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Book Treatability Study of in Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site  New Jersey

Download or read book Treatability Study of in Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site New Jersey written by and published by . This book was released on 2006 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Treatability Study of in Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site  New Jersey

Download or read book Treatability Study of in Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site New Jersey written by Vincent R. Vermeul and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Biological Remediation of Explosive Residues

Download or read book Biological Remediation of Explosive Residues written by Shree Nath Singh and published by Springer Science & Business Media. This book was released on 2013-08-04 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microbial degradation, Phytoremediation, Remediation, Explosive residues, Biotransformation, Mineralization, Degradative Enzymes, Degradation Pathways, Energetics, Soil contamination, Water contamination.

Book In Situ Treatment of Soil and Groundwater Contaminated with Chromium

Download or read book In Situ Treatment of Soil and Groundwater Contaminated with Chromium written by National Risk Management Research Laboratory (U.S.) and published by . This book was released on 2000 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book An In situ Permeable Reactive Barrier for the Treatment of Hexavalent Chromium and Trichloroethylene in Ground Water  Performance monitoring

Download or read book An In situ Permeable Reactive Barrier for the Treatment of Hexavalent Chromium and Trichloroethylene in Ground Water Performance monitoring written by and published by . This book was released on 1999 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Treatability Test Report for the Removal of Chromium from Groundwater at 100 D Area Using Electrocoagulation

Download or read book Treatability Test Report for the Removal of Chromium from Groundwater at 100 D Area Using Electrocoagulation written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. Department of Energy (DOE) has committed to accelerate cleanup of contaminated groundwater along the Columbia River. The current treatment approach was driven by a series of Interim Action Records of Decision (IAROD) issued in the mid-1990s. Part of the approach for acceleration involves increasing the rate of groundwater extraction for the chromium plume north of the 100-D Reactor and injecting the treated water in strategic locations to hydraulically direct contaminated groundwater toward the extraction wells. The current treatment system uses ion exchange for Cr(VI) removal, with off-site regeneration of the ion exchange resins. Higher flow rates will increase the cost and frequency of ion exchange resin regeneration; therefore, alternative technologies are being considered for treatment at high flow rates. One of these technologies, electrocoagulation (EC), was evaluated through a pilot-scale treatability test. The primary purpose of the treatability study was to determine the effectiveness of Cr(VI) removal and the robustness/implementability of an EC system. Secondary purposes of the study were to gather information about derivative wastes and to obtain data applicable to scaling the process from the treatability scale to full-scale. The treatability study work plan identified a performance objective and four operational objectives. The performance objective for the treatability study was to determine the efficiency (effectiveness) of hexavalent chromium removal from the groundwater, with a desired concentration of ≤ 20 micrograms per liter ([mu]g/L) Cr(VI) in the effluent prior to re-injection. Influent and effluent total chromium and hexavalent chromium data were collected using a field test kit for multiple samples per week, and from off-site laboratory analysis of samples collected approximately monthly. These data met all data quality requirements. Two of three effluent chromium samples analyzed in the off-site (that is, fixed) laboratory met the performance objective during the continuous operational testing. Effluent hexavalent chromium analyzed by the field laboratory met the performance goal in over 90 percent of the samples. All effluent hexavalent chromium samples during the batch testing with high influent hexavalent chromium concentrations (≈2000 [mu]g/L) met the performance objective. Although the EC system was able to meet the performance goal, it must be noted that it was not uncommon for the system to be operated in recycle mode to achieve the performance goal. The EC unit was sometimes, but not always, capable of a single pass treatment efficiency high enough to meet the performance goal, and recycling water for multiple treatment passes was effective. An operational objective was to determine the volume and composition of the waste streams to enable proper waste designation. The toxicity characteristic leaching procedure (TCLP) concentrations, pH, and free liquids were determined for solid material from the EC electrodes (mechanically removed scale), the filter press, and the tank bottoms for the effluent and waste collector tanks. These data met all data quality requirements. All solid-phase secondary waste streams were found to be below the TCLP limits for the toxicity characteristic, and a pH value within the limits for the corrosivity characteristic. Out of three samples, two (one of scale from the EC unit and one from filter press solids) failed the free liquid (paint filter) test, which is one of the acceptability criteria for Hanford's Environmental Restoration Disposal Facility (ERDF). The solid-phase waste generation rate was about 0.65-gallon of solid waste per 100 gallons of water treated. It is concluded that the solid-phase secondary waste generated from this technology under the conditions at the test site will meet the toxicity and corrosivity criteria for disposal. It is also concluded that with engineering and/or operational improvements, a solid-phase secondary waste could be produced that would meet the free liquid disposal requirements. The second operational objective was to assess the operational reliability and safety of the system. For the continuous operations testing period from July 23 to September 12,2007, the system was not able to operate unattended. An extensive period of startup and adjustment preceded continuous operations, but was unsuccessful in providing a suitable and robust operating condition. Primary operational reliability problems were related to the sensitivity of the solid separation process to operational conditions such that a robust operating procedure (for example, chemical dosage) was not identified during the treatability test. Poor solids separation and high effluent iron concentrations also led to operational difficulties associated with injection well fouling.

Book Field Applications of in Situ Remediation Technologies

Download or read book Field Applications of in Situ Remediation Technologies written by and published by DIANE Publishing. This book was released on 1998 with total page 41 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Remediation system evaluation Brewster Well Field superfund site  Brewster  New York

Download or read book Remediation system evaluation Brewster Well Field superfund site Brewster New York written by and published by DIANE Publishing. This book was released on with total page 46 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Field Applications of In Situ Remediation Technologies

Download or read book Field Applications of In Situ Remediation Technologies written by and published by . This book was released on 1998 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approximately 85% of the hazardous waste sites in the United States have contaminated ground water. The conventional approach for remediating contaminated ground water has been to extract the contaminated water, treat it above ground, and reinject or discharge the clean water ("pump- and-treat"). The recovered contaminants must be disposed of separately. It is becoming increasingly apparent that pump-and-treat technologies require considerable investment over extended period of time, and often times do not actually clean up the source of the contamination. Current policies and law stress "permanent" remedies over containment. Consequently, there is considerable interest and effort being expended on alternative, innovative treatment technologies for contaminated ground water. This report is one in a series that document recent pilot demonstrations and full-scale applications that either treat soil and ground water in place or increase the solubility and mobility of contaminants to improve their removal by other remediation technologies. It is hoped that this information will allow more regular consideration of new, less costly, and more effective technologies to address the problems associated with hazardous waste sites and petroleum.

Book In Situ Treatment of Soil and Groundwater Contaminated with Chromium

Download or read book In Situ Treatment of Soil and Groundwater Contaminated with Chromium written by and published by . This book was released on 2002-07-01 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contamination of soil & groundwater by chromium is a significant problem in the U.S. The poor performance of pump-&-treat systems in the mid-1980s provided the driving force for research of subsurface processes in order to develop more efficient groundwater remediation strategies & techniques. As a result, new information & treatment approaches have been developed for chromium-contaminated soil & groundwater treatment. This document brings together the most current information pertaining to the science of chromium contamination & the treatment & control of sites with groundwater &/or soil contaminated with it. List of acronyms, abbreviations, & symbols. Charts & tables.

Book In Situ Treatment Technology

Download or read book In Situ Treatment Technology written by Evan K. Nyer and published by CRC Press. This book was released on 2000-12-28 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Completely revised and updated, the second edition of the bestselling In Situ Treatment Technology adds three new chapters to provide the reader with an even more comprehensive reference source on remediation. This authoritative book goes beyond discussion of individual in situ technologies by providing an understanding of the geologic foun

Book Laboratory and Field Studies Directed Toward Accelerating Remediation at a Major US Superfund Site in New Jersey

Download or read book Laboratory and Field Studies Directed Toward Accelerating Remediation at a Major US Superfund Site in New Jersey written by Karen Wovkulich and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical amendments that either compete with As for sorption sites or dissolve Fe and Al (hydr)oxides can increase As mobility and potentially improve P&T remediation efficiency. Simple extrapolations from bench scale column experiments based on pore volumes suggest that treatment with 10 mM oxalic acid could lower the time necessary for clean up at the Vineland site from 600 years (with current techniques involving just groundwater) to potentially on the order of 4 years. Small scale (

Book Laboratory Evaluation of the in Situ Chemical Treatment Approach to Soil and Groundwater Remediation

Download or read book Laboratory Evaluation of the in Situ Chemical Treatment Approach to Soil and Groundwater Remediation written by and published by . This book was released on 1993 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: Results of initial proof of principle laboratory testing activities successfully demonstrated the viability of the in situ chemical treatment approach for remediation of soil and groundwater contaminated by hexavalent chromium. Testing activities currently in progress further indicate that soils contaminated with hexavalent chromium and uranium at concentrations of several hundred parts per million can be successfully treated with 100 ppM hydrogen sulfide gas mixtures. Greater than 90% immobilization of hexavalent chromium and 50% immobilization of uranium have been achieved in these tests after a treatment period of one day. Activities associated with further development and implementation of the in situ chemical treatment approach include conducting additional bench scale tests with contaminated geomedia, and undertaking scale-up laboratory tests and a field demonstration. This report discusses the testing and further development of this process.

Book SUMMARY CONCLUSIONS FOR THE PILOT IN SITU CHROMIUM REDUCTION TEST AT RIVERBANK ARMY AMMUNITIONS PLANT

Download or read book SUMMARY CONCLUSIONS FOR THE PILOT IN SITU CHROMIUM REDUCTION TEST AT RIVERBANK ARMY AMMUNITIONS PLANT written by and published by . This book was released on 2007 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: A treatability study was conducted at Riverbank Army Ammunition Plant's (RBAAP) Site 17, to evaluate the effectiveness of a permeable reactive barrier (PRB) for the treatment of hexavalent chromium (Cr{sup 6+}). The chromium contamination at Site 17 is hydrologically isolated and unsuitable for standard extraction and treatment (pump and treat). The majority of the chromium contamination at Site 17 is trapped within the fine grain sediments of a clay/slit zone (45 to 63). The PRB was established above and adjacent to the contaminated zone at Site 17 to reduce the hexavalent chromium as it leaches out of the contaminated clay/silt zone separating the A zone from the A zone. Site 17 and the monitoring network are described in the In-Situ Chromium Reduction Treatability Study Work Plan (CH2MHILL, January 2004). The PRB was created by reducing naturally occurring Fe{sup 3+} to Fe{sup 2+} with the injection of a buffered sodium dithionite solution into subsurface chromium source area. The Cr{sup 6+} leaching out of the contaminated clay/silt zone and migrating through the PRB is reduced by Fe{sup 2+} to Cr{sup 3+} and immobilized (Amonette, et al., 1994). The sodium dithionite will also reduce accessible Cr{sup 6+}, however the long-term reductant is the Fe{sup 2+}. Bench scale tests (Appendix A) were conducted to assess the quantity and availability of the naturally occurring iron at Site 17, the ability of the sodium dithionite to reduce the hexavalent chromium and Fe within the sediments, and the by-products produced during the treatment. Appendix A, provides a detailed description of the laboratory treatability tests, and provides background information on the technologies considered as possible treatment options for Site 17. Following the sodium dithionite treatment, groundwater/treatment solution was extracted to remove treatment by-products (sulfate, manganese, and iron). The following sections briefly discuss the current treatment status, future recommendations for Site 17, and future recommendations for the application of sodium dithionite at additional sites. At the completion of the treatability test, none of the wells at Site 17 had detectable hexavalent chromium, but the sulfate, iron, and manganese concentrations were detected and exceeded the CA secondary drinking water standards. The extraction done after the injection of the sodium dithionite solution to remove the sulfate, manganese, and iron has to a large extent negated the effectiveness of the iron reduction. Riverbank's local groundwater is naturally high in dissolved oxygen (concentration range at Site 17: 1.8 to 6.0 mg/l) and moving this type of groundwater through the reduced zone caused oxidation of the Fe2+ within the treatment zone, followed by a new release of hexavalent chromium detected in one of the treatment wells. Additional extraction at Site 17 will continue to degrade the PRB, threatening to release additional Cr{sup 6+} into the groundwater. Sulfate and manganese only exceed the CA secondary drinking water standards in the area immediately surrounding the PRB. It is unlikely that these contaminants will threaten any water supply wells in the area. The chromium concentrations are increasing in IW-17. The current concentration is still only a third of the original concentration. It might be worth investigating some of the new zero valent iron treatments, such as nanoscale zero-valent iron (NZVI) to replace the in-situ naturally occurring iron, which may no longer be available for reduction. The NZVI has been successfully tested at NASA in Florida (O'Hara, 2006), and demonstrated no release of metals from the natural sediments. This might also be a viable option for other sites at RBAAP.