Download or read book The Relationship Between the Hard Sphere Fluid and Fluids with Realistic Repulsive Forces written by John D. Weeks and published by . This book was released on 1971 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study considers the equilibrium statistical mechanics of classical fluids in which the potential energy is resolvable into repulsive pair interactions. A generalized cluster expansion is derived relating the thermodynamic and structural properties of such systems to those of the hard sphere fluid. The expansion is ordered by a softness parameter which is essentially the range of intermolecular distances in which the difference between the Mayer functions for the repulsive potential and an appropriate reference hard sphere potential is non-zero. The first (lowest order) approximation generated by the expansion equates the free energy and distribution function for the fluid to the respective functions appropriate to a system of hard spheres with diameter d. A prescription is given for choosing a temperature and density dependent diameter d of the reference hard sphere fluid so that the first approximation for the free energy contains errors of one order only. With this approximation, the results obtained for both model systems agree closely with those obtained by Monte Carlo calculations. (Author).
Download or read book Perturbation Theories for the Thermodynamic Properties of Fluids and Solids written by J. R. Solana and published by CRC Press. This book was released on 2013-03-22 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories—as well as integral equation theories and density functional theories—for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.
Download or read book Advances in Chemical Physics Volume 34 written by Ilya Prigogine and published by John Wiley & Sons. This book was released on 2009-09-08 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.
Download or read book High Pressure Fluid Phase Equilibria written by Ulrich K Deiters and published by Elsevier. This book was released on 2012-04-26 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. introduces phase diagram classes, how to recognize them and identify their characteristic features presents rational nomenclature of binary fluid phase diagrams includes problems and solutions for self-testing, exercises or seminars
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1971 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fundamentals and Practice in Statistical Thermodynamics Solutions Manual written by Jianzhong Wu and published by John Wiley & Sons. This book was released on 2024-07-12 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a solutions manual to accompany Fundamentals and Practice in Statistical Thermodynamics This textbook supplements, modernizes, and updates thermodynamics courses for both advanced undergraduates and graduate students by introducing the contemporary topics of statistical mechanics such as molecular simulation and liquid-state methods with a variety of realistic examples from the emerging areas of chemical and materials engineering. Current curriculum does not provide the necessary preparations required for a comprehensive understanding of these powerful tools for engineering applications. This text presents not only the fundamental ideas but also theoretical developments in molecular simulation and analytical methods to engineering students by illustrating why these topics are of pressing interest in modern high-tech applications.
Download or read book Theory and Simulation of Hard Sphere Fluids and Related Systems written by Angel Mulero and published by Springer. This book was released on 2008-07-10 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hard spheres and related objects (hard disks and mixtures of hard systems) are paradigmatic systems: indeed, they have served as a basis for the theoretical and numerical development of a number of fields, such as general liquids and fluids, amorphous solids, liquid crystals, colloids and granular matter, to name but a few. The present volume introduces and reviews some important basics and progress in the study of such systems. Their structure, thermodynamic properties, equations of state, as well as kinetic and transport properties are considered from different and complementary points of view. This book addresses graduate students, lecturers as well as researchers in statistical mechanics, physics of liquids, physical chemistry and chemical engineering.
Download or read book Molecular Thermodynamics of Nonideal Fluids written by Lloyd L. Lee and published by Butterworth-Heinemann. This book was released on 2016-02-06 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular Thermodynamics of Nonideal Fluids serves as an introductory presentation for engineers to the concepts and principles behind and the advances in molecular thermodynamics of nonideal fluids. The book covers related topics such as the laws of thermodynamics; entropy; its ensembles; the different properties of the ideal gas; and the structure of liquids. Also covered in the book are topics such as integral equation theories; theories for polar fluids; solution thermodynamics; and molecular dynamics. The text is recommended for engineers who would like to be familiarized with the concepts of molecular thermodynamics in their field, as well as physicists who would like to teach engineers the importance of molecular thermodynamics in the field of engineering.
Download or read book Theory of Simple Liquids written by Jean-Pierre Hansen and published by Academic Press. This book was released on 2013-08-12 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive coverage of topics in the theory of classical liquids Widely regarded as the standard text in its field, Theory of Simple Liquids gives an advanced but self-contained account of liquid state theory within the unifying framework provided by classical statistical mechanics. The structure of this revised and updated Fourth Edition is similar to that of the previous one but there are significant shifts in emphasis and much new material has been added. Major changes and Key Features in content include: Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchical reference theory of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation. Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchian reference of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation.
Download or read book Physical Chemistry Matter in equilibrium written by R. Stephen Berry and published by . This book was released on 1980 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Oxford Handbook of Philosophy of Physics written by Robert W. Batterman and published by Oxford University Press. This book was released on 2013-01-04 with total page 701 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Oxford Handbook provides an overview of many of the topics that currently engage philosophers of physics. It surveys new issues and the problems that have become a focus of attention in recent years. It also provides up-to-date discussions of the still very important problems that dominated the field in the past. In the late 20th Century, the philosophy of physics was largely focused on orthodox Quantum Mechanics and Relativity Theory. The measurement problem, the question of the possibility of hidden variables, and the nature of quantum locality dominated the literature on the quantum mechanics, whereas questions about relationalism vs. substantivalism, and issues about underdetermination of theories dominated the literature on spacetime. These issues still receive considerable attention from philosophers, but many have shifted their attentions to other questions related to quantum mechanics and to spacetime theories. Quantum field theory has become a major focus, particularly from the point of view of algebraic foundations. Concurrent with these trends, there has been a focus on understanding gauge invariance and symmetries. The philosophy of physics has evolved even further in recent years with attention being paid to theories that, for the most part, were largely ignored in the past. For example, the relationship between thermodynamics and statistical mechanics---once thought to be a paradigm instance of unproblematic theory reduction---is now a hotly debated topic. The implicit, and sometimes explicit, reductionist methodology of both philosophers and physicists has been severely criticized and attention has now turned to the explanatory and descriptive roles of "non-fundamental,'' phenomenological theories. This shift of attention includes "old'' theories such as classical mechanics, once deemed to be of little philosophical interest. Furthermore, some philosophers have become more interested in "less fundamental'' contemporary physics such as condensed matter theory. Questions abound with implications for the nature of models, idealizations, and explanation in physics. This Handbook showcases all these aspects of this complex and dynamic discipline.
Download or read book Introduction To Liquid State Physics written by Norman H March and published by World Scientific Publishing Company. This book was released on 2002-08-15 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This important book provides an introduction to the liquid state. A qualitative description of liquid properties is first given, followed by detailed chapters on thermodynamics, liquid structure in relation to interaction forces and transport properties such as diffusion and viscosity. Treatment of complex fluids such as anisotropic liquid crystals and polymers, and of technically important topics such as non-Newtonian and turbulent flows, is included. Surface properties and characteristics of the liquid-vapour critical point are also discussed. While the book focuses on classical liquids, the final chapter deals with quantal fluids.
Download or read book High Pressure Chemistry and Biochemistry written by R. van Eldik and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: It was the objective of the ASI on "Advances in High Pressure Studies of Chemical and Biochemical Systems" to present the current status of such studies and to emphasize the advances achieved during the nine years since the previous ASI on "High Pressure Chemistry". These advances are partly due to the improved instrumentation enabling static and dynamic measurements at pressures several orders of magnitude higher than before, and partly due to the more general availability of high pressure equipment. This has led to a remarkable development in various areas of physics and chemistry, and especially in biochemistry. Throughout the presentation of this Advanced Study Institute the emphasis fell on the teaching character of such a summer school, and the contributions in this volume are of such a nature. Following a general introduction to modern high pressure research, a series of chapters on theoretical and experimental studies of gases, fluids and solids at high temperatures and pressures are presented with special emphasis on the physical aspects involved. Instrumentation used in such studies, viz. shock compression, NMR spectroscopy, laser scattering, x-ray and neutron scattering, and vibrational spectroscopy are treated in detail. The subsequent chapters are devoted to the application of high pressure techniques in the broad areas of organic, inorganic and biochemistry_ The formal lectures were supplemented by 29 contributed papers, for which a list of titles is included.
Download or read book Structure Solvation Forces and Transport of Confined Fluids written by T. Kyle Vanderlick and published by . This book was released on 1988 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamics written by J. P. O'Connell and published by Cambridge University Press. This book was released on 2005-05-16 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamics: Fundamentals and Applications is a 2005 text for a first graduate course in Chemical Engineering. The focus is on macroscopic thermodynamics; discussions of modeling and molecular situations are integrated throughout. Underpinning this text is the knowledge that while thermodynamics describes natural phenomena, those descriptions are the products of creative, systematic minds. Nature unfolds without reference to human concepts of energy, entropy, or fugacity. Natural complexity can be organized and studied by thermodynamics methodology. The power of thermodynamics can be used to advantage if the fundamentals are understood. This text's emphasis is on fundamentals rather than modeling. Knowledge of the basics will enhance the ability to combine them with models when applying thermodynamics to practical situations. While the goal of an engineering education is to teach effective problem solving, this text never forgets the delight of discovery, the satisfaction of grasping intricate concepts, and the stimulation of the scholarly atmosphere.
Download or read book Colloidal Dispersions written by William Bailey Russel and published by Cambridge University Press. This book was released on 1991 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the physical side of colloidal science from the individual forces acting between particles smaller than a micrometer that are suspended in a liquid, through the resulting equilibrium and dynamic properties. A variety of internal forces both attractive and repulsive act in conjunction with Brownian motion and the balance between them all decides the phase behaviour. On top of this various external fields, such as gravity or electromagnetic fields, diffusion and non-Newtonian rheology produce complex effects, each of which is of important scientific and technological interest. The authors aim to impart a sound, quantitative understanding based on fundamental theory and experiments with well-characterised model systems. This broad grasp of the fundamentals lends insight and helps to develop the intuitive sense needed to isolate essential features of the technological problems and design critical experiments. The main prerequisites for understanding the book are basic fluid mechanics, statistical mechanics and electromagnetism, though self contained reviews of each subject are provided at appropriate points. Some facility with differential equations is also necessary. Exercises are included at the end of each chapter, making the work suitable as a textbook for graduate courses in chemical engineering or applied mathematics. It will also be useful as a reference for individuals in academia or industry undertaking research in colloid science.
Download or read book Detonation of Condensed Explosives written by Roger Cheret and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work marks a stage in the evolution of a scientific and technical field which has been developed by the Commissariat a l'Energie Atomique (CEA) over several decades. Many members of the staff of the CEA have won re nown in this field, and their work has brought it to the high degree of excel lence for which it is internationally recognized today. These scientists had to consider every aspect of the field, as it concerned: modeling, which has recourse to fluid thermodynamics, molecular phys ics, and chemistry; numerical evaluation, which relies on mathematical analysis and data processing; and experiments in the firing area, which require specific stress generators and instrumentation. Whilst this book is a testament to the activity and success of staff of the CEA, it also reviews a number ofthe advances made in the discipline. How ever, it is not intended to be an exhaustive account of those advances; it is assumed that the reader can, if desired, consult the standard monographs, and more recent, more specialized works (notably W.C. Davis and W. Fickett, and C.L. Mader). The history of the discipline is interesting in itself, and also as an illustra tion of the causes which lead to progress in a coherent body of scientific work. I should like to make some comments on this progress, of which there is a fascinating summary in the introduction, and which will figure largely throughout the work.
