Download or read book Thermodynamic Properties of Aqueous Solutions at High Temperatures written by Chia-tsun Liu and published by . This book was released on 1971 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book High Temperature Aqueous Solutions written by Roberto Fernandez-Prini and published by CRC Press. This book was released on 1991-12-19 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a thorough discussion of the thermodynamics of aqueous solutions and presents tools for analyzing and solving scientific and practical problems arising in this area. It also presents methods that can be used to deal with ionic and nonionic aqueous solutions under sub- or supercritical conditions. Illustrations and tables give examples of procedures employed to predict thermodynamic quantities of the solutions, and an appendix summarizing statistical mechanical equations used to describe the systems is also provided. High-Temperature Aqueous Solutions: Thermodynamic Properties contains essential information for physical chemists, geochemists, geophysicists, chemical technicians, and scientists involved in electric power generation.
Download or read book Thermodynamic Properties of High Temperature Aqueous Solutions written by Cecil M. Criss and published by . This book was released on 1961 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of High Temperature Aqueous Solutions written by and published by . This book was released on 1961 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Roberto Fernandez-Prini and published by Elsevier. This book was released on 2004-07-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors’ goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis. - Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures - The presentation of the book is understandable to readers from a variety of backgrounds
Download or read book Thermodynamic Properties of Aqueous Solutions Organic Substances written by V. P. Belousov and published by Springer. This book was released on 1994 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamic Properties of Aqueous Solutions of Organic Substances discusses the structure of aqueous solutions of organic substances and the intermolecular reactions in them, presenting experimental data, modern concepts concerning the properties of these solutions, and the results of computer simulation. The book offers an in-depth study of the properties of maximally dilute aqueous solutions of polar and nonpolar organic molecules as well as the specific enthalpies of mixing. The Addendum contains experimental data on the thermodynamic properties of infinitely dilute solutions.
Download or read book Excess Thermodynamic Properties of Concentrated Aqueous Solutions at High Temperatures written by and published by . This book was released on 2001 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Measurements of the vapor pressure of the solvent in wide ranges of concentration and temperature provide information on solute solvation and ion pairing--the two phenomena most often invoked for description of dilute solutions. Even in moderately concentrated solutions, as interionic distances become comparable to ionic diameters, these simple concepts gradually lose their meaning and solutions behave like molten salts. The usefulness of experimental vapor pressure results increases rapidly with their accuracy, since derived properties, such as solution enthalpies and heat capacities, can be calculated. Very accurate results can be obtained by the isopiestic method, but primary vapor pressure data for standard solutions are needed. In order to obtain vapor pressures at conditions where accurate isopiestic standards are not available and to establish more accurate standards, the ORNL isopiestic apparatus was modified for simultaneous direct vapor pressure measurements and isopiestic comparisons. There are no comprehensive solution theories derived from molecular level models and able to predict thermodynamic properties of various electrolytes as the composition changes from dilute solutions to molten salts in a wide range of temperatures. Empirical and semi-empirical models are useful for representation of experimental results, interpretation of measurements of other properties such as conductance., solubility or liquid-vapor partitioning of solutes, and for verification of theoretical predictions. Vapor pressures for aqueous CaCl2, CaBr2, LiCl, LiBr, LiI, NaI were measured at temperatures between 380 and 523 K in the concentration range extended to water activities below 0.2 (over 30 mol/kg for LiCl). General equations based on the modified Pitzer ion-interaction model were used to obtain enthalpy and heat capacity surfaces, which are compared with direct calorimetric measurements.
Download or read book The Thermodynamic Properties of Ions in Aqueous and Non aqueous Solutions at Various Temperatures written by Cecil M. Criss and published by . This book was released on 1965 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Properties of Aqueous Solutions of Electrolytes written by Ivan D. Zaytsev and published by CRC Press. This book was released on 1992-08-24 with total page 1784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources, and other such activities. This edition, the first available in English, has been substantially revised and augmented. Many new tables have been added because of a significantly larger list of electrolytes and their properties (electrical conductivity, boiling and freezing points, pressure of saturated vapors, activity and diffusion coefficients). The book is divided into two sections. The first section provides tables that list the properties of binary aqueous solutions of electrolytes, while the second section deals with the methods for calculating their properties in multicomponent systems. All values are given in PSI units or fractional and multiple units. Metrological characteristics of the experimental methods used for the determination of physico-chemical parameters are indicated as a relative error and those of the computational methods as a relative error or a root-mean square deviation.
Download or read book Handbook of Aqueous Electrolyte Thermodynamics written by Joseph F. Zemaitis, Jr. and published by John Wiley & Sons. This book was released on 2010-09-16 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.
Download or read book The Concentration and Temperature Dependence of the Thermodynamic Properties of Aqueous Solutions of Bolaform Electrolytes written by David Alan Foss and published by . This book was released on 1974 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Water and Aqueous Solutions at Subzero Temperatures written by Felix Franks and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Volume, the last of the series, is devoted to water in its metastable forms, especially at sub-zero temperatures. The past few years have wit nessed an increasing interest in supercooled water and amorphous ice. If the properties of liquid water in the normal temperature range are already eccentric, then they become exceedingly so below the normal freezing point, in the metastable temperature range. Water can be supercooled to -39°C without too much effort, and most of its physical properties show a re markable temperature dependence under these conditions. Although ade quate explanations are still lacking, the time has come to review available knowledge. The study of amorphous ice, that is, the solid formed when water vapor is condensed on a very cold surface, is of longer standing. It has achieved renewed interest because it may serve as a model for the liquid state. There is currently a debate whether or not a close structural relation ship exists between amorphous ice and supercooled water. The nucleation and growth of ice in supercooled water and aqueous solutions is also still one of those grey areas of research, although these topics have received considerable attention from chemists and physicists over the past two decades. Even now, the relationships between degree of supercooling, nucleation kinetics, crystal growth kinetics, cooling rate and solute concentration are somewhat obscure. Nevertheless, at the empirical level much progress has been made, because these topics are of considerable importance to biologists, technologists, atmospheric physicists and gla ciologists.
Download or read book Properties of Water and Aqueous Solutions at High Pressures and Temperatures written by C. Wayne Burnham and published by . This book was released on 1968 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of Water to 1 0000 C and 10 000 Bars written by C. Wayne Burnham and published by Geological Society of America. This book was released on 1969 with total page 105 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of Aqueous Solutions Etc written by J. B. Taylor and published by . This book was released on 1954 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of Aqueous NaCl from 273 to 823 K with Estimates for Higher Temperatures written by Lawrence Berkeley Laboratory and published by . This book was released on with total page 39 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Thermochemical Data for Compounds and Aqueous Species written by Herbert E. Barner and published by John Wiley & Sons. This book was released on 1977 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
