Download or read book Theoretical Spectroscopy of Transition Metal and Rare Earth Ions written by Mikhail G. Brik and published by CRC Press. This book was released on 2019-12-11 with total page 209 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes in detail the main concepts of theoretical spectroscopy of transition metal and rare-earth ions. It shows how the energy levels of different electron configurations are formed and calculated for the ions in a free state and in crystals, how group theory can help in solving main spectroscopic problems, and how the modern DFT-based methods of calculations of electronic structure can be combined with the semi-empirical crystal field models. The style of presentation makes the book helpful for a wide audience ranging from graduate students to experienced researchers. Performance of optical materials crucially depends on the impurity ions intentionally introduced into the crystalline host materials. The color of these materials, their emission and absorption spectra can be understood by analyzing the relations between the electronic properties of impurity ions and host crystal structure, which constitutes the main content of this book. It describes in detail the main concepts of theoretical spectroscopy of transition metal and rare earth ions.

Download or read book Theoretical Spectroscopy of Transition Metal and Rare Earth Ions written by Mikhail G. Brik and published by CRC Press. This book was released on 2019-12-11 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes in detail the main concepts of theoretical spectroscopy of transition metal and rare-earth ions. It shows how the energy levels of different electron configurations are formed and calculated for the ions in a free state and in crystals, how group theory can help in solving main spectroscopic problems, and how the modern DFT-based methods of calculations of electronic structure can be combined with the semi-empirical crystal field models. The style of presentation makes the book helpful for a wide audience ranging from graduate students to experienced researchers. Performance of optical materials crucially depends on the impurity ions intentionally introduced into the crystalline host materials. The color of these materials, their emission and absorption spectra can be understood by analyzing the relations between the electronic properties of impurity ions and host crystal structure, which constitutes the main content of this book. It describes in detail the main concepts of theoretical spectroscopy of transition metal and rare earth ions.

Download or read book Excited States Of Transition Elements Proceedings Of The 2nd International School written by Strek W and published by World Scientific. This book was released on 1992-09-30 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the recent advances in spectroscopy and theoretical modeling relevant to the interpretation of luminescence and laser phenomena in solid state materials. The available solid state matrices in crystalline and glassy states and the full range of activaters-transition metal ions, rare earth ions and actinides are considered here. Processes of activator excitation, energy transfer between activators and relaxation of excited states are particularly stressed.

Download or read book Spectroscopy of Crystals Containing Rare Earth Ions written by A.A. Kaplyanskii and published by Elsevier. This book was released on 2012-12-02 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: ``Spectroscopy of Crystals Containing Rare Earth Ions'' contains chapters on some key problems selected from a broad range of spectroscopic studies of RE-activated solids including both crystalline and glassy materials. Progress in crystal field theory is surveyed, an area which is basic to our understanding of the energy levels. The treatment of dynamical properties includes studies of coherence phenomena in isolated ions, energy transfer between ions and co-operative phenomena associated with ion-ion and ion-lattice interactions. In addition, the role of electron spins and nuclear spins is studied by light scattering and double resonance techniques. The presence of inhomogeneous broadening of spectral lines is observed and studied in many contexts, leading to new insights into general problems of the disordered state. Considerable attention is devoted to describing new experimental techniques whose development is of prime importance for progress in the spectroscopy of RE-activated solids. Many of these rely on the development and application of tunable lasers. At the moment this is a very active field of spectroscopy with more exciting developments likely to occur in the future.

Download or read book Spectroscopy of Solids Containing Rare Earth Ions written by A. A. Kapli͡anskiĭ and published by North Holland. This book was released on 1987 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopy of Crystals Containing Rare Earth Ions'' contains chapters on some key problems selected from a broad range of spectroscopic studies of RE-activated solids including both crystalline and glassy materials. Progress in crystal field theory is surveyed, an area which is basic to our understanding of the energy levels. The treatment of dynamical properties includes studies of coherence phenomena in isolated ions, energy transfer between ions and co-operative phenomena associated with ion-ion and ion-lattice interactions. In addition, the role of electron spins and nuclear spins is studied by light scattering and double resonance techniques. The presence of inhomogeneous broadening of spectral lines is observed and studied in many contexts, leading to new insights into general problems of the disordered state. Considerable attention is devoted to describing new experimental techniques whose development is of prime importance for progress in the spectroscopy of RE-activated solids. Many of these rely on the development and application of tunable lasers. At the moment this is a very active field of spectroscopy with more exciting developments likely to occur in the future.

Download or read book Luminescent Materials written by Mikhail G. Brik and published by Walter de Gruyter GmbH & Co KG. This book was released on 2023-03-06 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives an overview on the fundamentals and recent developments in the field of luminescent materials. Starting from the definitions and properties of phosphors, novel application areas as well as spectroscopic methods for characterization will be described. The reader will benefit from the vast knowledge of the authors with backgrounds in industry as well as academia.

Download or read book Optical Spectroscopy of Lanthanides written by Brian G. Wybourne and published by CRC Press. This book was released on 2007-04-25 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Optical Spectroscopy of Lanthanides: Magnetic and Hyperfine Interactions represents the sixth and final book by the late Brian Wybourne, an accomplished pioneer in the spectroscopy of rare earth ions, and Lidia Smentek, a leading theoretical physicist in the field. The book provides a definitive and up-to-date theoretical description of spec

Download or read book Transition Metal and Rare Earth Compounds written by Hartmut Yersin and published by Springer. This book was released on 2003-07-01 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal and rare earth compounds are investigated intensively because of important questions concerning fundamental research problems. More recently also their enormous potential for the development of new materials for photophysical and photochemical applications has been explored. Thus, it is important to focus on a deeper understanding of the elctronic energies, transition prohabilities, intermolecular interactions, etc.. This task has been accomplished by leading researchers in the field. They present introductions into, but also detailed reviews of the current state of knowledge of three different subjects.

Download or read book Theory and Application of Rare Earth Materials written by Changzhen Wang and published by Springer Nature. This book was released on 2023-05-18 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book starts with a theoretical introduction of the rare earth materials, and it subsequently analyzes the essential characteristics of these materials from elements, compounds to physical chemistry and metal materials, etc. Under the supplementary explanation of experimental data and results, the research is gradually guided into the multi-domain application scene. Through extensive analyses, this book displays comprehensively the distinguished values of the rare earth materials and the theoretical, empirical, and practical significance of rare earth materials is unraveled. It also covers an exhaustive review of 17 rare earth elements, their characteristics, and more possibilities in physical chemistry, functional materials, metallurgy, composites and engineering, and their prospects in production and technical applications. In-depth account of the whole spectrum of rare earth material research makes this book a unique reference to academic researchers, students, and engineers.

Download or read book Optical Spectra of Transparent Rare Earth Compounds written by S. Hufner and published by Elsevier. This book was released on 2012-12-02 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: Optical Spectra of Transparent Rare Earth Compounds investigates the optical spectra of transparent rare earth (RE) compounds such as europium chalcogenides. Emphasis is placed on the underlying physics in selected examples, and theoretical results are usually presented without proof in a form that allows their application to the interpretation of experimental data. This book is comprised of 11 chapters and begins with an overview of the spectra of RE ions in ionic crystals, paying particular attention to the sharpness of many lines in the absorption and emission spectra. How these very narrow lines arise, what interactions determine their energy, and how they can be used to investigate particular properties of the solid state are explained in detail. Subsequent chapters explore the energy structure of RE free ions in solids; trivalent RE ions in a static crystal field and in a phonon field; magnetic interactions and hyperfine interactions; and Jahn-Teller systems. The absorption spectra of europium chalcogenides are also considered, along with REs in glasses and RE lasers. This monograph is written primarily for solid state physicists and those who need an overall view of the basic features of rare earth spectra in transparent solids, such as new workers.

Download or read book Magnetooptical Spectroscopy of the Rare Earth Compounds Development and Application written by Uygun V. Valiev and published by Scientific Research Publishing, Inc. USA. This book was released on 2012-01-05 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comparison of theory with experiment is made for rare-earth compounds with garnet structure and orthoaluminate whose optical, magnetic and magnetooptical features have been studied sufficiently well by now.

Download or read book Spectroscopic Properties of Rare Earths in Optical Materials written by Guokui Liu and published by Springer Science & Business Media. This book was released on 2006-01-29 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aimed at researchers and graduate students, this book provides up-to-date information about the electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties covers electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions of materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.

Download or read book Optical Spectroscopy of Inorganic Solids written by B. Henderson and published by Oxford University Press. This book was released on 2006 with total page 678 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text describes the technique of optical spectroscopy applied to problems in condensed matter physics. It relates theoretical understanding to experimental measurement, including discussion of the optical spectroscopy of inorganic insulators, with many illustrative examples. Symmetry arguments are developed from a formal group theoretical basis and are frequently used, and a special effort is made to treat the subject of lattice vibrations and to show how these can affect the spectroscopic properties of solids. The elements of laser theory are developed, and the authors also explore the use of optically detected magnetic resonance techniques for the investigation of semiconducting materials.

Download or read book Phosphor Handbook written by Ru-Shi Liu and published by CRC Press. This book was released on 2022-01-31 with total page 866 pages. Available in PDF, EPUB and Kindle. Book excerpt: A benchmark publication, the first edition of the Phosphor Handbook, published in 1998, set the standard for references in the field. The second edition, updated and published in 2007, began exploring new and emerging fields. However, in the last 14 years, since the second edition was published, many notable advances and broader phosphor applications have occurred. Completely revised, updated, and expanded into three separate volumes, this third edition of the Handbook covers the most recent developments in phosphor research, characterization, and applications. This volume on ‘Experimental Methods for Phosphor Evaluation and Characterization’ addresses the theoretical and experimental methods for phosphor evaluation and characterization. The chapters in the book cover: First principle and DFT analysis of optical, structural, and chemical properties of phosphors Phosphor design and tuning through structure and solid solution Design for IR, NIR, and narrowband emission and thermally stable phosphors and nanophosphors Detailed illustration for measurement of the absolute photoluminescence quantum yield of phosphors Phosphor analysis through photoionization, high pressure, and synchrotron radiation studies

Download or read book Transition Metal and Rare Earth Compounds written by Hartmut Yersin and published by Springer. This book was released on 2014-03-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.

Download or read book Laser Spectroscopy of Solids written by W. M. Yen and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this volume we have attempted to present a concise survey of the spectroscopic properties of insulators as derived from the application of tunable laser spectro scopic techniques. As has been the case in gaseous atomic spectroscopy, the use of tunable lasers has allowed the extension and the refmement of optical measure ments in the condensed phases to unprecedented resolutions in the frequency and temporal domains. In turn, this firmer base of empirical fmdings has led to a more sophisticated theoretical understanding of the spectroscopy of optically excited states with major modifications being apparent in the area of their dynamic be havior. Yet the revivalistic nature of these advances implies that additional advan ces are to be expected as the techniques and developments outlined in this volume are put to widespread use. Regardless, it is our hope and that of our distinguished colleagues in this venture that the reviews presented here will be useful to neo phytes and veterans to this field alike - to the former as a laissez-passer into solid-state spectroscopy, to the latter as a useful synopsis and reference of recent developments. We have also attempted to expose the reader to the concept that optically active materials, be they organic or inorganic, as universality would require, be have in a like manner and, though terminology may vary in detail, the outline and general features of all insulators remain constant.

Download or read book Handbook on the Physics and Chemistry of Rare Earths written by and published by Elsevier. This book was released on 2011-09-22 with total page 559 pages. Available in PDF, EPUB and Kindle. Book excerpt: Optical spectroscopy has been instrumental in the discovery of many lanthanide elements. In return, these elements have always played a prominent role in lighting devices and light conversion technologies (Auer mantles, incandescent lamps, lasers, cathode-ray and plasma displays). They are also presently used in highly sensitive luminescent bio-analyses and cell imaging. This volume of the Handbook on the Physics and Chemistry of Rare Earths is entirely devoted to the photophysical properties of these elements. It is dedicated to the late Professor William T (Bill) Carnall who has pioneered the understanding of lanthanide spectra in the 1960’s and starts with a Dedication to this scientist. The following five chapters describe various aspects of lanthanide spectroscopy and its applications. Chapters 231 presents state-of-the-art theoretical calculations of lanthanide energy levels and transition intensities. It is followed by a review (Chapter 232) on both theoretical and experimental aspects of f-d transitions, a less well known field of lanthanide spectroscopy, yet very important for the design of new optical materials. Chapter 233 describes how confinement effects act on the photophysical properties of lanthanides when they are inserted into nanomaterials, including nanoparticles, nanosheets, nanowires, nanotubes, insulating and semiconductor nanocrystals. The use of lanthanide chelates for biomedical analyses is presented in Chapter 234; long lifetimes of the excited states of lanthanide ions allow the use of time-resolved spectroscopy, which leads to highly sensitive analyses devoid of background effect from the autofluorescence of the samples. The last review (Chapter 235) provides a comprehensive survey of near-infrared (NIR) emitting molecular probes and devices, spanning an all range of compounds, from simple chelates to macrocyclic complexes, heterometallic functional edifices, coordination polymers and other extended structures. Applications ranging from telecommunications to light-emitting diodes and biomedical analyses are assessed. - Provides a comprehensive look at optical spectroscopy and its applications- A volume in the continuing authoritative series which deals with the chemistry, materials science, physics and technology of the rare earth elements