Download or read book The Synthesis Reactivity and Electrochemical Study of Metallocene Substituted Diimine Ligands written by Eleanor Magdzinski and published by . This book was released on 2013 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of transition metal complexes containing redox-active ligands or ligands with redox-active substituents have been areas of ongoing interest in chemical research. To date, only a handful of examples involving redox-active ligands containing main group centres have been reported. This thesis presents work on the development of novel redox-active ligands utilizing an assortment of nitrogen-based frameworks (diiminopyridine (DIMPY), 1,4-diaza-1,3-butadiene (DAB), N-heterocyclic carbene (NHC)) that contain metallocene substituents (ferrocene and an understudied redox-active Co(III) moiety). Initially the syntheses of an N, N'-differocenyl diiminopyridine and its low-valent chalcogen (S2+, Se2+, Te2+) and pnictogen (P+) complexes are discussed. These complexes represent the first such examples of utilizing low-valent main group systems containing redox-active ligands with pendant ferrocenyl substituents. Other work focuses on the synthesis of the above listed nitrogen-based ligands containing novel mixed sandwich Co(III) substituents, and include comparative reactivity studies (SnCl2 and GeCl2.dioxane for DIMPY and SnCl4 and Pt2Me4(SMe2)2 for DAB) of those ligands to their ferrocene derivatives. Electrochemical studies reveals an instability of the Co(III) containing complexes, leading to the continuous variation in the ligand framework towards a more stable compound.
Download or read book Metallocenes written by Antonio Togni and published by Wiley-VCH. This book was released on 1998-10-15 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: That terms like sandwich complexes or the concept of compounds without direct chemical bonds between the central metal atom and the ligating atoms are nowadays common knowledge can be attributed to the sensational discovery of ferrocene in the early 1950s. Although ferrocene is still at the forefront of research, this two-volume book highlights the development of metallocene chemistry, and emphasizes the similarities and differences between ferrocene and other metallocenes. Do you require a transition metal to build metallocenes? Must the planes of the cyclopentadienyl ligands be parallel to allow the compound to behave like a typical metallocene? Do zirconocenes react by the same mechanism as molybdenocenes? What are the (potential) applications of these substances? Let yourself be guided by the leading experts in this field, and learn all about the synthesis, reactivity, and unique properties of these sandwich complexes. If you are more interested in applications, there is a wealth of polymeric and dendritic materials with metallocene building blocks described herein. This book also focusses on metallocenes as catalysts in polymerization or asymmetric reactions. If you are graduate student or researcher in organic, inorganic, organometallic, polymer chemistry, and materials science you will find this book an inspiring source of ideas for your own research.
Download or read book Aryl Substituted Imino N Heterocyclic Carbene Complexes Of Late Transition Metals written by Anna Candace Badaj and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Polyhedron written by and published by . This book was released on 1989 with total page 774 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Olefin Polymerization written by Walter Kaminsky and published by Wiley-VCH. This book was released on 2006-08-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.
Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 2003 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1985 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book American Chemical Society Directory of Graduate Research 1987 written by American Chemical Society, Committee on Professional Training Staff and published by . This book was released on 1987 with total page 1390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Experimental and Theoretical Approaches to Actinide Chemistry written by John K. Gibson and published by John Wiley & Sons. This book was released on 2018-03-19 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts in the field, the text includes information on new advances in experiment and theory and reveals the interplay between these two realms. The authors offer a multidisciplinary and multimodal approach to the nature of actinide chemistry, and explore the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry. The text covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques. The authors provide contemporary overviews of each topic area presented and describe the current and anticipated experimental approaches for the field, as well as the current and future computational chemistry and materials techniques. In addition, the authors explore the combination of experiment and theory. This important resource: Provides an essential resource the reviews the key aspects of contemporary actinide research Includes information on new advances in experiment and theory, and the interplay between the two Covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques Focuses on the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry Written for academics, students, professionals and researchers, this vital text contains a thorough review of the key aspects of actinide research and explores the most recent advances in experiment and theory.
Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Download or read book Chemtracts written by and published by . This book was released on 1992 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Syntheses written by Philip P. Power and published by John Wiley & Sons. This book was released on 2018-07-04 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: The newest volume in the authoritative Inorganic Syntheses book series provides users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely inorganic and organometallic compounds that can be used in reactions to develop new materials, drug targets, and bio-inspired chemical entities.
Download or read book Charge Trapping Non Volatile Memories written by Panagiotis Dimitrakis and published by Springer. This book was released on 2017-02-14 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the technology of charge-trapping non-volatile memories and their uses. The authors explain the device physics of each device architecture and provide a concrete description of the materials involved and the fundamental properties of the technology. Modern material properties, used as charge-trapping layers, for new applications are introduced. Provides a comprehensive overview of the technology for charge-trapping non-volatile memories; Details new architectures and current modeling concepts for non-volatile memory devices; Focuses on conduction through multi-layer gate dielectrics stacks.
Download or read book Bulletin of the Korean Chemical Society written by and published by . This book was released on 1980 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Analytical Electrochemistry written by Joseph Wang and published by John Wiley & Sons. This book was released on 2004-03-24 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays
Download or read book Chiral Ferrocenes in Asymmetric Catalysis written by Li-Xin Dai and published by John Wiley & Sons. This book was released on 2010-02-01 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book meets the long-felt need for a reference on ferrocenes with the focus on catalysis. It provides a thorough overview of the synthesis and characterization of different types of chiral ferrocene ligands, their application to various catalytic asymmetric reactions, and versatile chiral materials as well as drug intermediates synthesized from them. Written by the "who's who" of ferrocene catalysis, this is a guide to the design of new ferrocene ligands and synthesis of chiral synthetic intermediates, and will thus be useful for organic, catalytic and synthetic chemists working in academia, industrial research or process development.
Download or read book Zinc Catalysis written by Stephan Enthaler and published by John Wiley & Sons. This book was released on 2015-04-27 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.
