Download or read book The Characterization Persistence and Bioaccessibility of Roaster derived Arsenic in Surface Soils at Giant Mine Yellowknife NT written by Mackenzie Jane Bromstad and published by . This book was released on 2011 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approximately 20,000 tonnes of arsenic (As)-bearing emissions from roasting arsenopyrite ore were aerially released from 1949-1999 at Giant Mine, located outside Yellowknife, NT. As part of the process used to free refractory gold (Au) from arsenopyrite (FeAsS), roasting created As-bearing roaster off-gases that condensed into As2O3, one of the most toxic As compounds to humans. Roaster emissions also contained some As-bearing iron (Fe)- oxides. Arsenic emission controls were first implemented in 1951, and by the time the emission control process was completely refined in 1963, 86% of the total aerial As emissions at Giant had been released into the surrounding area. The continued presence of roaster-derived As2O3 in surface soils at Giant has been previously documented despite its theoretical instability in oxidizing surface environments. Wrye (2008) found As concentrations in roaster-affected soils occurring on rock outcrop (covering ~30% of the Giant property) greater than in many other surface soils; most outcrop soils were not considered when delineating areas of contaminated material for future removal in the Giant Mine Remediation Plan (currently undergoing environmental assessment). To investigate roaster-derived As persistence, outcrop soils and soil pore waters were analyzed. Comparing proportions of As, Sb, and Au concentrations in soil samples and historic As2O3-rich dust captured by emission controls show that most of the roaster-derived As in soils at Giant was likely deposited before 1964. Thin section examination has shown that while the vast majority of discrete As hosts in soils are As2O3, textural relationships and certain secondary As hosts in soils indicate that As2O3 is not static in surface soils and could be transforming over time, albeit very slowly. Bulk chemical relationships among As, antimony (Sb), and carbon support this. Topographic restriction by rock outcrops and dry, cold climate probably play a large role in elevated As concentrations and As2O3 persistence in outcrop soils. In light of possible future human exposure, As bioaccessibility from three adjacent samples was determined for synthetic human gastric (34%) and lung (18%) fluids.
Download or read book Arsenic written by Robert Bowell and published by Walter de Gruyter GmbH & Co KG. This book was released on 2014-11-21 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental Mineralogy and Bio-Geochemistry of Arsenic provides a comprehensive understanding of arsenic geochemistry in the near-surface environment. Topics covered include the mineralogy, thermodynamics, geochemistry, analysis, microbiology, and bioavailability of arsenic, with emphasis on implications for arsenic toxicity, geochemistry in natural ground waters, and mine-associated impacts and possible mitigation options. This volume is useful for those seeking to understand arsenic geochemistry and biological interactions in the near-surface environment, Clay Minerals does not use an online manuscript tracking/submission system. as well those working for mining companies, the chemicals industry, NGO’s or government bodies concerned with reducing the impact of arsenic on the environment.
Download or read book Distinguishing Between Natural and Anthropogenic Sources of Arsenic in Soils from the Giant Mine Northwest Territories and the North Brookfield Mine Nova Scotia written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Anthropogenic and geogenic sources of arsenic (As) have been identified in mining-impacted soils from the Giant mine (1948-1999), NT and the North Brookfield mine (1886-1906), NS. Both used roasting to extract gold from the arsenopyrite ore, decomposing it to As-bearing iron oxides (roaster oxides or RO) containing As, and releasing As3+-bearing arsenic trioxide (As2O3). Arsenic trioxide is considered highly soluble with the dissolved As3+ species being more mobile and toxic than other oxidation states. Soil profiles from the Giant mine show elevated As and antimony (Sb) at the surface (As=140-3300ppm) and decreasing concentrations with depth (As=22-600ppm). Surface soils contain anthropogenically-derived As2O3 identified using synchrotron methods (æXRD, æXANES) and environmental SEM. The persistence of As2O3 is attributed to Sb in As2O3 grains, dry climate and high organics in the soils. Anthropogenically-derived RO of maghemite (containing both As3+ and As5+) and natural arsenopyrite were observed. Sequential selective extractions (SSE) from surface soils show between 20% and 75% of As extracted in the crystalline iron-oxide phase is attributed to As2O3 and RO, while at depth As is bound by organics in the weaker leaches. North Brookfield mine soils show lower total As (2ppm to 45ppm) except near the roaster (4300ppm). No As2O3 was identified, probably due to the smaller scale and age of the mine, lower organic content and the lack of Sb. As-bearing phases include RO of hematite (As5+), As-rich rims on titanium-oxides, and As associated with clays and goethite. Adjacent to the roaster, SSE show As was also in the amorphous iron-oxide phase, also shown by As in arsenopyrite weathering rims. There are many differences between the North Brookfield and Giant mine soils including roasting techniques which produced different RO mineralogy, the scale of mining, climate, soil type, and the presence of As2O3. Currently, the Giant property is not publically accessible but m.
Download or read book Determining Natural background Arsenic Soil Concentrations in Yellowknife NWT and Deriving Site specific Human Health based Remediation Objectives for Arsenic in the Yellowknife Area Final Report written by Canada. Environment Canada and published by . This book was released on 2002 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Determining Natural background Arsenic Soil Concentrations in Yellowknife NWT and Deriving Site specific Human Health based Remediation Objectives for Arsenic in the Yellowknife Area written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Study of Arsenic Contamination from the Royal Oak Giant Mine Yellowknife Northwest Territories written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Abstracts of Papers written by Geological Association of Canada. Meeting and published by . This book was released on 2001 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Saskatoon 2002 27 29 Mai Des Plaines Au Bouclier L int rieur D un Continent written by Geological Association of Canada. Meeting and published by . This book was released on 2002 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Metabolism of Arsenite written by Joanne M. Santini and published by CRC Press. This book was released on 2018-10-03 with total page 203 pages. Available in PDF, EPUB and Kindle. Book excerpt: Up to 200 million people in 70 countries are at risk from drinking water contaminated with arsenic, which is a major cause of chronic debilitating illnesses and fatal cancers. Until recently little was known about the mobility of arsenic, and how redox transformations determined its movement into or out of water supplies. Although human activities contribute to the release of arsenic from minerals, it is now clear that bacteria are responsible for most of the redox transformation of arsenic in the environment. Bacterial oxidation of arsenite (to the less mobile arsenate) has been known since 1918, but it was not until 2000 that a bacterium was shown to gain energy from this process. Since then a wide range of arsenite-oxidizing bacteria have been isolated, including aerobes and anaerobes; heterotrophs and autotrophs; thermophiles, mesophiles and psychrophiles. This book reviews recent advances in the study of such bacteria. After a section on background—geology and health issues—the main body of the book concerns the cellular machinery of arsenite oxidation. It concludes by examining possible applications. Topics treated are: The geology and cycling of arsenic Arsenic and disease Arsenite oxidation: physiology, enzymes, genes, and gene regulation. Community genomics and functioning, and the evolution of arsenite oxidation Microbial arsenite oxidation in bioremediation Biosensors for arsenic in drinking water and industrial effluents
Download or read book Arsenic Contamination in the World written by Susan Murcott and published by IWA Publishing. This book was released on 2012-09-30 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: Arsenic Contamination in the World: an International Sourcebook provides a global compendium of cited arsenic occurrences in the world as they affect public health. This book details arsenic contamination by source, region and arsenic-affected country. Arsenic is identified in 105 countries and territories, representing a larger database than any previous published work. Sources of arsenic contamination are categorized as Anthropogenic, Geogenic, Volcanogenic, Coal, Mining and Petroleum-related. National, regional and international maps locate the affected areas and populations. A synthesis of critical country information includes an estimate of the exposed population of 226 million people worldwide. This reference work is an indispensable tool for medical doctors, public health workers, scientists, water experts, governments, industries, non-profit organizations and communities in identifying site-specific arsenic contamination. An extensive bibliography of peer-reviewed literature gives the reader important arsenic contamination locations as the first step towards remediation. This Sourcebook is updatable via an on-line annex which provides up-to-date information on new arsenic occurrences and developments. We invite readers to participate in updating this database at: http://www.iwawaterwiki.org/xwiki/bin/view/Articles/ExecutiveSummaryofArsenicContaminationintheWorld By synthesizing the known occurrences of arsenic world-wide, this reference book offers an essential tool for understanding and addressing the global arsenic geological-public health interface. Discounted ebook price available for customers from Developing Countries. Please contact [email protected] if you wish to purchase an ebook from a developing country @ £50.00 (PDF format). Author: Susan Murcott, Senior Lecturer, Civil and Environmental Engineering Department, Massachusetts Institute of Technology, USA Table of Contents: Executive Summary, African Region, Region of the Americas, Asia Region, European Region, Region of Australia and Oceania.
Download or read book Life in Extreme Environments written by Ricardo Amils Pibernat and published by Springer Science & Business Media. This book was released on 2007-07-21 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an intriguing look at how life can adapt to many different extreme environments. It addresses the limits for life development and examines different strategies used by organisms to adapt to different extreme environments.
Download or read book Organometallic Compounds in the Environment written by P. J. Craig and published by John Wiley & Sons. This book was released on 2003-09-12 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: A knowledge of the chemical structure and concentration of organometal compounds throughout the ecosystem is important in working out the pathways and mechanisms by which metals distribute themselves throughout the environment. Treating the topic as an integrated subject area, the Second Edition of Organometallic Compounds in the Environment covers all the recent developments in analytical techniques and reports all the new work that has been achieved since the first book. Covers the general importance and characteristics of organometallic species. Includes general developments in analytical techniques. Discusses several minority elements including antimony and selenium. The book addresses the subject in a single, manageable size and each chapter can be used either as a single review or sequentially within the topic area. A useful resource for all researchers and scientists in industry working with organometallic compounds, including, chemists, environmentalists and ecologists.
Download or read book Arsenic Geochemistry written by Darrell Kirk Nordstrom and published by CRC Press. This book was released on 2015-01-15 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an overview of arsenic in the environment emphasizing geochemistry. It covers arsenic in rocks, minerals, soils and sediments, surface and ground waters, vegetation, analytical chemistry, with a short section on toxicology and epidemiology, and case histories in about 50 countries.
Download or read book Extractive Metallurgy of Activated Minerals written by P. Baláž and published by Elsevier. This book was released on 2000-04-28 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanical activation of solids is a part of mechanochemistry, the science with a sound theoretical foundation exhibiting a wide range of potential application. Mechanical activation itself is an innovative procedure where an improvement in technological processes can be attained via a combination of new surface area and defects formation in minerals. Mechanical activation is of exceptional importance in extractive metallurgy and mineral processing and this area forms the topic of this book and is the result of more than twenty years of research and graduate teaching in the field. In pyrometallurgy, the mechanical activation of minerals makes it possible to reduce their decomposition temperatures or causes such a degree of disordering that the thermal activation may be omitted entirely. The potential mitigation of environmental pollutants is becoming increasingly important in this context. The lowering of reaction temperatures, the increase of the rate and amount of solubility, preparation of water soluble compounds, the necessity for simpler and less expensive reactors and shorter reaction times are some of the advantages of mechanical activation in hydrometallurgy. The environmental aspects of these processes are particularly attractive. Several industrial processes are examined and their flowsheets are presented as succesful of activation. In these processes, the introduction of a mechanical activation step into the technological cycle significantly modifies the subsequent steps. The book is designed for researchers, teachers, operators and students in the areas of extractive metallurgy, mineral processing, mineralogy, solid state chemistry and materials science.It will encourage newcomers to the mechanochemistry to do useful research and discover novel applications in this field.
Download or read book Metal Poisoning in Fish written by Elsa M. B. Sorensen and published by CRC Press. This book was released on 1991-05-03 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Poisoning in Fish provides a comprehensive look at many aspects of metal poisoning of euryhaline and stenohaline fish. Metals and metalloids are considered individually and collectively and include arsenic, lead, selenium, copper, cadmium, mercury, and zinc. This informative, readable volume is designed to help regulatory personnel, enforcement personnel, and scientists understand the impact of these elements on fish. Topics covered include mechanisms of action, toxicity, biological effects, accumulation, tissue distribution, concentration factors, maximum acceptable toxicant concentrations, application factors, biological half-lives, uptake kinetics, depuration kinetics, elemental speciation, and detoxification mechanisms. The book emphasizes the use of data gathered from a variety of sources to pinpoint specific elemental agents as causal factors in the morbidity and mortality of fish.
Download or read book Handbook of Arsenic Toxicology written by Swaran Jeet Singh Flora and published by Academic Press. This book was released on 2023-02-21 with total page 988 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Arsenic Toxicology, Second Edition presents the latest findings on arsenic, including its chemistry, sources and effects on the environment and human health. The book discusses both acute and chronic effects, discussing many aspects of arsenic, from physical and chemical properties, exposure, epidemiology, organ toxicity, diagnosis, prevention and treatment. Fully updated and revised, this new edition includes new topics on risk assessment, molecular mechanisms of arsenic, advances in the integrated approach to testing, assessment and development, evaluation and application of high content predictive models, and new alternative methods (NAMS) in the context of Adverse Outcome Pathways (AOPs) to assess toxicology. This comprehensive resource allows readers to effectively assess the risks related to arsenic, providing them with all they need to know on arsenic exposure, toxicity and toxicity prevention. Brings together current findings on the effects of arsenic on the environment and human health Includes state-of-the-art techniques in arsenic toxicokinetics, speciation and molecular mechanisms Provides all the information needed for effective risk assessment, prevention and countermeasures
Download or read book Aeolian Geomorphology written by Ian Livingstone and published by John Wiley & Sons. This book was released on 2019-03-18 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: A revised introduction to aeolian geomorphology written by noted experts in the field The new, revised and updated edition of Aeolian Geomorphology offers a concise and highly accessible introduction to the subject. The text covers the topics of deserts and coastlines, as well as periglacial and planetary landforms. The authors review the range of aeolian characteristics that include soil erosion and its consequences, continental scale dust storms, sand dunes and loess. Aeolian Geomorphology explores the importance of aeolian processes in the past, and the application of knowledge about aeolian geomorphology in environmental management. The new edition includes contributions from eighteen experts from four continents. All the chapters demonstrate huge advances in observation, measurement and mathematical modelling. For example, the chapter on sand seas shows the impact of greatly enhanced and accessible remote sensing and the chapter on active dunes clearly demonstrates the impact of improvements in field techniques. Other examples reveal the power of greatly improved laboratory techniques. This important text: Offers a comprehensive review of aeolian geomorphology Contains contributions from an international panel of eighteen experts in the field Includes the results of the most recent research on the topic Filled with illustrative examples that demonstrate the advances in laboratory approaches Written for students and professionals in the field, Aeolian Geomorphology provides a comprehensive introduction to the topic in twelve new chapters with contributions from noted experts in the field.
