Download or read book Transition Metal Complexes of Novel Ligands Derived from the Cis Cis 1 3 5 triaminocyclohexane TACH Framework written by Gyungse Park and published by . This book was released on 2000 with total page 1006 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Divalent Transition metal Complexes of Novel Hexadentate Ligands Based on Cis Cis 1 3 5 triaminocyclohexane written by Neng Ye and published by . This book was released on 2001 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthetic Approaches to Cis Cis 1 3 5 triaminocyclohexane tach and Tach based Ligands written by Allison Lisa Lindell and published by . This book was released on 2006 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2001 with total page 830 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal Complexes of Neutral Eta1 Carbon Ligands written by Remi Chauvin and published by Springer Science & Business Media. This book was released on 2010-01-12 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.

Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 2006 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Coordination Chemistry of Cis Trans 1 3 5 Triaminocyclohexane written by Georg Peter Maria Seeber and published by . This book was released on 2003 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal Complexes of Schiff Base Ligands Derived from Polyketones written by John Richard Tate and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Novel Di N heterocyclic Carbene Ligands and Related Transition Metal Complexes written by Marco Monticelli and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The PhD, a collaboration between the University of Padova and the University of Strasbourg, is focused on the chemistry of di(N-heterocyclic carbene) ligands and can be divided in four families of ligands that constitute the four chapters: i) metal complexes (Cu(I), Ag(I), Au(I), Ir(III), Ru(II)) with di(N-heterocyclic carbene) ligands bearing a rigid phenylene bridge between the carbene units; ii) metal complexes (Cu(I), Ag(I), Au(I), Ru(II)) combining an imidazole-based NHC ligand functionalized with a triazole in the 5 position of the backbone; iii) metal complexes (Ag(I), Au(I), Pd(II)) with heteroditopic ligands based on imidazol-2-ylidene and 1,2,3-triazol-5-ylidene moieties connected with a propylene bridge; iv) bis(benzoxazolium) proligands and attempted synthesis of related transition metal complex.

Download or read book Cyclopentadienyl Titanium Complexes of a Unique Tridentate Ligand CIS 1 3 5 cyclohexanetrialkoxide written by Wayne E. Buschmann and published by . This book was released on 1992 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition metal complexes of 1 3 5 Trimethylhexahydro s triazine written by James Michael Westerman and published by . This book was released on 1969 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structural Studies of Transition Metal Complexes of Electron rich Cis dithiolate Ligands written by Matthew Lynn Miller and published by . This book was released on 2003 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal Complexes with Multidentate Phosphorous nitrogen Ligands Synthesis Characterization and Reactivity written by Sergio Santiago Rozenel and published by . This book was released on 2011 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract Transition metal complexes with multidentate phosphorous/nitrogen ligands. Synthesis, characterization and reactivity. By Sergio Santiago Rozenel Doctor in Philosophy in Chemistry University of California, Berkeley Professor John Arnold, Chair Chapter 1: Chromium complexes supported by the multidentate monoanionic ligand [N2P2] {H[N2P2] = tBuN(H)SiMe2N(CH2CH2PiPr2)2} are presented, and the activity of these complexes towards ethylene oligomerization/polymerization is examined. The complexes [N2P2]CrCl2 (1) and [N2P2]CrCl (2) polymerized ethylene after activation with MAO. Derivatives of 1 and 2 were synthesized in order to gain insights about the active species in the ethylene oligomerization/polymerization processes. The alkyl complexes [N2P2]CrMe (3), [N2P2]CrCH2SiMe3 (4) and [N2P2]Cr(Cl)CH2SiMe3 (5), the cationic species {[N2P2]CrCl}BF4 (7), {[N2P2]CrCl}BPh4 (8) and {[N2P2]CrCH2SiMe3}BF4 (9), and the Cr(II) complex [N2P2]CrOSO2CF3 (11) were not active ethylene oligomerization/polymerization catalysts in absence of an activator. Reaction of 1 with two equivalents of MeLi led to reduction to 3. However, with one equivalent of MeLi the stable mixed alkyl-halide derivative [N2P2]Cr(Cl)Me (6) was obtained. Reaction of 2 with Red-Al® produced the hydride ([N2P2]Cr)2(ì-H)2 (10), which reacted with CO to produce the Cr(I) complex [N2P2]Cr(CO)2 (12). Reduction of 2 with KC8 in the presence of p-tolyl azide produced the dimeric cis μ-imido ([N2P2]Cr)2(ì-NC7H7)2 (13). A similar reduction in the presence of ethylene resulted in the isolation of the Cr(III) metallacyclohexane compound [N2P2]CrC4H8 (14). Chapter 2: A series of Co, Ni and Cu complexes with the ligand HN(CH2CH2PiPr2)2 (HPNP) has been isolated and their electrochemical behavior investigated by cyclic voltammetry. The nickel complexes [(HPNP¬)NiOTf]OTf and [(HPNP)NiNCCH3](BF4)2 display reversible reductions, as does the related amide derivative (NP2)NiBr. Related copper(I) and cobalt(II) derivatives were isolated and characterized. Addition of piperidine to [(HNP2)NiNCCH3](BF4)2 led to the formation of the new species [(HPNP)Ni(N(H)C(CH3)NC5H10)](BF4)2. Nucleophilic addition of piperidine to acetonitrile to produce HN=C(CH3)NC5H10 was catalyzed by [(HPNP)NiNCCH3](BF4)2. Chapter 3: A series of bimetallic ruthenium complexes [HPNPRu(N2)]2(μ-Cl)2](BF4)2 (2), [(HPNPRu(H2)Cl)2(μ-Cl)2](BF4)2 (3), [(HPNPRu)2(μ-H2NNH2)(μ-Cl)2](BF4)2 (4), [(HPNPRu)2(μ-Cl)2(μ-HNNPh)](BF4)2 (5), [HPNPRu(NH3)(ç2-N2H4)](BF4)Cl (6), [(HNP2Ru)2(μ-Cl)2(μ2-OSO2CF3)]OSO2CF3 (7), [HPNPRu]2(μ-Cl)3]BPh4 (8) and [HPNPRu]2(μ-Cl)3]BF4 (9) were isolated and characterized in the course of reactions aimed at studying the reduction of N2 and hydrazine. Complex 4 produces ammonia catalytically from hydrazine, and complex 2 generates ammonia upon reaction with Cp2Co/HLuBF4. DFT calculations support the idea that the diazene complex formed is more stable than the expected Chatt-type intermediate. Chapter 4: The reduction chemistry of cobalt complexes with the PNP ligand was explored. Reaction of (HPNP)CoCl2 (1) with n-BuLi generated the deprotonated Co(II) product (PNP)CoCl (2), and the Co(I) reduced species (HPNP)CoCl (3). The reaction of complex 2 with KC8 was investigated, where it was found that the products obtained depended upon the inert gas used to carry out the reaction: (PNP)CoN2 (4) under N2, bimetallic complex [(PNP)Co]2 (5) under Ar, and (HPNP)Co(H)3 (8) under H2. Complex 5 reacted with H2 to generate the bimetallic complex [(PNP)CoH]2 (6). With H2, H3SiPh and AgBPh4 complex 3 generated the species (HPNP)CoCl(H)2 (9), (HPNP)CoCl(H)SiH2Ph (10) and [(HPNP)CoCl]BPh4 (11) respectively. DFT calculations were performed to gain insights about the transformations observed.

Download or read book Metal Ligand Multiple Bonds written by William A. Nugent and published by Wiley-Interscience. This book was released on 1988-11-14 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.

Download or read book Two four six 2 4 6 tris 2 pyridyl 1 3 5 triazine as a Ligand in the Formation of Transition Metal Complexes written by Robert Sylvester Vagg and published by . This book was released on 1966 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Magnetic and Spectral Studies of Some Mono and Binuclear Transition Metal Complexes of Substituted 1 3 5 triketones and Their Schiff base Derivatives written by James Lonzo Mack and published by . This book was released on 1978 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Early Transition Metal Complexes of Pyrazole derived Ligands written by Sally C. Lawrence and published by . This book was released on 2003 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: