Download or read book Transition Metals in Homogeneous Catalysis written by Gerhard N. Schrauzer and published by . This book was released on 1971 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Homogeneous Catalysis written by Sumit Bhaduri and published by John Wiley & Sons. This book was released on 2014-09-08 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts
Download or read book Homogeneous Transition metal Catalysis written by Christopher Masters and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in- writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.
Download or read book Homogeneous Catalysis written by George W. Parshall and published by Wiley-Interscience. This book was released on 1992-08-07 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: The broadening technical advances in the production of pharmaceuticals, flavors, and fragrances have more than doubled the industrial applications of soluble transition metal catalysts. Indeed, transition metal catalysts have become an ascendant feature of a heightened academic interest in organometallic chemistry. This Second Edition of the landmark text offers a clear, systematic look at the state-of-the-science of homogeneous catalytic reactions. Focusing on specific processes, rather than principles of coordination or organometallic chemistry, this updated edition is an A-to-Z compilation of the homogeneous catalytic reactions commonly used in industry or that have broad application in the organic synthesis laboratory. Documenting examples of homogeneous catalytic reactions used in current commercial processes, this newest edition features Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol processes for dimerizing propylene as well as Du Pont's hydrocyanation process. Detailed coverage also includes isomerization of simple olefins, mechanism of olefin hydrogenation, oligomerization of olefins, chain transfer catalysis, reactions of carbon monoxide, specialty chemicals, reactions of acetylenes, esterification, polycondensation, and related processes. Featuring the latest findings in its existing coverage on pharmaceuticals, agricultural chemicals, flavors, fragrances, and electronic chemicals, this Second Edition clearly details the science's growing influence and practicality in industry and the lab. Organic and inorganic chemists, instructors, and students will find Homogeneous Catalysis, Second Edition a clear, up-to-date compendium of the catalytic reactionssharpening chemistry's cutting edge.
Download or read book Homogeneous Catalysis written by George William Parshall and published by John Wiley & Sons. This book was released on 1980 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.
Download or read book Industrial Applications of Homogeneous Catalysis written by A. Mortreux and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are now widely used in both laboratory and industrial-scale chemistry. Indeed, it is hard to find any complex synthesis or industrial process that does not, at some stage, utilize a catalytic reaction. The development of homogeneous transition metal catalysts on the laboratory scale has demonstrated that these systems can be far superior to the equivalent heterogeneous systems, at least in terms of selectivity. is an increasing interest in this field of research from both an Thus, there academic and industrial point of view. In connection with the rapid developments in this area, four universities from the E.E.C (Aachen, FRG; Liege, Belgium; Milan, Italy; and Lille, France) have collaborated to organise a series of seminars for high-level students and researchers. These meetings have been sponsored by the Commission of the E.E.C and state organizations. The most recent of these meetings was held in Lille in September 1985 and this book contains updated and expanded presentations of most of the lectures given there. These lectures are concerned with the field of homogeneous transition metal catalysis and its application to the synthesis of organic intermediates and fine chemicals from an academic and industrial viewpoint. The continuing petroleum crisis which began in the early 1970s has given rise to the need to develop new feedstocks for the chemical industry.
Download or read book Homogeneous Transition metal Catalysis written by Christopher. Masters and published by Springer. This book was released on 1980-12-15 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in· writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the .present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.
Download or read book Homogeneous Catalysis written by Piet W.N.M. van Leeuwen and published by Springer Science & Business Media. This book was released on 2006-08-02 with total page 413 pages. Available in PDF, EPUB and Kindle. Book excerpt: No available as softcover No other book available that gives insight into so many reactions of importance, while the field of homogeneous catalysis is becoming more and more important to organic chemists, industrial chemists, and academia. Gives real insight in the many new and old reactions of importance, based on the author's extensive experience in both teaching and industrial practice. Provide background to chemists trained in a different discipline and graduate and masters students who take catalysis as a main or secondary topic.
Download or read book Application of Transition Metal Catalysts in Organic Synthesis written by L. Brandsma and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.
Download or read book Homogeneous Catalysis with Metal Phosphine Complexes written by Louis M. Pignolet and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.
Download or read book Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2016-06-06 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the π-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.
Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Download or read book Homogeneous Catalysis with Metal Complexes written by Gheorghe Duca and published by Springer Science & Business Media. This book was released on 2012-06-15 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.
Download or read book Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2013-10-22 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis deals with the chemistry of organo-transition metal complexes and their uses as homogeneous catalysts and as intermediates in organic synthesis. The compounds are classified mainly from the number of carbon atoms that are actually bonded to the metal and to each other. This volume is comprised of eight chapters and begins with a discussion on alkyls, aryls, acetylides, fluorocarbon complexes, and carbides, along with olefin, allene, and acetylene complexes. The reader is then introduced to π-allylic and related complexes such as fluoroallyl complexes; complexes with conjugated diolefins including fluorodiolefins but excluding cyclobutadienes; cyclopentadienyl-metal, pentadienyl-metal, and related complexes; and arene complexes, related complexes with conjugated trienes, and thiophene complexes such as benzenoid-metal or arene-metal complexes, cyclopheptatriene complexes, and complexes with other six electron donors. Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes. This book will be a valuable source of information for inorganic chemists.
Download or read book Computational Modeling of Homogeneous Catalysis written by Feliu Maseras and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent results on a wide array of catalytic processes are collected in this volume. The book illustrates the importance of computational modelling in homogeneous catalysis by providing up-to-date reviews of its application to a variety of reactions of industrial interest.
Download or read book Homogeneous Catalysis written by George William Parshall and published by John Wiley & Sons. This book was released on 1980 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.
Download or read book Non Noble Metal Catalysis written by Robertus J. M. Klein Gebbink and published by John Wiley & Sons. This book was released on 2019-04-29 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt: An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals?enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes. Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns. Providing essential conceptual and practical exploration, this valuable resource: -Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications -Highlights the multiple advantages of using non-noble metals in homogenous catalysis -Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry -Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.
