Download or read book Tracing Biogeochemical Processes Using Sulfur Stable Isotopes Two Novel Applications written by Mélanie L. Cousineau and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Tracing Earth Surface Processes Using Novel Isotopic Approaches written by Kang-Jun Huang and published by Frontiers Media SA. This book was released on 2023-02-27 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Novel Applications of Stable Isotope Tracing Methods in Biomedical and Environmental Sciences written by Fiona Claire Larner and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Non Traditional Stable Isotopes written by Fang-Zhen Teng and published by Walter de Gruyter GmbH & Co KG. This book was released on 2017-03-06 with total page 902 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.
Download or read book Biogeochemistry Science and Education written by Chris Mead and published by . This book was released on 2014 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation is presented in two sections. First, I explore two methods of using stable isotope analysis to trace environmental and biogeochemical processes. Second, I present two related studies investigating student understanding of the biogeochemical concepts that underlie part one. Fe and Hg are each biogeochemically important elements in their own way. Fe is a critical nutrient for phytoplankton, while Hg is detrimental to nearly all forms of life. Fe is often a limiting factor in marine phytoplankton growth. The largest source, by mass, of Fe to the open ocean is windblown mineral dust, but other more soluble sources are more bioavailable. To look for evidence of these non-soil dust sources of Fe to the open ocean, I measured the isotopic composition of aerosol samples collected on Bermuda. I found clear evidence in the fine size fraction of a non-soil dust Fe source, which I conclude is most likely from biomass burning. Widespread adoption of compact fluorescent lamps (CFL) has increased their importance as a source of environmental Hg. Isotope analysis would be a useful tool in quantifying this impact if the isotopic composition of Hg from CFL were known. My measurements show that CFL-Hg is isotopically fractionated, in a unique pattern, during normal operation. This fractionation is large and has a distinctive, mass-independent signature, such that CFL Hg can be uniquely identified from other sources. Misconceptions research in geology has been a very active area of research, but student thinking regarding the related field of biogeochemistry has not yet been studied in detail. From interviews with 40 undergraduates, I identified over 150 specific misconceptions. I also designed a multiple-choice survey (concept inventory) to measure understanding of these same biogeochemistry concepts. I present statistical evidence, based on the Rasch model, for the reliability and validity of this instrument. This instrument will allow teachers and researchers to easily quantify learning outcomes in biogeochemistry and will complement existing concept inventories in geology, chemistry, and biology.
Download or read book Sediments Diagenesis and Sedimentary Rocks written by F.T. Mackenzie and published by Elsevier. This book was released on 2005-11-22 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers the formation and biogeochemistry of a variety of important sediment types from their initial formation through their conversion (diagenesis) to sedimentary rocks. The volume deals with the chemical, mineralogical, and isotopic properties of sediments and sedimentary rocks and their use in interpreting the environment of formation and subsequent events in the history of sediments, and the nature of the ocean-atmosphere system through geological time. Reprinted individual volume from the acclaimed Treatise on Geochemistry, (10 Volume Set, ISBN 0-08-043751-6, published in 2003). - Comprehensive and authoritative scope and focus - Reviews from renowned scientists across a range of subjects, providing both overviews and new data, supplemented by extensive bibliographies - Extensive illustrations and examples from the field
Download or read book Using Geochemical Data written by Hugh Rollinson and published by Cambridge University Press. This book was released on 2021-05-06 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is a complete rewrite, and expansion of Hugh Rollinson's highly successful 1993 book Using Geochemical Data: Evaluation, Presentation, Interpretation. Rollinson and Pease's new book covers the explosion in geochemical thinking over the past three decades, as new instruments and techniques have come online. It provides a comprehensive overview of how modern geochemical data are used in the understanding of geological and petrological processes. It covers major element, trace element, and radiogenic and stable isotope geochemistry. It explains the potential of many geochemical techniques, provides examples of their application, and emphasizes how to interpret the resulting data. Additional topics covered include the critical statistical analysis of geochemical data, current geochemical techniques, effective display of geochemical data, and the application of data in problem solving and identifying petrogenetic processes within a geological context. It will be invaluable for all graduate students, researchers, and professionals using geochemical techniques.
Download or read book Stable Isotope Ecology written by Brian Fry and published by Springer Science & Business Media. This book was released on 2007-01-15 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: A solid introduction to stable isotopes that can also be used as an instructive review for more experienced researchers and professionals. The book approaches the use of isotopes from the perspective of ecological and biological research, but its concepts can be applied within other disciplines. A novel, step-by-step spreadsheet modeling approach is also presented for circulating tracers in any ecological system, including any favorite system an ecologist might dream up while sitting at a computer. The author’s humorous and lighthearted style painlessly imparts the principles of isotope ecology. The online material contains color illustrations, spreadsheet models, technical appendices, and problems and answers.
Download or read book Application of Stable Isotopes and Geochemical Analysis to Characterize Sulfate Nitrate and Trace Element Contamination of Groundwater and Its Remediation at a Former Uranium Mining Site written by Ziheng Miao and published by . This book was released on 2013 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfate, nitrate, and certain trace elements are common groundwater contaminants observed at mining sites. Their source, fate, and remediation were investigated at a former uranium mining site. First, groundwater samples collected across the site were analyzed for geochemistry, stable isotopes, and trace elements. Then, two pilot-scale ethanol injection tests were conducted for biostimulation of nitrate and sulfate reduction. Groundwater was monitored in the test area before and after the tests. The results showed a mixing of two discrete sources of sulfate. Quantification of these two sources using two methods showed that sulfide-mineral oxidation of the mine tailings served as a steady but low-discharge source while sulfuric acid (applied during ore processing in the 1960s) served as a variable, strong source. It appears that sulfuric acid served as a sustained source of sulfate for approximately 40 years. This source may be from accumulation of sulfate salts (formed from sulfuric acid) in the source zone due to the arid climate of the site. Results showing correspondence of isotopic compositions of ammonium and nitrate confirmed the generation of nitrate via nitrification. Moreover, it was observed that ammonium concentration is closely related to concentrations of uranium and a series of other trace elements including chromium, selenium, vanadium, iron, and manganese. It is hypothesized that ammonium-nitrate transformation processes influence the disposition of the trace elements through mediation of redox potential, pH, and possibly aqueous complexation and solid-phase sorption. As for the biostimulation, sulfate reduction condition has been maintained for a period of approximately 3 years after a single input. Atypical fractionation behavior of the delta34S in sulfate was hypothesized to be caused by release of sulfate from sulfate minerals associated with the sediments. Elevated hydrogen sulfide concentrations were not observed until approximately four months after the start of the test. This behavior, in concert with the observed changes in aqueous iron and manganese species, suggests that hydrogen sulfide produced from sulfate reduction was precipitated, presumably in the form of iron sulfides, until the exhaustion of readily reducible iron oxides. Hydrogen sulfide produced thereafter appears to have been in part re-oxidized.
Download or read book Handbook of Stable Isotope Analytical Techniques written by Pier A. de Groot and published by Elsevier. This book was released on 2004-10-27 with total page 1265 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Parent with price) Volume I contains subjective reviews, specialized and novel technique descriptions by guest authors. Part 1 includes contributions on purely analytical techniques and Part 2 includes matters such as development of mass spectrometers, stability of ion sources, standards and calibration, correction procedures and experimental methods to obtain isotopic fractionation factors.Volume II will be available in 2005.
Download or read book Isoscapes written by Jason B. West and published by Springer Science & Business Media. This book was released on 2009-11-25 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable isotope ratio variation in natural systems reflects the dynamics of Earth systems processes and imparts isotope labels to Earth materials. Carbon isotope ratios of atmospheric CO2 record exchange of carbon between the biosphere and the atmosphere; the incredible journeys of migrating monarchs is documented by hydrogen isotopes in their wings; and water carries an isotopic record of its source and history as it traverses the atmosphere and land surface. Through these and many other examples, improved understanding of spatio-temporal isotopic variation in Earth systems is leading to innovative new approaches to scientific problem-solving. This volume provides a comprehensive overview of the theory, methods, and applications that are enabling new disciplinary and cross-disciplinary advances through the study of "isoscapes": isotopic landscapes. "This impressive new volume shows scientists deciphering and using the natural isotope landscapes that subtly adorn our spaceship Earth.", Brian Fry, Coastal Ecology Institute, Louisiana State University, USA "An excellent timely must read and must-have reference book for anybody interested or engaged in applying stable isotope signatures to questions in e.g. Anthropology, Biogeochemistry, Ecology, or Forensic Science regarding chronological and spatial movement, changes, or distribution relating to animals, humans, plants, or water.", Wolfram Meier-Augenstein, Centre for Anatomy & Human Identification, University of Dundee, UK "Natural resources are being affected by global change, but exactly where, how, and at what pace? Isoscapes provide new and remarkably precise answers.", John Hayes, Woods Hole Oceanographic Institution, USA "This exciting volume is shaping a new landscape in environmental sciences that is utilizing the remarkable advances in isotope research to enhance and extend the capabilities of the field.", Dan Yakir, Weizmann Institute of Science, Israel
Download or read book Stable Isotope Fractionations in Biogeochemical Reactive Transport written by Jennifer Lea Druhan and published by . This book was released on 2012 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: Characterizing the reactivity and fate of solutes in groundwater presents a formidable challenge in that these environments are inherently isolated from the observer. Samples are commonly limited to sediment cores and fluid collected from discrete well bores, while the measurements from these locations must be used to infer geochemical processes occurring across continuous, dynamic and heterogeneous systems. Stable isotope fractionations are an important tool in the quantitative analysis of reactive transport processes in porous media because they provide information coupled to, but distinct from solute concentrations. Examples of the combined analysis of solute concentrations and stable isotope fractionations abound in the literature, but almost entirely involve analytical models that decouple isotopic fractionation from the full extent of reactive pathways contributing to water-rock interaction in porous media flow. It is the purpose of this dissertation to apply analysis of stable isotopes to elucidate the processes of biogeochemical reactivity contributing to in situ bioreduction of uranium during electron donor augmentation in the Old Rifle aquifer in western Colorado. Bio-induced stabilization of heavy metals in subsurface systems involves a complex and concurrent series of dissimilatory reduction reactions, each with a unique metabolism and contaminant affinity. In such a complex system, application of simplified fractionation-reactivity relationships is shown to be inadequate to describe the behavior of multiple stable isotope systems. As a result, the methodology is developed to explicitly incorporate the isotopologues of these species into a multi-component reactive transport model of the system. The result is a means of mechanistically analyzing isotopic fractionation within an integrated framework encompassing the complete reactive network associated with electron-donor augmented bioreduction. The chapters herein are roughly divided into two sections. In the first half, sulfur and calcium isotopes are measured during field scale acetate amendments at Old Rifle. The results of these analyses demonstrate the utility of isotopic fractionation to track the development of terminal electron accepting processes and the formation of secondary mineral precipitates. However, these studies also demonstrate the limitations incurred by restriction to discrete well bores. In the second half, a flow-though column study is designed to overcome these limitations and test the extent to which individual isotopic fractionations are conserved during reactive transport under Old Rifle conditions. The results provide the first carbon budget during electron donor augmentation, and demonstrate that while the [delta]34S fractionation induced by biogenic sulfate reduction is conservative, ion exchange effects dampen the [delta]44Ca fractionation associated with carbonate precipitation.
Download or read book Stable Oxygen and Sulfur Isotopes Applied to Tracing Seepage from Mine Tailings written by Kimberly Sue Ries and published by . This book was released on 1982 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Stable Isotope Biogeochemistry and Ecology written by Cook Craig S. and published by . This book was released on 2018* with total page 173 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Compound specific Stable Isotope Analysis written by Maik A Jochmann and published by Royal Society of Chemistry. This book was released on 2015-11-09 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of Compound-specific Stable Isotope Analysis (CSIA) is increasing in many areas of science and technology for source allocation, authentication, and characterization of transformation reactions. Until now, there have been no textbooks available for students with an analytical chemical background or basic introductory books emphasising the instrumentation and theory. This book is the first to focus solely on stable isotope analysis of individual compounds in sometimes complex mixtures. It acts as both a lecture companion for students and a consultant for advanced scientists in fields including forensic and environmental science. The book starts with a brief history of the field before going on to explain stable isotopes from scratch. The different ways to express isotope abundances are introduced together with isotope effects and isotopic fractionation. A detailed account of the required technical equipment and general procedures for CSIA is provided. This includes sections on derivatization and the use of microextraction techniques in GC-IRMS. The very important topic of referencing and calibration in CSIA is clearly described. This differs from approaches used in quantitative analysis and is often difficult for the newcomer to comprehend. Examples of successful applications of CSIA in food authenticity, forensics, archaeology, doping control, environmental science, and extraterrestrial materials are included. Applications in isotope data treatment and presentation are also discussed and emphasis is placed on the general conclusions that can be drawn from the uses of CSIA. Further instrumental developments in the field are highlighted and selected experiments are introduced that may act as a basis for a short practical course at graduate level.
Download or read book Tracking Animal Migration with Stable Isotopes written by and published by Academic Press. This book was released on 2008-04-09 with total page 157 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tracking Animal Migration with Stable Isotopes provides a consolidated overview of the current knowledge of stable isotopes in terrestrial migration research questions. It offers ecologists and conservation biologists provide a practical handbook for those considering using stable isotopes in their migration research. - Presents information for readers to understand how to apply isotopic methods for tracking - Critical information on areas for future research - Practical guidelines and discussions of sample collection, sample preparation, and data analysis - Enhanced understanding of data and statistical analysis in isotope-based studies of migratory animals
Download or read book Use of Stable Isotopes of Carbon Nitrogen and Sulfur to Identify Sources of Nitrogen in Surface Waters in the Lower Susquehanna River Basin Pennsylvania written by Charles A. Cravotta and published by . This book was released on 2002 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt:
