Download or read book Thermodynamic and Transport Properties for Molten Salts written by George J. Janz and published by American Institute of Physics. This book was released on 1988 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic and Transport Properties of Organic Salts written by Paolo Franzosini and published by Elsevier. This book was released on 2013-10-22 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamic and Transport Properties of Organic Salts is concerned with the thermodynamic and transport properties of organic salts, namely, pure salts, mixtures, and solutions. The transport properties of pure molten salts and binary mixtures of molten salts with organic ions are given, along with the transport properties of organic salts in aqueous solutions. This book is divided into three sections and opens with a discussion on the statistical treatment and of computer simulation methods for molten salts as well as their results for pressure-volume-temperature (PVT) data. The PVT data for organic molten salts determined experimentally are considered, and the thermal properties as well as the melting mechanism of pure salts are described. A method by which PVT data at high pressure can be estimated from those at low pressure with sufficiently high accuracy is also outlined. The next section deals with salt mixtures, their phase diagrams, and their transport properties. The final section looks at the transport properties of organic salts in aqueous solutions; thermodynamic quantities of micelle formation; and formation of lyotropic liquid crystals by organic salts. Two appendixes showing the structure of the pure solids and the use of the melts in electrochemical studies are included. This monograph will be a useful resource for organic chemists.
Download or read book Molten Salts Handbook written by George J. Janz and published by Elsevier. This book was released on 2013-06-11 with total page 613 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten Salts Handbook focuses on the features, properties, and structure of molten salts. This book presents several topics in annotated bibliographic table form, including phase equilibria, chemical syntheses, and molten salt electrolytes. Organized into six chapters, this book starts with a tabular presentation of data of the physical properties, thermodynamic properties, electrochemical properties, practical features, as well as spectroscopy and structure of molten salts. This text then illustrates the design features of different experimental assemblies and provides information on the technique through a liberally annotated bibliography. Other chapters provide a chemical index, which offers a ready guide to the status of data over the entire range of interests. This book presents as well the properties of viscosity, density, surface tension, refractive index, and electrical conductance for different compounds as single salt melts. This book is a valuable resource for scientists and researchers from diverse fields, including theoretical and applied electrochemistry, inorganic coordination chemistry, and transition metal chemistry.
Download or read book Molten Salts written by Marcelle Gaune-Escard and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: Several state-of-the-art applications of molten salts are presented, such as metal-molten salt systems, room temperature glass formation, and room temperature melts. Several recent examples of applications highlight the importance of molten salts in various industries (batteries, pyrochemical reprocessing of nuclear fuel, synthesis and catalysis). The basic concepts of the structure, dynamics, electrochemistry, interfacial and thermodynamic properties are detailed and relevant experimental methods described. Such fundamental concepts are essential for an in-depth understanding of the physicochemical properties of molten salts in general, including metal-molten salts, glass forming and low temperature melts. Experimental methods for investigating structural, dynamical, electrochemical thermodynamical and interfacial properties are detailed, as also are techniques for data collection and analysis. Scientists, engineers and technologists will find the volume a valuable reference source covering a wide spectrum of fundamental concepts and modern technologies.
Download or read book Thermodynamic Properties of Molten salt Solutions written by Milton Blander and published by . This book was released on 1962 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molten Salt Chemistry written by Gleb Mamantov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts are of considerable significance to chemical technology. Applications range from the established ones, such as the production of aluminum, magnesium, sodium and fluorine, to those as yet to be fully exploited, such as molten salt batteries and fuel cells, catalysis, and solar energy. Molten salts are investigated for different purposes by many diverse techniques. There is a need to keep investigators working in different areas, such as metal production, power sources, and glass industry, aware of progress in various specialties, as well as to familiarize new research workers with the fundamental aspects of the broad field of molten salt _ chemistry. This volume constitutes the plenary lectures presented at the NATO Advanced Study Institute on Molten Salt Chemistry, Camerino, Italy, August 3-15, 1986. The fundamentals and several selected applications of molten salt chemistry were addressed. The major fundamental topics covered at this ASI were the structure of melts, thermodynamics of molten salt mixtures, theoretical and experimental studies of transport processes, metal-metal salt solutions, solvent properties of melt systems, acid-base effects in molten salt chemistry, electronic absorption, vibrational, and nuclear magnetic resonance spectroscopy of melt systems, electrochemistry and electroanalytical chemistry in molten salts, and organic chemistry in molten salts. The applied aspects of molten salt chemistry included the chemistry of aluminum production, electrodeposition using molten salts, and molten salt batteries and fuel cells.
Download or read book Molten Salts written by Gleb Mamantov and published by . This book was released on 1969 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molten Salts and Ionic Liquids written by Marcelle Gaune-Escard and published by John Wiley & Sons. This book was released on 2012-07-06 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: For many years, the related fields of molten salts and ionic liquids have drifted apart, to their mutual detriment. Both molten salts and ionic liquids are liquid salts containing only ions - all that is different is the temperature! Both fields involve the study of Coulombic fluids for academic and industrial purposes; both employ the same principles; both require skilled practitioners; both speak the same language; all then that is truly different is their semantics, and how superficial is that? The editors of this book, recognising that there was so much knowledge, both empirical and theoretical, which can be passed from the molten salt community to the ionic liquid community, and vice versa, organised a landmark meeting in Tunisia, designed to bridge the gap and heal the rift. Leaders from both communities met for a week for a mutual exchange, with a high tutorial content intermixed with cutting edge findings. This volume is a condensate of the principal offerings of that week, and emphasises the success which was achieved. Indeed, four future biannual meetings, under the title of “EUCHEM Conferences on Molten Salts and Ionic Liquids”, have now been planned as a direct result of this meeting of minds. Topics discussed in this volume include structure, dynamics, electrochemistry, interfacial and thermodynamic properties, spectroscopy, synthesis, and theoretical studies. Experimental and theoretical methods for investigating these data are elaborated, as are techniques for data collection and analysis. This book represents the first serious discussion on the transfer of these methods and techniques between the differing temperature regimes, and is a major contribution to the future of both fields.
Download or read book Advances in Molten Salt Chemistry written by J. Braunstein and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts are investigated by very diverse techniques and for differ ing purposes, and the results are reported in widely scattered journals. There is a need to keep investigators aware of progress in other specialties and to provide students with source and background material. Advances in Molten Salt Chemistry hopes to fill these needs by providing reviews of recent progress presented, insofar as is reasonable, with enough background material and commentary to be comprehensible to a nonspecialist. We prefer a discussion of underlying principles, to the extent that they are known, and we encourage authors to comment critically on the reliability of data, the utility of models, and the cogency of ideas and theories. We take a broad vie~ of the suitability of topics for inclusion in this series. Both fundamental and technological advances have a place here, as do studies on materials related to molten salts (like liquid silicates, very concentrated aqueous solutions, solutions of salts in liquid metals, and solid electrolytes). We intend this series to serve the needs of those who investigate or use molten salts. We welcome suggestions of topics and suitable authors, as well as comments on the strengths and shortcomings of what is published.
Download or read book Molten Salt Chemistry written by Gleb Mamantov and published by Springer. This book was released on 1987-06-30 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts are of considerable significance to chemical technology. Applications range from the established ones, such as the production of aluminum, magnesium, sodium and fluorine, to those as yet to be fully exploited, such as molten salt batteries and fuel cells, catalysis, and solar energy. Molten salts are investigated for different purposes by many diverse techniques. There is a need to keep investigators working in different areas, such as metal production, power sources, and glass industry, aware of progress in various specialties, as well as to familiarize new research workers with the fundamental aspects of the broad field of molten salt _ chemistry. This volume constitutes the plenary lectures presented at the NATO Advanced Study Institute on Molten Salt Chemistry, Camerino, Italy, August 3-15, 1986. The fundamentals and several selected applications of molten salt chemistry were addressed. The major fundamental topics covered at this ASI were the structure of melts, thermodynamics of molten salt mixtures, theoretical and experimental studies of transport processes, metal-metal salt solutions, solvent properties of melt systems, acid-base effects in molten salt chemistry, electronic absorption, vibrational, and nuclear magnetic resonance spectroscopy of melt systems, electrochemistry and electroanalytical chemistry in molten salts, and organic chemistry in molten salts. The applied aspects of molten salt chemistry included the chemistry of aluminum production, electrodeposition using molten salts, and molten salt batteries and fuel cells.
Download or read book Molten Salts Chemistry written by Frederic Lantelme and published by Newnes. This book was released on 2013-08-14 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts and fused media provide the key properties and the theory of molten salts, as well as aspects of fused salts chemistry, helping you generate new ideas and applications for fused salts.Molten Salts Chemistry: From Lab to Applications examines how the electrical and thermal properties of molten salts, and generally low vapour pressure are well adapted to high temperature chemistry, enabling fast reaction rates. It also explains how their ability to dissolve many inorganic compounds such as oxides, nitrides, carbides and other salts make molten salts ideal as solvents in electrometallurgy, metal coating, treatment of by-products and energy conversion.This book also reviews newer applications of molten salts including materials for energy storage such as carbon nano-particles for efficient super capacitors, high capacity molten salt batteries and for heat transport and storage in solar plants. In addition, owing to their high thermal stability, they are considered as ideal candidates for the development of safer nuclear reactors and for the treatment of nuclear waste, especially to separate actinides from lanthanides by electrorefining. Explains the theory and properties of molten salts to help scientists understand these unique liquids Provides an ideal introduction to this expanding field Illustrated text with key real-life applications of molten salts in synthesis, energy, nuclear, and metal extraction
Download or read book THE THERMODYNAMIC PROPERTIES OF MOLTEN SALTS Report No 4 Bimonthly Progress Report for August September 1955 written by and published by . This book was released on 1955 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this research is to determine the absolute entropies, heats of formation, and free energies of formation of selected salts in the temperature range of 800 to 1900 deg F. Assembling and testing of apparatus for measuring heat capacities from about 50 deg K to room temperature has been completed, including calibration of thermocouples by comparison with a platinum and with a copper resistance thermometer. This apparatus has been used to determine the absolute entropy of molybdenum hexafluoride vapor at 298.16 deg K. The result, 79.7 +- 0.6 calories/mole deg C, agrees well with that calculated from its spectrum, 80.05 cal/mole deg C.A solution calorimeter has also been assembled and tested. By comparing the heat of solution in aqueous sodium hydroxide of molybdenum hexafluoride with that of the oxide, the delta H of formation of the fluoride was found to be -392.2 cal/mole at 298.16 deg K. These data, together with other data extant in the literature, allow calculation of the desired thermodynamic functions over the temperature range of interest.
Download or read book Molten Salts Chemistry and Technology written by Marcelle Gaune-Escard and published by John Wiley & Sons. This book was released on 2014-05-12 with total page 902 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written to record and report on recent research progresses in the field of molten salts, Molten Salts Chemistry and Technology focuses on molten salts and ionic liquids for sustainable supply and application of materials. Including coverage of molten salt reactors, electrodeposition, aluminium electrolysis, electrochemistry, and electrowinning, the text provides researchers and postgraduate students with applications include energy conversion (solar cells and fuel cells), heat storage, green solvents, metallurgy, nuclear industry, pharmaceutics and biotechnology.
Download or read book Fundamental Understanding of Thermophysical Properties of Molten Salts Containing Nanoparticles written by Geng Qiao and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts have been widely used as thermal energy storage (TES) materials as they offer favourable specifications which enable them to be employed in TES applications. Finding a cost-effective method to enhance the energy storage capability of molten salts has caught the attention of many researchers. It was reported that by adding a small amount of nanoparticles, a major enhancement of the specific heat capacity was observed in molten salts. Though different studies argued that the enhancement was not found in other thermal storage materials, the observation of the enhancement was continuously reported. This work studied the thermal properties of molten salt based nanosuspensions synthesized with a novel method modified based on other studies. Molecular dynamics (MD) simulations were employed to study the thermodynamic properties of the nanosuspension systems. By the analysis of the effect on the internal energy of the nanosuspensions I draft general conclusions and explain why molten salt have this specific heat enhancement while other materials (e.g. water) does not. I use MD simulation to support, for the first time, a theory that can explain the apparently contradictory behaviour of the experimental data. Moreover, the main impact factor affecting the enhancement was investigated and discussed.
Download or read book Molten Salt Technology written by David G. Lovering and published by Springer. This book was released on 2014-11-14 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamics of Molten Salt Mixtures written by John Lumsden and published by . This book was released on 1966 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Thermodynamic Properties of Binary Molten Salt Mixtures by Enthalpy Measurements written by Peter Kurtz and published by . This book was released on 1964 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
