. This edition of Verified Synthesis of Zeolitic Materials contains all the recipes from the first edition plus 24 new recipes. Five new introductory articles have been included plus those from the first edition, some of which have been substantially revised. The XRD patterns have been recorded using different instrument settings from those in the first edition and are intended to conform to typical X-ray diffraction practice. In most cases, only the XRD pattern for the productas synthesised is printed here. The exceptions are those phases which show marked changes in the XRD pattern upon calcination.
Download or read book Molecular Sieves written by Rosemarie Szostak and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 473 pages. Available in PDF, EPUB and Kindle. Book excerpt: From areport by a Lieutenant Colonel W.A. Ross (Chern. News, Nov.15, 1878, p. 236). Progress did not accelerate during the next 50 years. McBain, in his clas sic 1932 book, The Sorption oi Gases by So lids, devoted a chapter to sorp tion by chabasite, other zeolites, and permeable crystals. McBain remarked that "great interest attaches to the finding of Weigel and Steinhoff [0. Weigel and E. Steinhoff, Z. Kris!., 61, 125 (1925{raquo}) that chabasite rapidly sorbs the vapors of water, methyl and ethyl alcohol and formie acid, whereas acetone, ether and benzene are largely excluded. The significance of their results was pointed out by McBain [J.W. McBain, Colloid. Syrnp. Mon., 20, 1 (1926{raquo}) and recognized by alliater writers. It is evident that the partially dehydrated chabasite forms a nearly perfect molecular sieve or a semipermeable membrane of extremely regular structure ... ". While the significance of the above observation may have been recog nized, it had little impact. Thus, an eminent pioneer in the synthesis and characterization af zeolites, Professor R.M. Barrer, spent nearly two dec ades (following his Ph. D. studies in the 1930s) developing a firm foundation for the rapid growth in scientific understanding and industrial applications of zeolites which has taken place during the last 30 years.
