Download or read book The Kinetics of the Complexing of Ferric Ion by Thiocyanate and Chloride Ions written by Claude Peter Coppel and published by . This book was released on 1958 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Kinetics of the Complexing of Ferric Ion by Thiocyanate and Chloride Ions thesis written by and published by . This book was released on 1957 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: An apparatus for rapidly mixing two solutions and recording the light absorption, which was developed by Connick and Below, has been modified. The mixing characteristics were studied and models were developed in an attempt to umder stand the observed mixing phenomena. The apparatus was applied to a study of the kinetics of the reactions Fe/sup +++/ + SCN/sup -/ = FeSCN/sup ++/ and Fe/ sup +++/ Cl/sup -/ = FeCl/sup ++/ in aqueous solution, with both reactions having the forward rate law STAd(FeX/sup ++/)/dt = k/sub 1/ (Fe/sup +++/) (X/sup -/) + k/ sub 2/ (Fe/sup +++/)(X/sup -/)/(H/sup +)!, where X/sup -/ represents either SC N/ sup -/ or Cl/sup -/. The rate constants k/sub 1/ and k/sub 2/ have been measured as a function of temperature, and the heats and entropies of activation have been calculated. Mechanisms for the observed rate law have been discussed and the entropies of activation were compared with those for analogous reaction rates and with some equilibrium entropies of complexing. A rate for chloride complexing of ferric ion was obtained from nuclear magnetic resonance studies and compared with the results of the spectrophotometric kinetic study. (auth).

Download or read book The Iron III Thiocyanate Reaction written by Kevin C. de Berg and published by Springer Nature. This book was released on 2019-11-13 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Brief presents an historical investigation into the reaction between ferric ions and thiocyanate ions, which has been viewed in different ways throughout the last two centuries. Historically, the reaction was used in chemical analysis and to highlight the nature of chemical reactions, the laws of chemistry, models and theories of chemistry, chemical nomenclature, mathematics and data analysis, and instrumentation, which are important ingredients of what one might call the nature of chemistry. Using the history of the iron(III) thiocyanate reaction as a basis, the book’s main objective is to explore how chemistry develops its own knowledge base; how it assesses the reliability of that base; and how some important tools of the trade have been brought to bear on a chemical reaction to achieve understanding, a worthwhile goal of any historical investigation.

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1975-04 with total page 1082 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Canadian Journal of Chemistry written by and published by . This book was released on 1962 with total page 1248 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Research and Development Abstracts of the USAEC written by and published by . This book was released on 1962 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemistry and geology written by R. C. Extermann and published by . This book was released on 1958 with total page 772 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Kinetics of Inorganic Reactions written by A. G. Sykes and published by Elsevier. This book was released on 2013-10-22 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kinetics of Inorganic Reactions provides a comprehensive account of the mechanisms of inorganic reaction. The book is comprised of 15 chapters that deal with the two main fields of inorganic reaction, the homogeneous gas-phase reactions and solution reactions. The first chapter of the text provides an introduction to some of the basic concepts in inorganic reaction, which include the mechanisms of a reaction, reactions in different phases, and the feasibilities of a reaction. Next, the book details the experimental techniques and treatment of data. The next series of chapters talks about gas-phase reactions. The book also dedicates a chapter in covering various types of reactions, including isotopic reaction and redox reaction. Chapters 12 to 14 deal with substitution reactions, while Chapter 15 talks about acid-base reactions. The text will be most useful to chemists and chemical engineers, particularly those who deal with inorganic chemistry.

Download or read book Research and Development Abstracts of the USAEC written by U.S. Atomic Energy Commission. Division of Technical Information and published by . This book was released on 1962 with total page 726 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Research and Development Abstracts of the USAEC written by U.S. Atomic Energy Commission and published by . This book was released on 1962-10 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Research with radioisotopes in chemistry and geology written by Richard C. Extermann and published by . This book was released on 1958 with total page 774 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Research and Development in Progress written by and published by . This book was released on 1973 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Inorganic Reaction Mechanisms written by A. McAuley and published by Royal Society of Chemistry. This book was released on 1977 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Download or read book Chemistry written by Arun Mittal and published by APH Publishing. This book was released on 2007 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Register of the University of California written by University of California (1868-1952) and published by . This book was released on 1958 with total page 1662 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Radioisotopes in Scientific Research Research with radioisotopes in chemistry and geology written by R. C. Extermann and published by . This book was released on 1958 with total page 772 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Analytical Profile of the Resin Spot Test Method written by Vladimir Grdinic and published by CRC Press. This book was released on 2018-05-04 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: The working title of the book was The Detection of Analytes by the Resin Spot Tests Method. Firstly, we decided to sort out all published qualitative methods systematically against analytes. We were not discouraged by the obstacles, such as the study of a great number of papers published in Japanese, the difficulty in locating (especially older) publications, or the time required. Still, having in mind not to burden unnecessarily the volume of the book, we dismissed the idea of systematically listing all the procedures in detail. Nevertheless, a relatively large number of them found a place in the book, and perhaps this will contribute to the stirring of spontaneous interest in this technique in the ranks of applied chemists and others who a priori shun the technique.