Download or read book Chemistry in Aqueous and Non aqueous Solvents written by Y. Mido and published by Discovery Publishing House. This book was released on 2001 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Aqueous Solution Chemistry, Acids and Bases, Solute-Solvent Interactions, Chemistry in Protonic Solvents Liquid Ammonia, Liquid Hydrogen, Fluoride, Sulphuric, Acid, Liquid, Hydrogen, Cyanide, Acetic Acid and Liquid Hydrogen Sulphide, Non- Protonic Solvents Liquid Dinitrogen Tetroxide, Liquid Sulphur, Dioxide and Liquid Halides.
Download or read book Non Aqueous Solvents in Inorganic Chemistry written by A. K. Holliday and published by Elsevier. This book was released on 2013-10-22 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: Non-Aqueous Solvents in Inorganic Chemistry gives a concise treatment of the important inorganic non-aqueous solvents, emphasizing why they do in fact exhibit solvent power, how they are prepared and handled experimentally, how they can be used as media for the synthesis or analysis of inorganic and organometallic compounds, and how far the various acid-base concepts can be useful in accounting for many (but not all) of the reactions observed. This book is intended primarily for the undergraduate reader—both for the intending Chemistry Honours or R.I.C. graduate and the non-specialist student of chemistry. The subject matter is presented in a simple and readable form, without the inclusion of elaborate tables of properties and with the minimum of detail necessary for comprehension. Therefore, those working for the A- and S-level chemistry examinations for the G.C.E. could read much of the book with profit; and the research student who aspires to work in the field of non-aqueous solvents will, it is hoped, find this book a useful introduction to a fascinating branch of inorganic chemistry.
Download or read book The Chemistry of Non aqueous Solvents Acidic and basic solvents written by J. J. Lagowski and published by . This book was released on 1966 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Non aqueous Solvents written by Ludwig Frederick Audrieth and published by . This book was released on 1953 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry in Non Aqueous Solvents written by B. Trémillon and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Arising no doubt from its pre-eminence as a natural liquid, water has always been considered by chemists as the original solvent in which very varied chemical reactions can take place, both for preparational and for analytical purposes. This explains the very long-standing interest shown in the study of aqueous solutions. In this con nection, it must be stressed that the theory of Arrhenius and Ostwald (1887-1894) on electrolytic dissociation, was originally devised solely for solutions in water and that the first true concept of acidity resulting from this is linked to the use of this solvent. The more recent development of numerous physico-chemical measurement methods has made possible an increase of knowledge in this area up to an extremely advanced degree of systematization. Thus today we have available both a very large amount of experimental data, together with very refined methods of deduction and of quantitative treatment of chemical reactions in solution which enable us to make the fullest use of this data. Nevertheless, . it appears quite evident at present that there are numerous chemical processes which cannot take place in water, and that its use as a solvent imposes 2 INTRODUCTION limitations. In order to overcome these limitations, it was natural that interest should be attracted to solvents other than water and that the new possibilities thus opened up should be explored.
Download or read book The Chemistry of Non aqueous Solvents written by J. J. Lagowski and published by . This book was released on 1978 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Nonaqueous Solvents VB written by J.J. Lagowski and published by Elsevier. This book was released on 2012-12-02 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Nonaqueous Solvents, Volume V: Acidic and Aprotic Solvents, Part B covers the theoretical aspects of individual solvents in nonaqueous solution chemistry. This volume is divided into five chapters. The first two chapters discuss the purification, structure, physical properties, electrochemistry, solubilities, and reactions of specific solvents, including trifluoroacetic and halosulfuric acids. Chapter 3 deals briefly with the preparations and properties of the interhalogens, principally in the liquid state. This chapter emphasizes their uses as nonaqueous solvents, especially through extensive study of their acid-base reactions. Spectroscopic data and their contribution to the understanding of their solution chemistries are also considered. Chapter 4 surveys the autoionization, purification methods, solubilities, solvolytic reactions, conductivity, conductometric, potentiometric, spectrophotometric, and visual titrations, as well as the isolation of solid complexes in inorganic halides and oxyhalides. Chapter 5 describes the solubility, reactivity, and spectroscopic data of molten salts. This book is of value to analytical chemists, and analytical chemistry teachers and students.
Download or read book The Chemistry of Nonaqueous Solvents VA written by J.J. Lagowski and published by Elsevier. This book was released on 2012-12-02 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Nonaqueous Solvents, Volume V-A: Principles and Basic Solvents provides the theoretical aspects of nonaqueous solution chemistry independent of solvent and information on individual solvent systems. This volume contains chapters on solvation and complex formation in protic and aprotic solvents; solvent basicity; ion-selective electrodes in nonaqueous solvents; nonaqueous solvents in organic electroanalytical chemistry; and anhydrous hydrazine and water-hydrazine mixtures. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.
Download or read book The Chemistry of Non aqueous Solvents written by J. J. Lagowski and published by . This book was released on 1966 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Chemistry in Nonaqueous Solvents written by Arthur Kenneth Holliday and published by Pergamon. This book was released on 1965 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Non aqueous Solvents written by Joseph J. Lagowski and published by . This book was released on 1967 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Coordination Chemistry in Non Aqueous Solutions written by Victor Gutmann and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt: Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.
Download or read book Acids and Bases written by Brian G. Cox and published by OUP Oxford. This book was released on 2013-01-31 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base strengths and to the rates and equilibria of many processes: for example, synthetic reactions involving acids, bases and nucleophiles; isolation of pharmaceutical actives through salt formation; formation of zwitter- ions in amino acids; and chromatographic separation of substrates. This book seeks to enhance our understanding of acids and bases by reviewing and analysing their behaviour in non-aqueous solvents. The behaviour is related where possible to that in water, but correlations and contrasts between solvents are also presented. Fundamental background material is provided in the initial chapters: quantitative aspects of acid-base equilibria, including definitions and relationships between solution pH and species distribution; the influence of molecular structure on acid strengths; and acidity in aqueous solution. Solvent properties are reviewed, along with the magnitude of the interaction energies of solvent molecules with (especially) ions; the ability of solvents to participate in hydrogen bonding and to accept or donate electron pairs is seen to be crucial. Experimental methods for determining dissociation constants are described in detail. In the remaining chapters, dissociation constants of a wide range of acids in three distinct classes of solvents are discussed: protic solvents, such as alcohols, which are strong hydrogen-bond donors; basic, polar aprotic solvents, such as dimethylformamide; and low-basicity and low polarity solvents, such as acetonitrile and tetrahydrofuran. Dissociation constants of individual acids vary over more than 20 orders of magnitude among the solvents, and there is a strong differentiation between the response of neutral and charged acids to solvent change. Ion-pairing and hydrogen-bonding equilibria, such as between phenol and phenoxide ions, play an increasingly important role as the solvent polarity decreases, and their influence on acid-base equilibria and salt formation is described.
Download or read book Solvation Ionic and Complex Formation Reactions in Non Aqeuous Solvents written by K. Burger and published by Elsevier. This book was released on 2012-12-02 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
Download or read book Electrochemistry in Nonaqueous Solutions written by Kosuke Izutsu and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Download or read book Chemistry in Non aqueous Solvents written by Harry Hall Sisler and published by . This book was released on 1961 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Nonaqueous Solvents III written by J.J. Lagowski and published by Elsevier. This book was released on 2012-12-02 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Nonaqueous Solvents, Volume III: Inert, Aprotic, and Acidic Solvents is a compilation of critical surveys of specific solvent systems. The compendium contains discussions on the solution chemistry of sulfur dioxide and acyl halides; the solvent properties of hydrogen sulfide and carboxylic acids; and the Bronsted acid-base behavior in inert organic solvents. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.
