Download or read book The Chemistry of Low valent Late Transition Metal Amides and Amidinates written by Tung Suet Lam and published by . This book was released on 2002 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis Structures and Reactivities of Low valent Late Transition Metal Amides written by Chung Hei Lam and published by . This book was released on 2001 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry of Low valent Early Transition Metals and Lanthanides written by Ravinder Minhas and published by . This book was released on 1996 with total page 550 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Novel Chemistry of Low valent Early Transition Metal Complexes written by Mikhail Victorovich Barybin and published by . This book was released on 1999 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Amide Chemistry written by Michael Lappert and published by John Wiley & Sons. This book was released on 2008-12-23 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power’s 1980 book “Metal and Metalloid Amides.” An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals alkaline earth metals zinc, cadmium and mercury the transition metals group 3 and lanthanide metals group 13 metals silicon and the group 14 metals group 15 metals the actinide metals Accompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.
Download or read book Preparation Characterisation and Reactivity of Low Oxidation State d Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands written by Jamie Hicks and published by Springer. This book was released on 2016-10-24 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.
Download or read book Chemistry of Low valent Early Transition Metals and Lanthanides written by Ravinder Minhas and published by . This book was released on 1996 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal and Metalloid Amides written by M. F. Lappert and published by Ellis Horwood. This book was released on 1980 with total page 860 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Low Valent Chemistry of the Early Transition Metals written by N. J. Cooper and published by . This book was released on 1976 with total page 185 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Reactions of Low valent Transition Metal Complexes written by D. C. Wood and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Low valent Main Group Complexes and Their Transition Metal like Reactivity written by Matthew M. D. Roy and published by . This book was released on 2019 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book One electron Transfer Reactions of Low valent Transition Metal Complexes written by S. J. Raven and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Syntheses and Reactions of Early Transition Metal Amidinate Compounds written by Adam Christopher Lamb and published by . This book was released on 2013 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homoleptic Groups 4 and 5 metal amide compounds have been used as precursors in CVD/ALD processes to make microelectronic metal oxide thin films. These compounds are often very air sensitive. Ancillary ligands such as amidinates have been used to reduce their air sensitivity and to make their handling easier. Reactions of amidinates with dioxygen and water have thus been used to make metal oxide thin films. Studies of these reactions are important in order to make better precursors and purer thin films. This dissertation focuses on the following areas: (a) Syntheses of zirconium and Group 5 amidinate amides; (b) Studies of the reactions of zirconium amidinate amides with dioxygen or water; (c) Probing the pathway in the formation of an archetypical tungsten alkylidyne complex. Zr[MeC(Ni̳Pr)2]2(NMe2)2 [zirconium amidinate amide] has been prepared through three different routes: two salt metathesis reactions and one aminolysis. The aminolysis of M(NR2)n̳ [metal amide] with i̳PrN(H)C(Me)=Ni̳Pr [diisopropylamidine] gives cleaner products in better yields and this route has been chosen to make amidinates in this dissertation. Reactions of zirconium amidinate amide complexes with dioxygen, water or hydrogen peroxide have been studied. Metal-containing products were {(μ-O)Zr[MeC(Ni̳Pr)2]2}2 [zirconium amidinate oxo dimer] and {(μ-O)Zr[MeC(Ni̳Pr)2]2}n̳ [zirconium amidinate oxo polymer] based on NMR, IR, MS and elemental analysis. Also, the reaction of Zr[MeC(Ni̳Pr)2]2(NMe2)2 with dioxygen yields {(m-h2:h2-O2)Zr[MeC(Ni̳Pr)2]2}3 [zirconium peroxo amidinate trimer] and its crystal structure is reported. Ta[MeC(Ni̳Pr)2](NMe2)4 [tantalum amidinate amide] and carbon tetrachloride undergo an amide-chloride exchange, giving Ta[MeC(Ni̳Pr)2](NMe2)3Cl [tantalum amidinate amide chloride]. Ta[MeC(Ni̳Pr)2](NMe2)3Cl has also been synthesized through the aminolysis of Ta(NMe2)4Cl [tantalum amide chloride] with a diisopropyl amidine. W(CH2t̳Bu)3(≡Ct̳Bu) [tungsten neopentyl neopentylidyne] has been prepared through the reaction of W(OMe)3Cl3 [tungsten chloride methoxide] and Zn(CH2t̳Bu)2 [dineopentyl zinc]. Also, a side product which has been characterized through NMR spectroscopies to be W(OMe)2Cl(CH2t̳Bu)3 [tungsten neopentyl chloride methoxide].
Download or read book Electronic Properties and Oxidation reduction Chemistry of a Series of Late Transition Metal Complexes written by Jia Luo (Lecturer in chemistry) and published by . This book was released on 2014 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book An Exploration of Mid to High valent Transition Metal Complexes for Application to Catalysis written by Kelly E. Aldrich and published by . This book was released on 2019 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt: The valency or oxidation state of a transition metal in a complex plays a large role in determining the reactivity of the complex. With transition metal chemistry, historically accessible chemistry has often focused on metals in a low oxidation state. However, transformations involving transition metals in high oxidation states are of equal importance in providing complex products for use in consumer products. Expanding the applications and understanding of transition metal complexes in high oxidation states is the focus of the research presented in this dissertation. Fundamental studies of how ligands interact with high valent metals is presented in chapters 2 and 3, where a chromium(VI) model complex has been used to study bonding interactions between this d0 transition metal and phosphine ligands. Practical application of high valent titanium(IV) catalysts to C--N bond forming reactions is presented in chapters 4--6. Finally, chapters 7 and 8 focus on the changes in the character of M--N double bonds, with M=Fe and Ru, as the metal is forced to higher oxidation states. Collectively, these studies demonstrate different approaches to the same general problems and questions of how chemists can better understand and utilize high valent transitions metals to do catalytically-target desired transformations.
Download or read book Organotransition Metal Chemistry From Bonding to Catalysis written by John F. Hartwig and published by . This book was released on 2010-02-10 with total page 1172 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1999 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt:
