Download or read book The Thermodynamics of Linear Fluids and Fluid Mixtures written by Miloslav Pekař and published by Springer Science & Business Media. This book was released on 2013-11-19 with total page 315 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, Samohýl and Pekař offer a consistent and general non-equilibrium thermodynamic description for a model of chemically reacting mixtures. This type of model is frequently encountered in practice and up until now, chemically reacting systems (out of equilibrium) have rarely been described in books on non-equilibrium thermodynamics. Readers of this book benefit from the systematic development of the theory; this starts with general principles, going through the applications to single component fluid systems, and finishing with the theory of mixtures, including chemical reactions. The authors describe the simplest mixture model – the linear fluid – and highlight many practical and thermodynamically consistent equations for describing transport properties and reaction kinetics for this model. Further on in the book, the authors also describe more complex models. Samohýl and Pekař take special care to clearly explain all methodology and starting axioms and they also describe in detail applied assumptions and simplifications. This book is suitable for graduate students in chemistry, materials science and chemical engineering as well as professionals working in these and related areas.
Download or read book The Thermodynamics of Linear Fluids and Fluid Mixtures written by Miloslav Peka and published by . This book was released on 2013-11-30 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Applied Thermodynamics of Fluids written by A. R. H. Goodwin and published by Royal Society of Chemistry. This book was released on 2010 with total page 535 pages. Available in PDF, EPUB and Kindle. Book excerpt: Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Download or read book Fluid and Thermodynamics written by Kolumban Hutter and published by Springer. This book was released on 2018-09-22 with total page 627 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third volume describes continuous bodies treated as classical (Boltzmann) and spin (Cosserat) continua or fluid mixtures of such bodies. It discusses systems such as Boltzmann continua (with trivial angular momentum) and Cosserat continua (with nontrivial spin balance) and formulates the balance law and deformation measures for these including multiphase complexities. Thermodynamics is treated in the spirit of Müller–Liu: it is applied to Boltzmann-type fluids in three dimensions that interact with neighboring fluids on two-dimensional contact surfaces and/or one-dimensional contact lines. For all these situations it formulates the balance laws for mass, momenta, energy, and entropy. Further, it introduces constitutive modeling for 3-, 2-, 3-d body parts for general processes and materially objective variable sets and their reduction to equilibrium and non-equilibrium forms. Typical (reduced) fluid spin continua are liquid crystals. Prominent nematic examples of these include the Ericksen–Leslie–Parodi (ELP) formulation, in which material particles are equipped with material unit vectors (directors). Nematic liquid crystals with tensorial order parameters of rank 1 to n model substructure behavior better, and for both classes of these, the book analyzes the thermodynamic conditions of consistency. Granular solid–fluid mixtures are generally modeled by complementing the Boltzmann laws with a balance of fluctuation (kinetic) energy of the particles. The book closes by presenting a full Reynolds averaging procedure that accounts for higher correlation terms e.g. a k-epsilon formulation in classical turbulence. However, because the volume fraction is an additional variable, the theory also incorporates ‘k-epsilon equations’ for the volume fraction.
Download or read book Equations of State for Fluids and Fluid Mixtures written by J.V. Sengers and published by Elsevier. This book was released on 2000-10-30 with total page 896 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.
Download or read book Hydrodynamic Fluctuations in Fluids and Fluid Mixtures written by Jose M. Ortiz de Zarate and published by Elsevier. This book was released on 2006-04-19 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed. · Systematic exposition of fluctuating hydrodynamics and its applications · First book on nonequilibrium fluctuations in fluids · Fluctuating Boussinesq equations and nonequilibrium fluids · Fluid layers and onset of convection · Rayleigh scattering and Brillouin scattering in fluids · Shadowgraph technique for measuring fluctuations · Fluctuations near hydrodynamic instabilities
Download or read book Perturbation Theories for the Thermodynamic Properties of Fluids and Solids written by J. R. Solana and published by CRC Press. This book was released on 2013-03-22 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perturbation theory forms an important basis for predicting the thermodynamic characteristics of real fluids and solids. This book provides a comprehensive review of current perturbation theories-as well as integral equation theories and density functional theories-for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the book avoids complex theoretical derivations as much as possible. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.
Download or read book Fluid and Thermodynamics written by Kolumban Hutter and published by Springer. This book was released on 2016-06-10 with total page 639 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first volume discusses fluid mechanical concepts and their applications to ideal and viscous processes. It describes the fundamental hydrostatics and hydrodynamics, and includes an almanac of flow problems for ideal fluids. The book presents numerous exact solutions of flows in simple configurations, each of which is constructed and graphically supported. It addresses ideal, potential, Newtonian and non-Newtonian fluids. Simple, yet precise solutions to special flows are also constructed, namely Blasius boundary layer flows, matched asymptotics of the Navier-Stokes equations, global laws of steady and unsteady boundary layer flows and laminar and turbulent pipe flows. Moreover, the well-established logarithmic velocity profile is criticised.
Download or read book Thermodynamic Properties of Fluids and Fluid Mixtures written by I. M. Abdulagatov and published by Begell House Publishers. This book was released on 1999-01-01 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book considers various methods of experimental study of thermal and caloric properties of pure substances and binary mixtures in wide ranges of the variation of independent variables, including the near critical region. Containing over 100 tables and figures, and exhaustively researched (over 500 references are listed), this monograph is addressed to both theorists and experimenters working in the fields of molecular physics, chemical technology, and power engineering, as well as researchers, lecturers, postgraduates, and students.
Download or read book Thermodynamics of Fluids Under Flow written by D. Jou and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on the authors’ successful theory for extended irreversible thermodynamics, the book analyzes the thermodynamic aspects of several phenomena induced by the flow in fluid systems.
Download or read book Thermomechanics written by J. C. Gibbings and published by Elsevier. This book was released on 2016-06-06 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermomechanics gives an introduction to the governing equations of thermodynamics and of the mechanics of fluids. The book first gives a summary of the Newtonian mechanics of rigid bodies, which is followed by a discussion of mechanical properties of infinitesimal elements, including continuum, density, surface tension, stresses, and pressure. Temperature and the zero'th law; units; and the system of finite size are then examined. The book also explains the laws of thermodynamics including its applications. Heat processes, motionless fluids, and mixtures of phases are also tackled. The text then explains the conservation of mass in a fluid flow; the equations relating process phenomena; and the momentum equation for fluids in motion. The last part encompasses the adiabatic flow. The text will best serve those interested in thermomechanics and related concepts.
Download or read book Thermodynamics of Irreversible Processes in Fluid Mixtures written by Ivan Samohýl and published by . This book was released on 1987 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mechanical and Thermodynamical Modeling of Fluid Interfaces written by Rene Gatignol and published by World Scientific. This book was released on 2001 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book constitutes a comprehensive survey of the balance equations for mass, momentum and energy for the interfaces in pure fluids and mixtures. Constitutive laws are presented for many situations in engineering science, and examples are provided, including surface viscosity effects, variable surface tension and vapor recoil. In addition, some extensions of existing theory are given: stretch effect in premixed flames, relaxation zones downstream two-phase shock waves, and effective surface tension for steep gradient zones. Contents: Thermodynamics and Kinematics of Interfaces; Interface Balance Laws; Constitutive Relations Deduced from Linear Irrevesible Thermodynamics for the Two-Dimensional Interfaces; Classical Three-Dimensional Constitutive Relations Deduced from Linear Irreversible Thermodynamics and Their Consequences for Interfaces; Second Gradient Theory Applied to Interfacial Medium; Typical Problems Involving Surface Tensions and Other Surface Properties. Readership: Graduates, physicists, applied mathematicians and engineers seeking classical knowledge in continuum mechanics and thermodynamics, especially in the thermodynamics of irreversible processes.
Download or read book Fluid and Thermodynamics written by Kolumban Hutter and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This third volume describes continuous bodies treated as classical (Boltzmann) and spin (Cosserat) continua or fluid mixtures of such bodies. It discusses systems such as Boltzmann continua (with trivial angular momentum) and Cosserat continua (with nontrivial spin balance) and formulates the balance law and deformation measures for these including multiphase complexities. Thermodynamics is treated in the spirit of Müller-Liu: it is applied to Boltzmann-type fluids in three dimensions that interact with neighboring fluids on two-dimensional contact surfaces and/or one-dimensional contact lines. For all these situations it formulates the balance laws for mass, momenta, energy, and entropy. Further, it introduces constitutive modeling for 3-, 2-, 3-d body parts for general processes and materially objective variable sets and their reduction to equilibrium and non-equilibrium forms. Typical (reduced) fluid spin continua are liquid crystals. Prominent nematic examples of these include the Ericksen-Leslie-Parodi (ELP) formulation, in which material particles are equipped with material unit vectors (directors). Nematic liquid crystals with tensorial order parameters of rank 1 to n model substructure behavior better, and for both classes of these, the book analyzes the thermodynamic conditions of consistency. Granular solid-fluid mixtures are generally modeled by complementing the Boltzmann laws with a balance of fluctuation (kinetic) energy of the particles. The book closes by presenting a full Reynolds averaging procedure that accounts for higher correlation terms e.g. a k-epsilon formulation in classical turbulence. However, because the volume fraction is an additional variable, the theory also incorporates 'k-epsilon equations' for the volume fraction.
Download or read book Thermodynamics of Fluids Under Flow written by David Jou and published by Springer Science & Business Media. This book was released on 2010-12-02 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the second edition of the book “Thermodynamics of Fluids under Flow,” which was published in 2000 and has now been corrected, expanded and updated. This is a companion book to our other title Extended irreversible thermodynamics (D. Jou, J. Casas-Vázquez and G. Lebon, Springer, 4th edition 2010), and of the textbook Understanding non-equilibrium thermodynamics (G. Lebon, D. Jou and J. Casas-Vázquez, Springer, 2008. The present book is more specialized than its counterpart, as it focuses its attention on the non-equilibrium thermodynamics of flowing fluids, incorporating non-trivial thermodynamic contributions of the flow, going beyond local equilibrium theories, i.e., including the effects of internal variables and of external forcing due to the flow. Whereas the book's first edition was much more focused on polymer solutions, with brief glimpses into ideal and real gases, the present edition covers a much wider variety of systems, such as: diluted and concentrated polymer solutions, polymer blends, laminar and turbulent superfluids, phonon hydrodynamics and heat transport in nanosystems, nuclear collisions, far-from-equilibrium ideal gases, and molecular solutions. It also deals with a variety of situations, emphasizing the non-equilibrium flow contribution: temperature and entropy in flowing ideal gases, shear-induced effects on phase transitions in real gases and on polymer solutions, stress-induced migration and its application to flow chromatography, Taylor dispersion, anomalous diffusion in flowing systems, the influence of the flow on chemical reactions, and polymer degradation. The new edition is not only broader in scope, but more educational in character, and with more emphasis on applications, in keeping with our times. It provides many examples of how a deeper theoretical understanding may bring new and more efficient applications, forging links between theoretical progress and practical aims. This updated version expands on the trusted content of its predecessor, making it more interesting and useful for a larger audience.
Download or read book Equations of State for Fluids and Fluid Mixtures written by International Union of Pure and Applied Chemistry. Commission on Thermodynamics and published by . This book was released on 2000 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: These volumes have been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The volumes give a presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.
Download or read book Liquids and Liquid Mixtures written by J S Rowlinson and published by Butterworth-Heinemann. This book was released on 2013-09-03 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.
