Download or read book Thermodynamic properties of multicomponent fluid mixtures written by Gregory J. Ashton and published by . This book was released on 1975 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of Multicomponent Fluid Mixtures written by Gregory Joseph Ashton and published by . This book was released on 1975 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of Nonelectrolyte Solutions written by William Acree and published by Academic Press. This book was released on 2012-12-02 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.
Download or read book Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory written by John Telotte and published by . This book was released on 2019-05-31 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: A solution of groups technique was developed for use with fluctuation solution theory. The general expressions for calculation of pressure and chemical potential changes from some fixed reference states have been shown. A new corresponding states theory correlation for direct correlation function integrals was proposed and used with the group contribution technique for calculation of pressure changes during compression for several n-alkanes and methanol. This work gives a detailed analysis of the RISM theory of liquids. Shown are new results for perturbation theory and a generalized compressibility theorem for RISM fluids. The use of the RISM theory for calculation of thermodynamic properties of real fluids also is given. The use of hard sphere reference fluids for development of equations of state has been explored. A generalized hard sphere equation of state was developed. It was shown that the most accurate hard sphere equation of state is not the best reference system for construction of a liquid phase equation of state of the van der Waals form. Dissertation Discovery Company and University of Florida are dedicated to making scholarly works more discoverable and accessible throughout the world. This dissertation, "Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory" by John Charles Telotte, was obtained from University of Florida and is being sold with permission from the author. A digital copy of this work may also be found in the university's institutional repository, IR@UF. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation.
Download or read book Thermodynamic Properties of Multicomponent Mixtures from the Solution of Groups Approach to Direct Correlation Function Solution Theory written by John Charles Telotte and published by . This book was released on 1985 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: A solution of groups technique was developed for use with fluctuation solution theory. The general expressions for calculation of pressure and chemical potential changes from some fixed reference states have been shown. A new corresponding states theory correlation for direct correlation function integrals was proposed and used with the group contribution technique for calculation of pressure changes during compression for several n-alkanes and methanol. This work gives a detailed analysis of the RISM theory of liquids. Shown are new results for perturbation theory and a generalized compressibility theorem for RISM fluids. The use of the RISM theory for calculation of thermodynamic properties of real fluids also is given. The use of hard sphere reference fluids for development of equations of state has been explored. A generalized hard sphere equation of state was developed. It was shown that the most accurate hard sphere equation of state is not the best reference system for construction of a liquid phase equation of state of the van der Waals form.
Download or read book Thermodynamic Properties of Fluids and Fluid Mixtures written by I. M. Abdulagatov and published by Begell House Publishers. This book was released on 1999-01-01 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book considers various methods of experimental study of thermal and caloric properties of pure substances and binary mixtures in wide ranges of the variation of independent variables, including the near critical region. Containing over 100 tables and figures, and exhaustively researched (over 500 references are listed), this monograph is addressed to both theorists and experimenters working in the fields of molecular physics, chemical technology, and power engineering, as well as researchers, lecturers, postgraduates, and students.
Download or read book Kinetic and Thermodynamic Lumping of Multicomponent Mixtures written by G. Astarita and published by Elsevier. This book was released on 2012-12-02 with total page 367 pages. Available in PDF, EPUB and Kindle. Book excerpt: Information necessary to solve scientific or engineering problems is often so vast, that the need arises to lump information together into a more manageable subset in order to proceed. The idea of lumping is one which is used, more or less consciously, in a large variety of fields. The thermodynamics and kinetic behavior of multicomponent mixtures is an area where the requirements of lumping have been clearly identified and the techniques and results of lumping have been analyzed in considerable detail. This book comprises the proceedings of a Symposium on Kinetic and Thermodynamic Lumping of Multicomponent Mixtures which was held at the American Chemical Society Meeting in Atlanta, GA, in April 1991. Papers presented at the symposium consisted of both invited and contributed papers. Each invited paper was a review of a subfield within the landscape of the symposium while the contributed papers contain detailed analyses of specific problems. The symposium brought together active researchers in this field to report on and discuss the progress which has been made in the lumping of mixtures of very many components for a number of different applications, and to identify the important problem areas which still remain. This volume will serve both as an introduction to anyone entering the field, and as a reference work for more experienced researchers.
Download or read book High Pressure Phase Behaviour of Multicomponent Fluid Mixtures written by R.J. Sadus and published by Elsevier. This book was released on 2012-12-02 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: The high pressure phase behaviour of binary fluid mixtures has been extensively studied during the last three decades. There is ample experimental data for a wide variety of binary mixtures and extensive methods for prediction have been developed. In contrast, the investigation of ternary and other multicomponent fluids is in its infancy. Experimental ternary mixture critical data are very rare and theoretical studies have been limited to data correlation rather than genuine prediction. The phase behaviour of ternary and other multicomponent fluid mixtures has many novel aspects which are not manifested in binary mixtures. The properties of ternary mixtures are also likely to be more difficult to characterize experimentally. It is in this context that calculated phase diagrams have an important role in leading the discovery of new phenomena and guiding experimental work. The criteria for phase equilibria of multicomponent fluids with particular emphasis on the critical state are examined in this book, and models for predicting fluid equilibria (e.g., different equations of state) are compared. Particular attention is paid to the critical state of ternary mixtures which has hitherto been largely neglected. The problems associated with predicting ternary equilibria are discussed, and some novel aspects of ternary critical phenomena are illustrated. The books also describes a novel type of critical transition which appears to be a common feature of the equilibria of ternary mixtures. Extensive phase diagrams of a wide range of ternary mixtures including systems containing carbon dioxide, water, nitrogen and tetrafluoromethane as one or more component are presented. The theoretical treatment is detailed in the appendix and a computation of known experimental critical points is also included.
Download or read book Thermophysical Properties of Fluids written by Marc J. Assael and published by World Scientific. This book was released on 1996 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.
Download or read book Applied Thermodynamics of Fluids written by A. R. H. Goodwin and published by Royal Society of Chemistry. This book was released on 2010 with total page 535 pages. Available in PDF, EPUB and Kindle. Book excerpt: Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Download or read book Thermodynamic Properties of Complex Fluid Mixtures written by Gerd Maurer and published by Wiley-VCH. This book was released on 2004-06-25 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: A priority programme of the Deutsche Forschungsgemeinschaft (DFG) was conducted to investigate the thermophysical and thermochemical fundamentals relevant for process design in the chemical and petrochemical industry as well as for biotechnological and environmental process sciences. The priority programme comprised 27 projects in which researchers form various disciplines like applied thermodynamics, industrial chemistry, physical chemistry, process sciences, or biotechnology collaborated to solve some of the major problems of modern thermodynamics. The research results are exclusively documented in this book and cover topics like phase equilibrium in chemical reactive mixtures, in aqueous solutions of electrolytes, aqueous two-phase systems and polymer solutions, high pressure fluid phase equilibria, and microemulsion systems. The results contribute to a better understanding of important phase equilibrium phenomena and help to improve process models.
Download or read book Perturbation Theories for the Thermodynamic Properties of Fluids and Solids written by J. R. Solana and published by CRC Press. This book was released on 2013-03-22 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories—as well as integral equation theories and density functional theories—for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.
Download or read book Prediction of the thermodynamic properties of multicomponent mixtures written by Angela Jane Gunning and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Properties of Gases and Liquids 5E written by Bruce E. Poling and published by McGraw Hill Professional. This book was released on 2000-11-27 with total page 802 pages. Available in PDF, EPUB and Kindle. Book excerpt: Must-have reference for processes involving liquids, gases, and mixtures Reap the time-saving, mistake-avoiding benefits enjoyed by thousands of chemical and process design engineers, research scientists, and educators. Properties of Gases and Liquids, Fifth Edition, is an all-inclusive, critical survey of the most reliable estimating methods in use today --now completely rewritten and reorganized by Bruce Poling, John Prausnitz, and John O’Connell to reflect every late-breaking development. You get on-the-spot information for estimating both physical and thermodynamic properties in the absence of experimental data with this property data bank of 600+ compound constants. Bridge the gap between theory and practice with this trusted, irreplaceable, and expert-authored expert guide -- the only book that includes a critical analysis of existing methods as well as hands-on practical recommendations. Areas covered include pure component constants; thermodynamic properties of ideal gases, pure components and mixtures; pressure-volume-temperature relationships; vapor pressures and enthalpies of vaporization of pure fluids; fluid phase equilibria in multicomponent systems; viscosity; thermal conductivity;diffusion coefficients; and surface tension.
Download or read book Thermodynamics Of Fluids Measurement And Correlation written by A Anderko and published by World Scientific. This book was released on 1990-03-01 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a collection of papers, mostly state-of-the-art reviews, describing main topics of current research in Applied Thermodynamics. The papers deal with measurements of thermodynamic properties which are important for process design in chemical and related industries as well as for theoretical investigations of pure fluids and mixtures. Besides measuring techniques, methods are reviewed for the processing and correlation of experimental data.
Download or read book Modeling of Thermodynamic Properties and Phase Equilibria of Multicomponent Systems Related to the Oil and Gas Industry Using the PC SAFT Equation of State written by Sally Hisham Mohamed El Meragawi and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Equations of state (EoS) have proved to be a reliable tool in chemical engineering thermodynamics for modeling the physical properties of complex systems. Various types of EoS have been developed based on different theories. For various reasons, some have become more popular for use in industry and academia. Of the popular EoS, two were chosen for investigation in this thesis. The first one was the Perturbed Chain- Statistical Associating Fluid Theory (PC-SAFT), an equation derived based on statistical mechanics and the second was the Peng-Robinson (PR) EoS, a cubic EoS commonly used in industry. In this work, the prediction capabilities of these two EoS were compared for several properties. The analysis began with an evaluation of their use in the prediction of the saturation properties of pure components and derivative properties from ambient conditions to the supercritical range. The particular derivative properties studied include the isochoric and isobaric heat capacities, the speed of sound, and the isothermal compressibility. In general, it was concluded that PC-SAFT outperforms PR in all cases. Next, the same primary and derivative properties of several binary and a select ternary mixture were studied. To improve agreement with experimental data, a binary interaction parameter was introduced and fitted to binary mixture vapor - liquid equilibria (VLE) data. This procedure drastically improved the accuracy of the models compared to the case where no binary interaction parameter used for the case of VLE predictions. However, for the case of the derivative properties, the use of the binary interaction parameter to ensure a more accurate representation of the interactions between molecules had only a marginal effect on the prediction of these properties. Finally, phase equilibria of hydrates were studied. As EoS for fluids are not designed to predict the properties of solid phases, the van der Waals-Platteeuw model was incorporated to allow for the prediction of three-phase equilibrium conditions of various hydrate formers. Specifically, this work focused on the equilibrium of a water-rich liquid phase, a hydrate phase and a vapor phase rich in a hydrate former. In all cases, calculations of the solid hydrate phase properties are based on the Kihara potential. This potential requires three parameters to be defined; initial values for which were found through a review of the literature. The accuracy of the predictions of the three-phase equilibrium is highly dependent on the reliability of these parameters. Thus, one of the parameters, the so-called Îæ parameter, was fitted to hydrate equilibrium data and resulted in a significant improvement in the accuracy of predictions of both PC-SAFT and PR EoS. The new set of parameters was then used to predict the three-phase equilibrium of several binary, ternary and quaternary mixtures of hydrate forming agents. Several conclusions are drawn from this work, including the observation that the accuracy of the models is reduced when the number of components increases. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/155481
Download or read book Thermodynamic Properties of Supercritical Fluids and Their Mixtures at Very High Pressures written by Gerrit Jan Fairley Breedveld and published by . This book was released on 1972 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt:
