Download or read book The Role of Dissolved Organic Matter in Aquatic Photochemical Oxidation Processes written by Jannis Henrik Wenk and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Photobiogeochemistry of Organic Matter written by Khan M.G. Mostofa and published by Springer Science & Business Media. This book was released on 2012-12-15 with total page 919 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photoinduced processes, caused by natural sunlight, are key functions for sustaining all living organisms through production and transformation of organic matter (OM) in the biosphere. Production of hydrogen peroxide (H2O2) from OM is a primary step of photoinduced processes, because H2O2 acts as strong reductant and oxidant. It is potentially important in many aquatic reactions, also in association with photosynthesis. Allochthonous and autochthonous dissolved organic matter (DOM) can be involved into several photoinduced or biological processes. DOM subsequently undergoes several physical, chemical, photoinduced and biological processes, which can be affected by global warming. This book is uniquely structured to overview some vital issues, such as: DOM; H2O2 and ROOH; HO•; Degradation of DOM; CDOM, FDOM; Photosynthesis; Chlorophyll; Metal complexation, and Global warming, as well as their mutual interrelationships, based on updated scientific results.
Download or read book Biogeochemistry of Marine Dissolved Organic Matter written by Dennis A. Hansell and published by Academic Press. This book was released on 2014-10-02 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Marine dissolved organic matter (DOM) is a complex mixture of molecules found throughout the world's oceans. It plays a key role in the export, distribution, and sequestration of carbon in the oceanic water column, posited to be a source of atmospheric climate regulation. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, focuses on the chemical constituents of DOM and its biogeochemical, biological, and ecological significance in the global ocean, and provides a single, unique source for the references, information, and informed judgments of the community of marine biogeochemists. Presented by some of the world's leading scientists, this revised edition reports on the major advances in this area and includes new chapters covering the role of DOM in ancient ocean carbon cycles, the long term stability of marine DOM, the biophysical dynamics of DOM, fluvial DOM qualities and fate, and the Mediterranean Sea. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, is an extremely useful resource that helps people interested in the largest pool of active carbon on the planet (DOC) get a firm grounding on the general paradigms and many of the relevant references on this topic. Features up-to-date knowledge of DOM, including five new chapters The only published work to synthesize recent research on dissolved organic carbon in the Mediterranean Sea Includes chapters that address inputs from freshwater terrestrial DOM
Download or read book Chemical Processes in Marine Environments written by Antonio Gianguzza and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses recent developments in the study of chemical processes and equilibria in the marine environment and in the air/water and water/sediment interfaces. The chemical cycle of carbon as well as the effect of organic substances on the speciation and distribution of inorganic and organometallic substances are extensively discussed. Much of the recent progress in the area is the direct result of advanced analytical technologies and chemometric applications which are highlighted in the book.
Download or read book The Importance of Photochemical Processes in the Utilization of Dissolved Organic Matter by Bacteria in Two Freshwater and Two Marine Aquatic Ecosystems written by Karen Louise Bushaw and published by . This book was released on 1998 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aquatic Organic Matter Fluorescence written by Paula G. Coble and published by Cambridge University Press. This book was released on 2014-07-14 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: A core text on principles, laboratory/field methodologies, and data interpretation for fluorescence applications in aquatic science, for advanced students and researchers.
Download or read book Advanced Oxidation Processes for Water Treatment written by Mihaela I. Stefan and published by IWA Publishing. This book was released on 2017-09-15 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada
Download or read book Surface Water Photochemistry written by Paola Calza and published by Royal Society of Chemistry. This book was released on 2015-11-20 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Borne out of the current widespread interest in the pollution of water bodies, this book explores the latest research concerning the photochemical fate of organic pollutants in surface water. The main objective is to give insight into both the functioning of ecosystems and the behaviour of emerging pollutants in those ecosystems. Particular importance is dedicated to techniques that can be used in the field and in the laboratory for the detection of pollutants and of their transformation intermediates. The inclusion of photochemical processes that have not gained previous coverage will afford the reader novel insights, whilst the focus on modelling and transformation intermediates will ensure the title's relevance to academics, the chemical manufacturing industries and environmental assessment experts alike.
Download or read book UV Effects in Aquatic Organisms and Ecosystems written by E Walter Helbling and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers extensive coverage of the most important aspects of UVR effects on all aquatic (not just freshwater and marine) ecosystems, encompassing UV physics, chemistry, biology and ecology. Comprehensive and up-to-date, UV Effects in Aquatic Organisms and Ecosystems aims to bridge the gap between environmental studies of UVR effects and the broader, traditional fields of ecology, oceanography and limnology. Adopting a synthetic approach, the different sections cover: the physical factors controlling UVR intensity in the atmosphere; the penetration and distribution of solar radiation in natural waters; the main photochemical process affecting natural and anthropogenic substances; and direct and indirect effects on organisms (from viruses, bacteria and algae to invertebrate and vertebrate consumers). Researchers and professionals in environmental chemistry, photochemistry, photobiology and cell and molecular biology will value this book, as will those looking at ozone depletion and global change.
Download or read book Direct and Indirect Photoreactions of Chromophoric Dissolved Organic Matter written by Jared Verrill Goldstone and published by . This book was released on 2002 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photochemical transformations of chromophoric dissolved organic matter (CDOM) are one of the principal processes controlling its fate in coastal waters. The photochemical decomposition of CDOM leads to the formation of a variety of biologically available carbon substrates. Photomineralization of CDOM to dissolved inorganic carbon may constitute a significant flux in the global carbon cycle. Photoreactions ultimately lead to the destruction of the chromophores and hence to the loss of absorption and fluorescence (bleaching), thus acting as a sink for CDOM. Photodecomposition may proceed both via direct photochemical reactions, following absorption of photons by CDOM, or via indirect processes, involving DOM reactions with photochemically generated intermediates such as reactive oxygen species (ROS). The reactions of CDOM with two important ROS, superoxide (02- ) and hydroxyl radical (OH), have different consequences. Superoxide reactions with CDOM did not appear to degrade the CDOM. Instead, CDOM catalysed the dismutation of 02- to 02 and HOOH. This reactivity has the effect of limiting the steady-state concentration of 02- in most coastal waters. In contrast, reactions of CDOM with radiolytically produced OH formed CO2 and several low molecular weight carboxylic acids, as well as bleached both the absorption and fluorescence at slow rates. These reactions did not increase the bioavailability of this material to a microbial consortium. Both direct and indirect photochemical processes are expected to be accelerated by the presence of iron.
Download or read book Dynamics in the Reactivity and Photochemical Production of Hydroxyl Radical in Treated Wastewater Effluent and Aquatic Dissolved Organic Matter written by Molly C. Semones and published by . This book was released on 2017 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: The hydroxyl radical (HO•) is a photochemically generated species that is important in the attenuation of organic contaminants in sunlit natural surface waters and in advanced oxidation processes (AOPs) used to treat drinking and wastewater. The steady state concentration of HO•, ([HO•]ss), in photochemical systems is typically measured indirectly using probe compounds. In this work, we investigate the use of caffeine as a photochemical probe for the detection of HO• in the presence of dissolved organic matter (DOM) solutions derived from allochthonous and autochthonous precursors using both the first order and initial rates approach to kinetic analysis to determine [HO•]ss in aqueous solution. Values for [HO•]ss are found to agree within a factor of two of values measured using terepthalic acid (TPA), a well-established probe for the detection of HO•, in the identical DOM solutions. Additionally, we find that caffeine is more selective for HO• than previously believed since it does not appear to undergo reaction with long-lived reactive transients as was formerly presumed. The presence of nitrate in wastewater effluent could play an important role in the formation of HO•, and therefore also in the fate of contaminants in sunlit receiving waters. We investigate the interplay between HO• formation derived from both effluent dissolved organic matter (EfOM) and nitrate (NO3-). The assumption of little to no interaction between NO3- and EfOM during HO• production (RHO•), needed to determine the contribution of DOM to hydroxyl radical formation in waters containing NO3- without extracting EfOM from the wastewater, is invalid. We based our findings on measurements of RHO• and [HO•]ss using benzene and caffeine as HO• probes in both whole wastewater effluent and solutions of EfOM isolated by solid phase extraction from the same effluent sample. The RHO• value measured for the isolate in the absence of NO3- (0.074 ± 0.009 (SE) nM s-1) is 1.5 fold higher than that found for bulk, non-isolated EfOM (0.049 ± 0.026 (SE) nM s-1), which was calculated by subtracting the estimated contribution of NO3- to overall HO• production from the RHO• obtained for the Southerly whole wastewater. This difference calculated this way is not significantly different (a=0.05, p=0.39). We find that we are able to reproduce the RHO• found with benzene for Southerly wastewater effluent (0.199 ± 0.022 nM s-1) using a NO3-ROH• curve generated in a Southerly isolate solution (0.178 ± 0.011 nM s-1). Similarly, [HO•]ss values measured in Southerly whole wastewater effluent using caffeine as a probe compound (1.32 ± 0.096 fM) were comparable to measurements made in Southerly EfOM (1.50 ± 0.091 fM). We revise the ratio at which NO3- and DOM contribute equally in solution from the value reported by Vione et al. (2006) of 3.3 x 10-5 [(mol NO3-) (mg-C)-1]) upwards to 8.1 ± 1.5 x 10-5 [(mol NO3-) (mg-C)-1] based on the average of the ratios determined for the three DOM isolates used in this study. Values for [HO•]ss in IHSS isolate solutions and whole wastewater effluent determined by benzene and caffeine are in good agreement, which supports the use of caffeine as a credible HO• probe compound, subject to caveats detailed within this work, in both isolate solutions and whole water containing NO3-. Organic UV-filters are key ingredients found in sunscreens, cosmetics and plastic goods. Concerns have been raised about potential ecological and human health effects of certain organic UV filters that are currently FDA approved for use in the United States. Here, we investigate the photochemical fate of two of these compounds, oxybenzone and sulisobenzone. Both oxybenzone and sulisobenzone have previously been detected in surface waters, seawater, and treated wastewater effluent. Enhanced photodegradation of oxybenzone and sulisobenzone was observed under simulated solar irradiation in solutions of International Humic Substance Society standards (Pony Lake fulvic acid and Suwannee River Natural Organic Matter), filtered wastewater effluent (Southerly Wastewater Treatment Plant in Lockbourne, OH), and Scioto River water (Columbus, OH). Quenching experiments with isopropanol revealed that the main pathway for degradation appears to be reaction with the hydroxyl radical (HO•). Observed degradation rates were 2-3 times slower than estimates calculated using literature reported second-order rate constants and measured hydroxyl radical steady-state concentrations for SRNOM, PLFA and Scioto waters. The Southerly sample, however, exhibited nearly identical expected and observed rate constants, which we take to indicate the presence of unidentified reactive species that can react with oxybenzone and sulisobenzone. Values obtained in this work were used to calculate second-order rate constants for oxybenzone and sulisobenzone with the hydroxyl radical, as well as to estimate environmental half-lives for these compounds. Near surface 24-hour averaged half-lives of 3.0 and 4.0 days were calculated for oxybenzone and sulisobenzone,respectively. When extrapolated to an environmentally representative water column, these same 24-hour averaged half-lives increased to 2.4 and 3.5 years, respectively.
Download or read book Aquatic Humic Substances written by I. H. Suffet and published by . This book was released on 1989 with total page 906 pages. Available in PDF, EPUB and Kindle. Book excerpt: Here is a cohesive compilation of recent research results into the many aspects of water purification. Major sections cover the characterization and environmental impact of aquatic humic substances, their reactions in natural water and sediments, and their influences on water treatment. Topics examined include hazardous waste chemicals, water solubility enhancement, sorption, metal speciation, and photochemistry. Specific types of treatment processes are also described.
Download or read book Biogeochemistry of Marine Dissolved Organic Matter written by Dennis A. Hansell and published by Elsevier. This book was released on 2024-07-04 with total page 870 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biogeochemistry of Marine Dissolved Organic Matter, 3rd edition is the most up-to-date revision of the fundamental reference for the biogeochemistry of marine dissolved organic matter. Since its original publication in June 2002, the science, questions, and priorities have advanced, and the editors of this essential guide, have added nine new chapters, including one on the South China Sea. An indispensable manual edited by the most distinguished experts in the field, this book is addressed to graduate students, marine scientists, and all professionals interested in advancing their knowledge of the field. Features up-to-date knowledge on DOM, including 9 new chapters Presents the only published work to synthesize recent research on dissolved organic carbon in the South China, a region receiving a great deal of attention in recent decades Offers contributions by world-class research leaders
Download or read book Aquatic and Surface Photochemistry written by George R. Helz and published by CRC Press. This book was released on 2018-01-10 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes.This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.
Download or read book Aquatic Humic Substances written by Dag Hessen and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Humic substances occur in all kinds of aquatic systems, but are particularly important in northern, coniferous areas. They strongly modify the aquatic ecosystems and also constitute a major problem in the drinking water supply. This volume covers all aspects of aquatic humic substances, from their origin and chemical properties, their effects on light and nutrient regimes and biogeochemical cycling, to their role regarding organisms, productivity and food web organization from bacteria to fish. Special emphasis is paid to carbon cycling and food web organization in humic lakes, but aspects of marine carbon cycling related to humus are treated as well.
Download or read book Advanced Oxidation Processes for Water and Wastewater Treatment written by Simon Parsons and published by IWA Publishing. This book was released on 2004-03-01 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: The suitability of Advanced Oxidation Processes (AOPs) for pollutant degradation was recognised in the early 1970s and much research and development work has been undertaken to commercialise some of these processes. AOPs have shown great potential in treating pollutants at both low and high concentrations and have found applications as diverse as ground water treatment, municipal wastewater sludge destruction and VOCs control. Advanced Oxidation Processes for Water and Wastewater Treatment is an overview of the advanced oxidation processes currently used or proposed for the remediation of water, wastewater, odours and sludge. The book contains two opening chapters which present introductions to advanced oxidation processes and a background to UV photolysis, seven chapters focusing on individual advanced oxidation processes and, finally, three chapters concentrating on selected applications of advanced oxidation processes. Advanced Oxidation Processes for Water and Wastewater Treatment will be invaluable to readers interested in water and wastewater treatment processes, including professionals and suppliers, as well as students and academics studying in this area. Dr Simon Parsons is a Senior Lecturer in Water Sciences at Cranfield University with ten years' experience of industrial and academic research and development.
Download or read book Photochemical Degradation of Aquatic Dissolved Organic Matter written by Julia Alison Howitt and published by . This book was released on 2003 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:
